MX348336B - Conversion catalitica zeolitica de alcoholes a hidrocarburos. - Google Patents

Conversion catalitica zeolitica de alcoholes a hidrocarburos.

Info

Publication number
MX348336B
MX348336B MX2013014804A MX2013014804A MX348336B MX 348336 B MX348336 B MX 348336B MX 2013014804 A MX2013014804 A MX 2013014804A MX 2013014804 A MX2013014804 A MX 2013014804A MX 348336 B MX348336 B MX 348336B
Authority
MX
Mexico
Prior art keywords
hydrocarbons
alcohols
catalytic conversion
alcohol
metal
Prior art date
Application number
MX2013014804A
Other languages
English (en)
Other versions
MX2013014804A (es
Inventor
Keller Martin
K Narula Chaitanya
H Davison Brian
Original Assignee
Ut Battelle Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ut Battelle Llc filed Critical Ut Battelle Llc
Publication of MX2013014804A publication Critical patent/MX2013014804A/es
Publication of MX348336B publication Critical patent/MX348336B/es

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/40—
    • B01J35/56—
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    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
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    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
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    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
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    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
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    • C12P7/06—Ethanol, i.e. non-beverage
    • C12P7/08—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
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    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C12P7/08—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate
    • C12P7/10—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate substrate containing cellulosic material
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/16—Butanols
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/66—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
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    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7869—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7892—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

Se describe un método para convertir un alcohol a un hidrocarburo, el método comprende poner en contacto dicho alcohol con un catalizador de zeolita cargado de metal a una temperatura de por lo menos 100°C y hasta 550°C, donde dicho alcohol se puede producir mediante un proceso de fermentación, dicho metal es un ion de metal positivamente cargado, y dicho catalizador de zeolita cargado de metal es catalíticamente activo para convertir dicho alcohol a dicho hidrocarburo.
MX2013014804A 2011-06-15 2012-06-14 Conversion catalitica zeolitica de alcoholes a hidrocarburos. MX348336B (es)

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US201161497256P 2011-06-15 2011-06-15
PCT/US2012/042399 WO2012174205A1 (en) 2011-06-15 2012-06-14 Zeolitic catalytic conversion of alcohols to hydrocarbons

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EP (1) EP2720990B1 (es)
CN (1) CN103827058B (es)
BR (1) BR112013032184B1 (es)
CA (1) CA2839399C (es)
HU (1) HUE037515T2 (es)
MX (1) MX348336B (es)
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Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2839399C (en) 2011-06-15 2021-03-23 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to hydrocarbons
US9296665B2 (en) * 2012-12-13 2016-03-29 Pioneer Energy Inc. Synthesis of drop-in liquid fuels and chemicals from methanol, ethanol or syngas using mixed catalysts
US9434658B2 (en) 2013-03-06 2016-09-06 Ut-Battelle, Llc Catalytic conversion of alcohols to hydrocarbons with low benzene content
WO2014171688A1 (ko) * 2013-04-18 2014-10-23 롯데케미칼 주식회사 에너지 절감형 에탄올 탈수 촉매 및 이를 이용한 에틸렌 제조방법
KR101587345B1 (ko) * 2014-04-10 2016-01-20 롯데케미칼 주식회사 에틸렌 제조를 위한 에탄올 탈수 촉매 및 이를 이용한 에틸렌 제조방법
CN103272634B (zh) * 2013-05-28 2015-07-22 常州大学 纳米金属负载型分子筛催化剂的制备方法
MX2015017980A (es) 2013-07-02 2016-08-05 Ut Battelle Llc Conversion catalitica de alcohol con al menos tres atomos de carbono a una mezcla de hidrocarburos.
RU2558955C1 (ru) 2014-08-12 2015-08-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из жидких углеводородных фракций и установка для его осуществления
RU2544241C1 (ru) 2014-01-22 2015-03-20 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения ароматических углеводородов из природного газа и установка для его осуществления
RU2544017C1 (ru) 2014-01-28 2015-03-10 Ольга Васильевна Малова Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
RU2550354C1 (ru) 2014-03-28 2015-05-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из легких алифатических углеводородов и установка для его осуществления
US20160160133A1 (en) * 2014-12-09 2016-06-09 Phillips 66 Company Ethanol to fuels in a catalytic cracking unit stripper
US20160340594A1 (en) * 2014-12-09 2016-11-24 Phillips 66 Company Systems for ethanol to fuels in a catalytic cracking unit stripper
US9732283B2 (en) 2014-12-26 2017-08-15 Phillips 66 Company System for integrated catalytic cracking with ethanol conversion to fuel
RU2594564C1 (ru) * 2015-05-18 2016-08-20 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Катализатор и способ конверсии этанола, метанола или их смеси
CN106316734A (zh) * 2015-06-19 2017-01-11 中国石油化工股份有限公司 醇类化合物芳构化为芳烃的方法
CN106316733B (zh) * 2015-06-19 2019-01-25 中国石油化工股份有限公司 醇类化合物芳构化制芳烃的方法
RU2597269C1 (ru) * 2015-08-18 2016-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Тверской государственный технический университет" (ТвГТУ) Способ получения гетерогенного катализатора синтеза углеводородов из метанола
AU2016374791B2 (en) * 2015-12-22 2020-08-20 Eco-Oil Miljöbränslen I Sverige AB Conversion of alcohols to hydrocarbons using a dual catalyst system comprising basic oxide on mixed oxide or mesoporous carrier and etched metal loaded zeolite catalyst
WO2017155424A1 (en) 2016-03-09 2017-09-14 Limited Liability Company "New Gas Technologies-Synthesis" (Llc "Ngt-Synthesis") Method and plant for producing high-octane gasolines
US10696606B2 (en) * 2016-06-09 2020-06-30 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to hydrocarbon fractions with reduced gaseous hydrocarbon content
CN107008489B (zh) * 2017-03-09 2020-04-28 华南理工大学 用于木质素加氢解聚的分子筛负载钒基催化剂及其制备方法
US11053181B2 (en) 2018-08-09 2021-07-06 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to olefins
CN111040799A (zh) * 2018-10-11 2020-04-21 中国石油化工股份有限公司 一种含氧化合物的催化转化方法
US11292753B2 (en) * 2019-10-30 2022-04-05 Ut-Battelle, Llc Method for alcohol upgrading to jet, diesel, gasoline, and valuable co-products
US11691129B2 (en) 2021-01-27 2023-07-04 Ut-Battelle, Llc Direct catalytic conversion of alcohols to olefins of higher carbon number with reduced ethylene production
US20230183079A1 (en) * 2021-12-10 2023-06-15 Ut-Battelle, Llc Metal-zeolite compositions prepared by mechanochemical synthesis, and methods of use
FR3135265A1 (fr) 2022-05-06 2023-11-10 Totalenergies Onetech Procédé d’obtention d’hydrocarbures, et installation associée
FR3135264A1 (fr) 2022-05-06 2023-11-10 Totalenergies Onetech Procédé de fabrication d’un carburéacteur, carburéacteur et installation associés
FR3135263A1 (fr) 2022-05-06 2023-11-10 Totalenergies Onetech Procédé de fabrication d’un carburéacteur comprenant une étape de conversion d’un flux d’alcool dans un lit fluidisé, carburéacteur et installation associés

Family Cites Families (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3998898A (en) * 1973-08-09 1976-12-21 Mobil Oil Corporation Manufacture of gasoline
US3894107A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of alcohols, mercaptans, sulfides, halides and/or amines
US3899544A (en) 1974-03-28 1975-08-12 Mobil Oil Corp Conversion of alcohols and ethers to hydrocarbons
US4058576A (en) 1974-08-09 1977-11-15 Mobil Oil Corporation Conversion of methanol to gasoline components
US4138440A (en) 1974-08-14 1979-02-06 Mobil Oil Corporation Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst
US4071573A (en) 1974-09-23 1978-01-31 Mobil Oil Corporation Prolonging zeolite catalyst life in methanol conversion to gasoline by disposing of exothermic reaction heat
US3928483A (en) 1974-09-23 1975-12-23 Mobil Oil Corp Production of gasoline hydrocarbons
US3931349A (en) 1974-09-23 1976-01-06 Mobil Oil Corporation Conversion of methanol to gasoline components
US3969427A (en) 1974-11-19 1976-07-13 Mobil Oil Corporation Conversion of alcohols and/or ethers to hydrocarbons
US3998899A (en) 1975-08-06 1976-12-21 Mobil Oil Corporation Method for producing gasoline from methanol
US4025571A (en) * 1976-05-12 1977-05-24 Mobil Oil Corporation Manufacture of hydrocarbons
US4035430A (en) 1976-07-26 1977-07-12 Mobil Oil Corporation Conversion of methanol to gasoline product
US4148835A (en) 1978-04-14 1979-04-10 Mobil Oil Corporation Hydrocarbon manufacture from alcohols
US4278565A (en) 1979-03-14 1981-07-14 Mobil Oil Corporation Hydrocarbon manufacture from alcohols
US4289606A (en) 1979-05-31 1981-09-15 Exxon Research & Engineering Co. Hydrocarbon cracking with mixture of zeolites Y and ZSM-5
US4338475A (en) 1979-10-30 1982-07-06 Mobil Oil Corporation Converting alcohols to hydrocarbons
US4423274A (en) 1980-10-03 1983-12-27 Mobil Oil Corporation Method for converting alcohols to hydrocarbons
US4690903A (en) * 1981-02-02 1987-09-01 Mobil Oil Corporation Process for preparing organic fuels and chemicals from biomass
CA1186345A (en) * 1981-12-14 1985-04-30 Martin M.Y. Chang Hydrocarbon production
US4427789A (en) 1982-03-08 1984-01-24 Mobil Oil Corporation Activation of zeolites
ZA834412B (en) 1982-07-20 1985-02-27 Mobil Oil Corp Two-stage,zeolite catalyzed process for the conversion of alcohols to hydrocarbons
DE3228269A1 (de) 1982-07-29 1984-02-02 Degussa Ag, 6000 Frankfurt Katalysator fuer die konvertierung von alkoholen und/oder aliphatischen aethern zu ungesaettigten kohlenwasserstoffen und das verfahren zu dessen herstellung
US4404414A (en) 1982-09-28 1983-09-13 Mobil Oil Corporation Conversion of methanol to gasoline
US4499327A (en) 1982-10-04 1985-02-12 Union Carbide Corporation Production of light olefins
EP0130368A1 (en) 1983-05-31 1985-01-09 Union Carbide Corporation Conversion of methanol to hydrocarbons
US4608355A (en) * 1983-08-10 1986-08-26 Mobil Oil Corporation Hydrocarbon conversion catalyst
US4596704A (en) 1983-11-22 1986-06-24 Mobil Oil Corporation Activation of zeolites
US4524234A (en) 1984-10-19 1985-06-18 Union Carbide Corporation Production of hydrocarbons with aluminophosphate molecular sieves
DE3532748A1 (de) 1985-09-13 1987-03-19 Degussa Templatverbindungen, ihre herstellung und verwendung
US4788369A (en) 1985-12-31 1988-11-29 Mobil Oil Corporation Conversion of methanol to gasoline
US4788042A (en) 1985-12-31 1988-11-29 Mobil Oil Corporation System for conversion of methanol to gasoline
LU86284A1 (fr) * 1986-01-30 1987-09-03 Belge Etat Procede d'obtention d'ethylene a partir d'ethanol
US4822939A (en) * 1986-07-11 1989-04-18 Mobil Oil Corporation Process for the conversion of lower aliphatic oxygenates to olefins and aromatics with gallium containing ZSM-5 catalyst
US4849093A (en) 1987-02-02 1989-07-18 Union Oil Company Of California Catalytic aromatic saturation of hydrocarbons
US5314665A (en) 1987-07-27 1994-05-24 Nissan Motor Co., Ltd. Catalytic converter
US4851606A (en) * 1988-04-25 1989-07-25 Mobil Oil Corporation Control of waste water chemical oxygen demand in an oxygenate to hydrocarbon conversion process
US5045287A (en) 1988-07-25 1991-09-03 Mobil Oil Corporation Multireactor system for conversion of methanol to gasoline and distillate
WO1990012855A1 (en) 1989-04-24 1990-11-01 Mobil Oil Corporation Conversion of alcohols to ether-rich gasoline
US5041690A (en) 1989-04-28 1991-08-20 Mobil Oil Corporation Conversion of alcohols to ether-rich gasoline
US5177279A (en) 1990-10-23 1993-01-05 Mobil Oil Corporation Integrated process for converting methanol to gasoline and distillates
EP0688308B1 (en) 1993-03-08 2000-04-05 Mobil Oil Corporation Benzene reduction in gasoline by alkylation with higher olefins
RU2082500C1 (ru) 1994-08-03 1997-06-27 Акционерное общество "Ангарская нефтехимическая компания" Катализатор гидродепарафинизации углеводородных дистиллятов
US5773676A (en) * 1996-08-06 1998-06-30 Phillips Petroleum Company Process for producing olefins and aromatics from non-aromatics
JPH11217343A (ja) 1998-01-30 1999-08-10 Sangi Co Ltd 化学工業原料及びハイオク燃料の合成法
US6046373A (en) * 1998-04-29 2000-04-04 Exxon Chemical Patents Inc. Catalytic conversion of oxygenates to olefins
RU2163624C2 (ru) * 1998-11-25 2001-02-27 Научно-инженерный центр "Цеосит" Объединенного института катализа СО РАН Способ получения высокооктановых бензиновых фракций и ароматических углеводородов
US6239057B1 (en) 1999-01-15 2001-05-29 Uop Llc Catalyst for the conversion of low carbon number aliphatic hydrocarbons to higher carbon number hydrocarbons, process for preparing the catalyst and process using the catalyst
US7393990B2 (en) * 2001-06-26 2008-07-01 Exxonmobil Chemical Patents Inc. Production of light olefins from oxygenate using framework gallium-containing medium pore molecular sieve
US6642425B2 (en) 2002-03-05 2003-11-04 Sasol North America Inc. Reactive distillation process for the alkylation of aromatic hydrocarbons
US7442425B2 (en) 2003-09-30 2008-10-28 Corning Incorporated High porosity honeycomb and method
JP2005118700A (ja) 2003-10-17 2005-05-12 Ngk Insulators Ltd ハニカム構造体、及び触媒コンバータ
US7906304B2 (en) * 2005-04-05 2011-03-15 Geosynfuels, Llc Method and bioreactor for producing synfuel from carbonaceous material
RU2428455C2 (ru) * 2005-08-18 2011-09-10 Хальдор Топсеэ А/С Способ превращения трудно конвертируемых оксигенатов в бензин
US7678955B2 (en) 2005-10-13 2010-03-16 Exxonmobil Chemical Patents Inc Porous composite materials having micro and meso/macroporosity
EP1969100B1 (en) * 2005-12-12 2019-02-27 Neste Oyj Process for producing a branched hydrocarbon component
US7425659B2 (en) 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
CA2539231C (en) 2006-03-10 2013-08-13 Baojian Shen Catalyst composition for treating heavy feedstocks
US7872054B2 (en) 2006-03-24 2011-01-18 Wisconsin Alumni Research Foundation Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions
BRPI0716009A2 (pt) * 2006-10-16 2014-11-18 Nat Inst Of Advanced Ind Scien Aparelho e processo para produção de etanol
US7829751B2 (en) 2006-10-27 2010-11-09 Exxonmobil Chemical Patents, Inc. Processes for converting oxygenates to olefins using aluminosilicate catalysts
WO2008069984A2 (en) * 2006-12-01 2008-06-12 E. I. Du Pont De Nemours And Company Production of butenes and derivatives thereform from dry ethanol
US20080132730A1 (en) 2006-12-01 2008-06-05 Leo Ernest Manzer Process for making butenes from dry 2-butanol
JP2010532419A (ja) 2007-06-29 2010-10-07 エナジー・アンド・エンヴァイロンメンタル・リサーチ・センター・ファウンデイション 別々に生成したブレンドストックに由来する航空機グレードのケロシン
KR101548755B1 (ko) 2007-08-13 2015-08-31 사우디 베이식 인더스트리즈 코포레이션 지방족 산소화물을 방향족화물로 변환시키는 방법
US20100018503A1 (en) 2008-07-22 2010-01-28 Perry Robert B Upper guide system for solenoid actuated fuel injectors
MX2011011037A (es) 2009-04-20 2012-02-21 Qteros Inc Composiciones y metodos para la fermentacion de biomasa.
WO2011078909A1 (en) 2009-12-22 2011-06-30 Conocophillips Company Conversion of carbohydrates to hydrocarbons
CN103153920B (zh) * 2010-08-03 2015-04-15 道达尔研究技术弗吕公司 由异丁醇制造烯烃的方法
CN103153921A (zh) * 2010-08-03 2013-06-12 道达尔研究技术弗吕公司 由甲醇和异丁醇制造烯烃的方法
CA2839399C (en) 2011-06-15 2021-03-23 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to hydrocarbons
US9616417B2 (en) * 2011-07-22 2017-04-11 Haldor Topsoe A/S Catalyst for the conversion of oxygenates to olefins and a process for preparing said catalyst
US9296665B2 (en) * 2012-12-13 2016-03-29 Pioneer Energy Inc. Synthesis of drop-in liquid fuels and chemicals from methanol, ethanol or syngas using mixed catalysts
US9434658B2 (en) * 2013-03-06 2016-09-06 Ut-Battelle, Llc Catalytic conversion of alcohols to hydrocarbons with low benzene content
MX2015017980A (es) 2013-07-02 2016-08-05 Ut Battelle Llc Conversion catalitica de alcohol con al menos tres atomos de carbono a una mezcla de hidrocarburos.

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US20180187091A1 (en) 2018-07-05
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US20140100404A1 (en) 2014-04-10
US9938467B2 (en) 2018-04-10
EP2720990A4 (en) 2014-12-24
BR112013032184B1 (pt) 2021-05-25
US20240034937A1 (en) 2024-02-01
US20170066974A1 (en) 2017-03-09
EP2720990B1 (en) 2018-03-07
MX2013014804A (es) 2014-06-04
BR112013032184A2 (pt) 2019-09-24
EP2720990A1 (en) 2014-04-23
US9533921B2 (en) 2017-01-03
US20140273146A1 (en) 2014-09-18
CA2839399A1 (en) 2012-12-20
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US11773333B2 (en) 2023-10-03

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