TW200500135A - Desulfurizing agent and method for production thereof, method for desulfurization, and method for producing hydrogen for fuel cell - Google Patents

Desulfurizing agent and method for production thereof, method for desulfurization, and method for producing hydrogen for fuel cell

Info

Publication number
TW200500135A
TW200500135A TW093105416A TW93105416A TW200500135A TW 200500135 A TW200500135 A TW 200500135A TW 093105416 A TW093105416 A TW 093105416A TW 93105416 A TW93105416 A TW 93105416A TW 200500135 A TW200500135 A TW 200500135A
Authority
TW
Taiwan
Prior art keywords
desulfurizing agent
desulfurization
sulfur
fuel cell
containing compound
Prior art date
Application number
TW093105416A
Other languages
Chinese (zh)
Inventor
Koichiro Furusawa
Tetsuji Suzuki
Kyo Ishimori
Masabumi Katsuta
Original Assignee
Univ Waseda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Waseda filed Critical Univ Waseda
Publication of TW200500135A publication Critical patent/TW200500135A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0211—Compounds of Ti, Zr, Hf
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0218—Compounds of Cr, Mo, W
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229—Compounds of Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/003—Additives for gaseous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Fuel Cell (AREA)
  • Gas Separation By Absorption (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)

Abstract

This invention provides a desulfurizing agent exhibiting ultra-high performance capability and allowing sulfur to be removed from a sulfur-containing compound instantaneously in a one-stage process with high efficiency, and also capable of being regenerated and used repeatedly; a method for producing the same; a method of desulfurization capable of effectively removing sulfur from a sulfur-containing compound using the same; and a method for producing high purity hydrogen gas for use in a fuel cell on a large scale at a low cost using high degree of the desulfurizing agent . A desulfurizing agent is characterized in that it is represented by the general formula: ZnFe2O4/SiO2/a molybdenum compound (MoS2 and/or MoO3), or ZnFe2O4/SiO2/a molybdenum compound/a titanium compound(TiO2). An instantaneous desulfurization is achieved by contacting a sulfur-containing compound with the desulfurizing agent. Meanwhile, an oxidation regenerated desulfurizing agent can be used or the desulfurization can be temporarily stopped. Further, high purity hydrogen for fuel cell can be obtained by a reforming treatment after desulfurization.
TW093105416A 2003-03-11 2004-03-02 Desulfurizing agent and method for production thereof, method for desulfurization, and method for producing hydrogen for fuel cell TW200500135A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003065060 2003-03-11
JP2003386108A JP4625970B2 (en) 2003-03-11 2003-11-17 Desulfurizing agent, method for producing the same, desulfurizing method, and method for producing hydrogen for fuel cell

Publications (1)

Publication Number Publication Date
TW200500135A true TW200500135A (en) 2005-01-01

Family

ID=32992947

Family Applications (1)

Application Number Title Priority Date Filing Date
TW093105416A TW200500135A (en) 2003-03-11 2004-03-02 Desulfurizing agent and method for production thereof, method for desulfurization, and method for producing hydrogen for fuel cell

Country Status (3)

Country Link
JP (1) JP4625970B2 (en)
TW (1) TW200500135A (en)
WO (1) WO2004080588A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4722414B2 (en) * 2004-06-02 2011-07-13 学校法人早稲田大学 Desulfurizing agent, method for producing the same, desulfurizing method, and method for producing high-purity hydrogen
KR101352973B1 (en) 2005-10-26 2014-01-22 삼성에스디아이 주식회사 Desulfurization adsorbent for fuel cell and desulfurizing method using the same
CN101235324B (en) * 2007-11-13 2011-06-08 沈阳航空工业学院 High-temperature coal gas desulfurizer using coal ash as carrier
FR2937045B1 (en) * 2008-10-10 2012-11-30 Inst Francais Du Petrole USE OF ZINC FERRITE-BASED SOLIDS IN A PROCESS FOR THE DEEP DEULFURIZATION OF OXYGENIC LOADS
JP2016064352A (en) * 2014-09-24 2016-04-28 一般財団法人電力中央研究所 Desulfurizing agent, and manufacturing method of desulfurizing agent
CN106807335A (en) * 2015-11-27 2017-06-09 武汉中地金盾环境科技有限公司 Magnetic retention polyamino adsorbent particulate material, preparation method and applications
CN111378285B (en) * 2020-04-30 2022-03-15 新纳奇材料科技江苏有限公司 High-strength high-flame-retardant organic silicon foam material and preparation method thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA93401B (en) * 1992-01-27 1993-08-24 Phillips Petroleum Co Composition useful as sulfur absorption for fluid streams.
JP3998218B2 (en) * 1995-02-10 2007-10-24 財団法人電力中央研究所 Carbon deposition control desulfurization agent
US5710089A (en) * 1995-06-07 1998-01-20 Phillips Petroleum Company Sorbent compositions
US5726117A (en) * 1995-06-07 1998-03-10 Phillips Petroleum Company Sorbent compositions containing zinc subjected to a steam treatment
JP3563923B2 (en) * 1997-06-11 2004-09-08 三菱重工業株式会社 Desulfurizing agent and method for producing the same
JPWO2002074883A1 (en) * 2001-03-21 2004-07-08 学校法人早稲田大学 Desulfurizing agent, method for producing and using the same

Also Published As

Publication number Publication date
JP2004290955A (en) 2004-10-21
JP4625970B2 (en) 2011-02-02
WO2004080588A1 (en) 2004-09-23

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