MX380447B - Conversión catalítica de alcoholes a hidrocarburos con bajo contenido de benceno. - Google Patents

Conversión catalítica de alcoholes a hidrocarburos con bajo contenido de benceno.

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Publication number
MX380447B
MX380447B MX2015011706A MX2015011706A MX380447B MX 380447 B MX380447 B MX 380447B MX 2015011706 A MX2015011706 A MX 2015011706A MX 2015011706 A MX2015011706 A MX 2015011706A MX 380447 B MX380447 B MX 380447B
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MX
Mexico
Prior art keywords
alcohol
converting
hydrocarbon fraction
benzene
catalyst
Prior art date
Application number
MX2015011706A
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English (en)
Other versions
MX2015011706A (es
Inventor
Brian H Davison
Chaitanya K Narula
Martin Keller
Original Assignee
Ut Battelle Llc
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Publication date
Application filed by Ut Battelle Llc filed Critical Ut Battelle Llc
Publication of MX2015011706A publication Critical patent/MX2015011706A/es
Publication of MX380447B publication Critical patent/MX380447B/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
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    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • B01J29/80—Mixtures of different zeolites
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
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    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
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    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
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Abstract

Un método para convertir un alcohol en una fracción de hidrocarburo que tiene un contenido de benceno rebajado, que comprende: convertir dicho alcohol a una fracción de hidrocarburo que entra en contacto con dicho alcohol, en condiciones adecuadas para la conversión de dicho alcohol a dicha fracción de hidrocarburo, con un catalizador de zeolita cargado con metal catalíticamente activo para la conversión de dicho alcohol a dicha fracción de hidrocarburo, y entrar en contacto dicha fracción de hidrocarburo con un catalizador de alquilación de benceno, bajo condiciones adecuadas para la alquilación de benceno, para formar el producto benceno alquilado en dicha fracción de hidrocarburo. También se describe una composición de catalizador útil en el método, que comprende una mezcla de (i) un catalizador de zeolita cargado con metal catalíticamente activo para la conversión de dicho alcohol a dicho hidrocarburo, y (ii) un catalizador de alquilación de benceno, en donde (i) y (ii) pueden estar en un estado mezclado o separado. También se describe un reactor para alojar el catalizador y la modalidad de la reacción.
MX2015011706A 2013-03-06 2014-03-04 Conversión catalítica de alcoholes a hidrocarburos con bajo contenido de benceno. MX380447B (es)

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US13/787,112 US9434658B2 (en) 2013-03-06 2013-03-06 Catalytic conversion of alcohols to hydrocarbons with low benzene content
PCT/US2014/020154 WO2014137991A1 (en) 2013-03-06 2014-03-04 Catalytic conversion of alcohols to hydrocarbons with low benzene content

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EP2964380A1 (en) 2016-01-13
CA2903389A1 (en) 2014-09-12
BR112015021621B1 (pt) 2024-02-15
EP2964380A4 (en) 2017-03-29
MX2015011706A (es) 2016-01-15
CN105050713A (zh) 2015-11-11
EP2964380B1 (en) 2020-05-06
US20140256010A1 (en) 2014-09-11
CA2903389C (en) 2021-01-19
BR112015021621A2 (pt) 2017-07-18
US20140322781A1 (en) 2014-10-30
US9278892B2 (en) 2016-03-08
CN105050713B (zh) 2019-01-29
HK1215227A1 (zh) 2016-08-19
US9434658B2 (en) 2016-09-06
WO2014137991A1 (en) 2014-09-12

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