MX9801912A - Hidrogenacion de compuestos aromaticos en los cuales al menos un grupo amino es unido a un nucleo aromatico. - Google Patents

Hidrogenacion de compuestos aromaticos en los cuales al menos un grupo amino es unido a un nucleo aromatico.

Info

Publication number
MX9801912A
MX9801912A MX9801912A MX9801912A MX9801912A MX 9801912 A MX9801912 A MX 9801912A MX 9801912 A MX9801912 A MX 9801912A MX 9801912 A MX9801912 A MX 9801912A MX 9801912 A MX9801912 A MX 9801912A
Authority
MX
Mexico
Prior art keywords
aromatic
amino group
hydrogenation
joined
aromatic compounds
Prior art date
Application number
MX9801912A
Other languages
English (en)
Other versions
MXPA98001912A (es
MX201531B (es
Inventor
Heinz Rutter
Thomas Ruhl
Boris Breitscheidel
Jochem Henkelmann
Andreas Henne
Thomas Wettling
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of MX9801912A publication Critical patent/MX9801912A/es
Publication of MXPA98001912A publication Critical patent/MXPA98001912A/es
Publication of MX201531B publication Critical patent/MX201531B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
    • C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Compuestos aromáticos en los cuales al menos un grupo amino es unido a un nucleo aromático son hidrogenos por un proceso en el cual el catalizador comprende rutenio y, si se requiere, al menso un metal del subgrupo I, VII o bien VIII en una cantidad de 0.01 a 30% en peso, en bese al peso total del catalizador; son aplicados a un vehículo y el vehículo tiene un diámetro promedio de poro de al menos 0.1 æm y una área superficial no mayor que 15 m2/g.
MX9801912A 1995-09-12 1996-09-11 Hidrogenacion de compuestos aromaticos en los cuales al menos un grupo amino es unido a un nucleo aromatico. MX201531B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19533718.2 1995-09-12
DE19533718A DE19533718A1 (de) 1995-09-12 1995-09-12 Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Aminogruppe an einen aromatischen Kern gebunden ist
PCT/EP1996/003983 WO1997010202A1 (de) 1995-09-12 1996-09-11 Verfahren zur hydrierung von aromatischen verbindungen, in denen mindestens eine aminogruppe an einen aromatischen kern gebunden ist

Publications (3)

Publication Number Publication Date
MX9801912A true MX9801912A (es) 1998-05-31
MXPA98001912A MXPA98001912A (es) 1998-10-23
MX201531B MX201531B (es) 2001-04-24

Family

ID=7771928

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9801912A MX201531B (es) 1995-09-12 1996-09-11 Hidrogenacion de compuestos aromaticos en los cuales al menos un grupo amino es unido a un nucleo aromatico.

Country Status (10)

Country Link
US (1) US5773657A (es)
EP (1) EP0873300B1 (es)
JP (1) JPH11513362A (es)
KR (1) KR100474024B1 (es)
CN (1) CN1140496C (es)
BR (1) BR9610151A (es)
CZ (1) CZ293839B6 (es)
DE (2) DE19533718A1 (es)
MX (1) MX201531B (es)
WO (1) WO1997010202A1 (es)

Families Citing this family (40)

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DE19604791A1 (de) * 1996-02-09 1997-08-14 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Hydroxylgruppe an einen aromatischen Kern gebunden ist
EP0813906A3 (de) * 1996-06-19 1998-11-18 Basf Aktiengesellschaft Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines geträgerten Rutheniumkatalysators
US6248924B1 (en) * 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
DE19651129A1 (de) * 1996-12-09 1998-06-10 Basf Ag Verfahren zur Hydrierung einer aromatischen Verbindung in Gegenwart eines Trägerkatalysators
DE29824628U1 (de) * 1997-12-19 2001-11-29 Basf Ag Cyclohexanpolycarbonsäurederivate und diese enthaltende Kunststoffzusammensetzungen
DE19824906A1 (de) * 1998-06-04 1999-12-09 Bayer Ag Verfahren zur Herstellung von variablen Gemischen aus Cyclohexylamin und Dicyclohexylamin
DE19827282A1 (de) * 1998-06-19 1999-12-23 Bayer Ag Verfahren zur Herstellung von cycloaliphatischen Aminen
ATE245137T1 (de) * 1998-11-12 2003-08-15 Lonza Ag Verfahren zur herstellung von cyclohexandiaminen
DE59906309D1 (de) 1998-11-12 2003-08-21 Lonza Ag Verfahren zur herstellung von cyclohexandiaminen
DE19909176A1 (de) * 1999-03-03 2000-09-07 Kataleuna Gmbh Catalysts Hydrierkatalysator und Verfahren zu seiner Herstellung
DE19917051A1 (de) * 1999-04-15 2000-10-19 Basf Ag Verfahren zur Hydrierung von unsubstituierten oder alkylsubstituierten Aromaten unter Verwendung eines Makroporen aufweisenden Katalysators
JP3715482B2 (ja) * 1999-11-04 2005-11-09 エヌ・イーケムキャット株式会社 水素含有ガス中の一酸化炭素選択酸化触媒並びに該触媒を用いた一酸化炭素除去方法及び固体高分子電解質型燃料電池システム
CN1153788C (zh) * 1999-12-08 2004-06-16 陶氏环球技术公司 不饱和聚合物的氢化方法
JP3786007B2 (ja) * 2001-05-29 2006-06-14 住友金属鉱山株式会社 炭化水素油中に含む芳香族化合物の水素化処理用触媒
US6706658B2 (en) * 2001-12-21 2004-03-16 Engelhard Corporation Catalyst for purification of aromatic acids
DE50213288D1 (de) 2002-05-31 2009-04-02 Evonik Degussa Gmbh Geträgerter Rutheniumkatalysator und Verfahren zur Hydrierung eines aromatischen Amins in Gegenwart dieses Katalysators
TW200700152A (en) * 2005-04-21 2007-01-01 Shell Int Research Hydrogenation catalyst and hydrogenation method
US7465833B2 (en) * 2005-09-22 2008-12-16 Air Products And Chemicals, Inc. Hydrogenation of aromatic amines to alicyclic amines using a lithium aluminate-based catalyst
KR20080112373A (ko) * 2006-04-13 2008-12-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 알데하이드의 수소화 방법
US7932408B2 (en) * 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
WO2008122029A1 (en) * 2007-04-02 2008-10-09 Inventure Chemical, Inc. Simultaneous esterification and alcohol ysis/hydrolysis of oil-containing materials with cellulosic and peptidic content
US7943792B2 (en) * 2007-04-02 2011-05-17 Inventure Chemical Inc. Production of biodiesel, cellulosic sugars, and peptides from the simultaneous esterification and alcoholysis/hydrolysis of materials with oil-containing substituents including phospholipids and peptidic content
WO2009090179A2 (de) * 2008-01-18 2009-07-23 Basf Se Verfahren zur herstellung von cycloaliphatischen aminen
US7777085B2 (en) * 2008-10-01 2010-08-17 Inventure Chemical, Inc. Method for conversion of oil-containing algae to 1,3-propanediol
CN105384645A (zh) * 2008-11-18 2016-03-09 因温斯特技术公司 1,2-二氨基环已烷和化学方法
WO2011032877A1 (de) * 2009-09-18 2011-03-24 Basf Se Verwendung eines stereoisomerengemisches von diaminomethylcyclohexan als härter für epoxidharze
CN102633649B (zh) * 2012-03-29 2013-08-21 山东潍焦集团有限公司 一种苯胺气相催化加氢合成环己胺的方法
HRP20211641T1 (hr) 2012-07-13 2022-02-04 Roche Glycart Ag Bispecifična protutijela anti-vegf/anti-ang-2 i njihova primjena u liječenju vaskularnih očnih bolesti
CN102775313A (zh) * 2012-07-30 2012-11-14 江苏恒祥化工有限责任公司 一种高压连续化加氢制备1,4-环己二胺的方法
CN102921415B (zh) * 2012-10-31 2015-03-11 江苏清泉化学股份有限公司 加氢催化剂及其制备方法和在合成2-甲基四氢呋喃中的应用
HUE035346T2 (en) 2013-12-11 2018-05-02 Basf Se Process for hydrogenation of 4,4'-methylene dianiline
EP2883864A1 (de) 2013-12-11 2015-06-17 Basf Se Verfahren zur hydrierung aromatischer verbindungen
CN104177262B (zh) * 2014-07-15 2016-08-24 景县本源精化有限公司 脂环胺固化剂的制备方法
CN106278904B (zh) * 2016-08-08 2018-03-27 河北工业大学 由苯一锅法制备环己胺的方法
CN109790104B (zh) * 2016-10-10 2022-09-09 巴斯夫欧洲公司 氢化甲苯二胺(tda)焦油的方法
CN108067213B (zh) * 2016-11-15 2020-01-31 万华化学集团股份有限公司 一种用于苯胺精馏残渣资源化利用的催化剂及其制备方法
CN107089917A (zh) * 2017-05-26 2017-08-25 清华大学 多段流化床中硝基苯类化合物加氢制备苯胺类化合物的工艺
CN109651167B (zh) * 2017-10-10 2021-10-01 中国石油化工股份有限公司 用于生产环己胺的加氢催化剂
WO2020207874A1 (de) * 2019-04-12 2020-10-15 Basf Se Katalysatorsystem für die herstellung von aromatischen aminen

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Also Published As

Publication number Publication date
KR19990044594A (ko) 1999-06-25
CZ293839B6 (cs) 2004-08-18
CN1140496C (zh) 2004-03-03
DE19533718A1 (de) 1997-03-13
DE59605800D1 (de) 2000-09-28
CZ74198A3 (cs) 1998-09-16
KR100474024B1 (ko) 2005-05-16
JPH11513362A (ja) 1999-11-16
CN1200107A (zh) 1998-11-25
BR9610151A (pt) 1999-05-18
EP0873300A1 (de) 1998-10-28
EP0873300B1 (de) 2000-08-23
MX201531B (es) 2001-04-24
US5773657A (en) 1998-06-30
WO1997010202A1 (de) 1997-03-20

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