MX389231B - Método de preparación de aditivos de óxidos metálicos de tamaño nanométrico que reducen la temperatura de sinterizado y/o incrementan la productividad en la fabricación de piezas cerámicas, mejorando propiedades mecánicas sin afectar las propiedades de gresificación de cuerpos cerámicos, losetas o revestimientos. - Google Patents

Método de preparación de aditivos de óxidos metálicos de tamaño nanométrico que reducen la temperatura de sinterizado y/o incrementan la productividad en la fabricación de piezas cerámicas, mejorando propiedades mecánicas sin afectar las propiedades de gresificación de cuerpos cerámicos, losetas o revestimientos.

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Publication number
MX389231B
MX389231B MX2017004430A MX2017004430A MX389231B MX 389231 B MX389231 B MX 389231B MX 2017004430 A MX2017004430 A MX 2017004430A MX 2017004430 A MX2017004430 A MX 2017004430A MX 389231 B MX389231 B MX 389231B
Authority
MX
Mexico
Prior art keywords
additives
ceramic
sintering temperature
allow
properties
Prior art date
Application number
MX2017004430A
Other languages
English (en)
Other versions
MX2017004430A (es
Inventor
Fix Fierro Carlos
Enrique Acosta Gonzalez Guillermo
Gutierrez Antonio Joel
Avila Jaime Parada
Bustos Monica Ibeth Aguilera
Original Assignee
Nanomateriales Quim Avanzados S A De C V
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanomateriales Quim Avanzados S A De C V filed Critical Nanomateriales Quim Avanzados S A De C V
Priority to MX2017004430A priority Critical patent/MX389231B/es
Priority to BR112019020789-9A priority patent/BR112019020789B1/pt
Priority to EP17904875.6A priority patent/EP3608299A4/en
Priority to PCT/MX2017/000081 priority patent/WO2018186729A1/es
Priority to US16/603,131 priority patent/US11339098B2/en
Publication of MX2017004430A publication Critical patent/MX2017004430A/es
Priority to CONC2019/0011965A priority patent/CO2019011965A2/es
Publication of MX389231B publication Critical patent/MX389231B/es

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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/6261—Milling
    • C04B35/62615—High energy or reactive ball milling
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
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    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Wrappers (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

El objeto de la presente invención es un proceso para la fabricación, acondicionamiento y estabilización de una familia aditivos base óxidos de sodio, potasio, boro, silicio, zinc, calcio, entre otros, preparados por métodos fisicoquímicos y de síntesis química que forman estructuras nanométricas, reformulados con aditivos defloculantes, secuestrantes y dispersantes que permiten obtener una dispersión o polvo con la capacidad de disminuir la temperatura de sinterizado de un cuerpo cerámico por su alto poder de fundencia, que se maximiza por el uso de la nanotecnología en las estructuras obtenidas, el proceso consiste en la preparación de semillas de nucleación de óxidos metálicos, silicatos y carbonatos mediante un proceso fisicoquímico, y los cuales permiten crecer mediante un proceso químico estructuras de índole nanométrico en un proceso de síntesis química en vía húmeda de óxidos de sodio, boro, silicio, zinc, potasio y calcio. La combinación de estos óxidos permite estructurar elementos de alto poder fundente por su alta área superficial y su composición fisicoquímica. Los aditivos elaborados en la presente invención se estabilizan químicamente con agentes defloculantes, que permiten a los aditivos ser incorporados en el proceso de molienda en medio acuoso del cuerpo cerámico. Las aplicaciones elaboradas con los aditivos de la presente invención permiten disminuir la temperatura de sinterizado de un cuerpo rojo desde 1150°C hasta 1000°C y en cuerpos porcelánicos gres de 1180°C a 1050°C, con el uso de 0.2 a 5 % del aditivo, o bien incrementando la velocidad del tratamiento térmico hasta en un 20%, pudiendo ser utilizado en la fabricación de sanitarios, piezas de moldeo, componentes para herramientas, revestimientos, cenefas, esmaltes, engobes y otros componentes cerámicos. La presente invención propone varias formulaciones de aditivos nanoestructurados con propiedades fundentes de alto desempeño, que permiten optimizar y uniformizar el proceso de sinterizado y mejorar las propiedades mecánicas del cuerpo cerámico. Así mismo propone diferentes métodos de aplicación del aditivo de formulaciones cerámicas.
MX2017004430A 2017-04-05 2017-04-05 Método de preparación de aditivos de óxidos metálicos de tamaño nanométrico que reducen la temperatura de sinterizado y/o incrementan la productividad en la fabricación de piezas cerámicas, mejorando propiedades mecánicas sin afectar las propiedades de gresificación de cuerpos cerámicos, losetas o revestimientos. MX389231B (es)

Priority Applications (6)

Application Number Priority Date Filing Date Title
MX2017004430A MX389231B (es) 2017-04-05 2017-04-05 Método de preparación de aditivos de óxidos metálicos de tamaño nanométrico que reducen la temperatura de sinterizado y/o incrementan la productividad en la fabricación de piezas cerámicas, mejorando propiedades mecánicas sin afectar las propiedades de gresificación de cuerpos cerámicos, losetas o revestimientos.
BR112019020789-9A BR112019020789B1 (pt) 2017-04-05 2017-07-20 Aditivos nanoestruturados de baixo ponto de fusão e seus processos de preparação
EP17904875.6A EP3608299A4 (en) 2017-04-05 2017-07-20 PROCESS FOR THE PREPARATION OF METAL OXIDE ADDITIVES OF NANOMETRIC SIZE REDUCING SINTER TEMPERATURE AND / OR INCREASING PRODUCTIVITY IN THE MANUFACTURING OF CERAMIC PARTS, IMPROVING MECHANICAL PROPERTIES WITHOUT AFFECTING BODY PROPRIETATIONS, VESSELS OR COATINGS
PCT/MX2017/000081 WO2018186729A1 (es) 2017-04-05 2017-07-20 Método para la preparación de aditivos de óxidos metálicos de tamaño nanométrico que reducen la temperatura de sinterizado y/o incrementan la productividad en la fabricación de piezas cerámicas, mejorando propiedades mecánicas sin afectar las propiedades de gresificación de cuerpos cerámicos, losetas o revestimientos
US16/603,131 US11339098B2 (en) 2017-04-05 2017-07-20 Preparation method of nanometric size metal oxide additives that reduce the temperature of sinterized and/or increase productivity in the manufacture of ceramic parts, improving mechanical properties without affecting the gresification properties of ceramic bodies, tiles or coatings
CONC2019/0011965A CO2019011965A2 (es) 2017-04-05 2019-10-25 Método para la preparación de aditivos de óxidos metálicos de tamaño nanométrico que reducen la temperatura de sinterizado y/o incrementan la productividad en la fabricación de piezas cerámicas, mejorando propiedades mecánicas sin afectar las propiedades de gresificación de cuerpos cerámicos, losetas o revestimientos

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2017004430A MX389231B (es) 2017-04-05 2017-04-05 Método de preparación de aditivos de óxidos metálicos de tamaño nanométrico que reducen la temperatura de sinterizado y/o incrementan la productividad en la fabricación de piezas cerámicas, mejorando propiedades mecánicas sin afectar las propiedades de gresificación de cuerpos cerámicos, losetas o revestimientos.

Publications (2)

Publication Number Publication Date
MX2017004430A MX2017004430A (es) 2018-11-09
MX389231B true MX389231B (es) 2025-03-20

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MX2017004430A MX389231B (es) 2017-04-05 2017-04-05 Método de preparación de aditivos de óxidos metálicos de tamaño nanométrico que reducen la temperatura de sinterizado y/o incrementan la productividad en la fabricación de piezas cerámicas, mejorando propiedades mecánicas sin afectar las propiedades de gresificación de cuerpos cerámicos, losetas o revestimientos.

Country Status (6)

Country Link
US (1) US11339098B2 (es)
EP (1) EP3608299A4 (es)
BR (1) BR112019020789B1 (es)
CO (1) CO2019011965A2 (es)
MX (1) MX389231B (es)
WO (1) WO2018186729A1 (es)

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CN104446495B (zh) * 2014-09-30 2016-10-05 丁晓瑞 一种氮化硅陶瓷材料及其制备方法
CN104609865A (zh) * 2015-02-09 2015-05-13 广东工业大学 一种氮化硅基导电陶瓷的制备方法及氮化硅基导电陶瓷刀具的成型方法
CN105837226B (zh) * 2016-03-22 2019-08-16 上海泛联科技股份有限公司 一种氮化硅陶瓷摩擦片及其制备方法与应用

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