MX2015011706A - Conversion catalitica de alcoholes a hidrocarburos con bajo contenido de benceno. - Google Patents
Conversion catalitica de alcoholes a hidrocarburos con bajo contenido de benceno.Info
- Publication number
- MX2015011706A MX2015011706A MX2015011706A MX2015011706A MX2015011706A MX 2015011706 A MX2015011706 A MX 2015011706A MX 2015011706 A MX2015011706 A MX 2015011706A MX 2015011706 A MX2015011706 A MX 2015011706A MX 2015011706 A MX2015011706 A MX 2015011706A
- Authority
- MX
- Mexico
- Prior art keywords
- alcohol
- converting
- hydrocarbon fraction
- benzene
- catalyst
- Prior art date
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title abstract 15
- 229930195733 hydrocarbon Natural products 0.000 title abstract 8
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 8
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- 150000001298 alcohols Chemical class 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 6
- 238000000034 method Methods 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 230000029936 alkylation Effects 0.000 abstract 2
- 238000005804 alkylation reaction Methods 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- 230000002152 alkylating effect Effects 0.000 abstract 1
- 150000001555 benzenes Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
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- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
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- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
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- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un método para convertir un alcohol en una fracción de hidrocarburo que tiene un contenido de benceno rebajado, que comprende: convertir dicho alcohol a una fracción de hidrocarburo que entra en contacto con dicho alcohol, en condiciones adecuadas para la conversión de dicho alcohol a dicha fracción de hidrocarburo, con un catalizador de zeolita cargado con metal catalíticamente activo para la conversión de dicho alcohol a dicha fracción de hidrocarburo, y entrar en contacto dicha fracción de hidrocarburo con un catalizador de alquilación de benceno, bajo condiciones adecuadas para la alquilación de benceno, para formar el producto benceno alquilado en dicha fracción de hidrocarburo. También se describe una composición de catalizador útil en el método, que comprende una mezcla de (i) un catalizador de zeolita cargado con metal catalíticamente activo para la conversión de dicho alcohol a dicho hidrocarburo, y (ii) un catalizador de alquilación de benceno, en donde (i) y (ii) pueden estar en un estado mezclado o separado. También se describe un reactor para alojar el catalizador y la modalidad de la reacción.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US13/787,112 US9434658B2 (en) | 2013-03-06 | 2013-03-06 | Catalytic conversion of alcohols to hydrocarbons with low benzene content |
PCT/US2014/020154 WO2014137991A1 (en) | 2013-03-06 | 2014-03-04 | Catalytic conversion of alcohols to hydrocarbons with low benzene content |
Publications (1)
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MX2015011706A true MX2015011706A (es) | 2016-01-15 |
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MX2015011706A MX2015011706A (es) | 2013-03-06 | 2014-03-04 | Conversion catalitica de alcoholes a hidrocarburos con bajo contenido de benceno. |
Country Status (9)
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US (2) | US9434658B2 (es) |
EP (1) | EP2964380B1 (es) |
CN (1) | CN105050713B (es) |
BR (1) | BR112015021621B1 (es) |
CA (1) | CA2903389C (es) |
HK (1) | HK1215227A1 (es) |
HU (1) | HUE048948T2 (es) |
MX (1) | MX2015011706A (es) |
WO (1) | WO2014137991A1 (es) |
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BR112013032184B1 (pt) * | 2011-06-15 | 2021-05-25 | Ut-Battelle, Llc | métodos para converter um álcool em um hidrocarboneto, em um produto de hidrocarboneto e em uma mistura de compostos de hidrocarboneto |
RU2558955C1 (ru) | 2014-08-12 | 2015-08-10 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" | Способ получения концентрата ароматических углеводородов из жидких углеводородных фракций и установка для его осуществления |
RU2544017C1 (ru) | 2014-01-28 | 2015-03-10 | Ольга Васильевна Малова | Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей |
RU2544241C1 (ru) | 2014-01-22 | 2015-03-20 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" | Способ получения ароматических углеводородов из природного газа и установка для его осуществления |
RU2550354C1 (ru) | 2014-03-28 | 2015-05-10 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" | Способ получения концентрата ароматических углеводородов из легких алифатических углеводородов и установка для его осуществления |
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-
2013
- 2013-03-06 US US13/787,112 patent/US9434658B2/en active Active
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2014
- 2014-03-04 WO PCT/US2014/020154 patent/WO2014137991A1/en active Application Filing
- 2014-03-04 CA CA2903389A patent/CA2903389C/en active Active
- 2014-03-04 HU HUE14761233A patent/HUE048948T2/hu unknown
- 2014-03-04 BR BR112015021621-8A patent/BR112015021621B1/pt active IP Right Grant
- 2014-03-04 MX MX2015011706A patent/MX2015011706A/es unknown
- 2014-03-04 CN CN201480012377.7A patent/CN105050713B/zh active Active
- 2014-03-04 EP EP14761233.7A patent/EP2964380B1/en active Active
- 2014-04-28 US US14/263,257 patent/US9278892B2/en active Active
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- 2016-03-17 HK HK16103161.9A patent/HK1215227A1/zh unknown
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EP2964380B1 (en) | 2020-05-06 |
BR112015021621B1 (pt) | 2024-02-15 |
CA2903389C (en) | 2021-01-19 |
BR112015021621A2 (pt) | 2017-07-18 |
US20140322781A1 (en) | 2014-10-30 |
US9434658B2 (en) | 2016-09-06 |
EP2964380A1 (en) | 2016-01-13 |
EP2964380A4 (en) | 2017-03-29 |
HK1215227A1 (zh) | 2016-08-19 |
CA2903389A1 (en) | 2014-09-12 |
CN105050713B (zh) | 2019-01-29 |
HUE048948T2 (hu) | 2020-09-28 |
WO2014137991A1 (en) | 2014-09-12 |
US9278892B2 (en) | 2016-03-08 |
CN105050713A (zh) | 2015-11-11 |
US20140256010A1 (en) | 2014-09-11 |
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