EA201291227A1 - Катализатор ароматизации метана, способ изготовления и способ использования катализатора - Google Patents
Катализатор ароматизации метана, способ изготовления и способ использования катализатораInfo
- Publication number
- EA201291227A1 EA201291227A1 EA201291227A EA201291227A EA201291227A1 EA 201291227 A1 EA201291227 A1 EA 201291227A1 EA 201291227 A EA201291227 A EA 201291227A EA 201291227 A EA201291227 A EA 201291227A EA 201291227 A1 EA201291227 A1 EA 201291227A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalyst
- methane
- manufacturing
- metal
- aromation
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000002184 metal Substances 0.000 abstract 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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- B01J37/0201—Impregnation
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- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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Abstract
В настоящем документе описан катализатор конверсии метана в ароматические углеводороды. Катализатор содержит активный металл или его соединение и неорганический оксидный носитель, где активный металл добавляют к носителю в форме оксалата металла. Полученный из оксалата металла катализатор проявляет превосходную активность при конверсии обогащенного метаном исходного материала в ароматические продукты по сравнению с катализаторами, полученными из не содержащих оксалаты металлов предшественников. Также описаны способ изготовления катализатора и способ использования катализатора.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US33399510P | 2010-05-12 | 2010-05-12 | |
PCT/US2011/036053 WO2011143303A2 (en) | 2010-05-12 | 2011-05-11 | Methane aromatization catalyst, method of making and method of using the catalyst |
Publications (1)
Publication Number | Publication Date |
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EA201291227A1 true EA201291227A1 (ru) | 2013-05-30 |
Family
ID=44914954
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EA201291227A EA201291227A1 (ru) | 2010-05-12 | 2011-05-11 | Катализатор ароматизации метана, способ изготовления и способ использования катализатора |
Country Status (6)
Country | Link |
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US (2) | US9079169B2 (ru) |
CN (1) | CN102883811B (ru) |
BR (1) | BR112012028770A2 (ru) |
EA (1) | EA201291227A1 (ru) |
SG (1) | SG185117A1 (ru) |
WO (1) | WO2011143303A2 (ru) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2825185A1 (en) * | 2011-01-26 | 2012-08-02 | Shell Internationale Research Maarschappij B.V. | A zinc-containing methane aromatization catalyst, method of making and method of using the catalyst |
CN102921453B (zh) * | 2012-10-25 | 2014-10-29 | 浙江工业大学 | 一种低温制备甲烷无氧芳构化催化剂的方法 |
CN103934016B (zh) * | 2013-01-23 | 2016-08-17 | 中国石油化工股份有限公司 | Mo/分子筛负载型催化剂制备方法 |
RU2525117C1 (ru) * | 2013-03-28 | 2014-08-10 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Способ активации молибден-цеолитного катализатора ароматизации метана |
CN103736517B (zh) * | 2013-12-27 | 2016-03-23 | 陕西延长石油(集团)有限责任公司碳氢高效利用技术研究中心 | 一种甲烷制芳烃催化剂的活化方法 |
CN103736518B (zh) * | 2013-12-27 | 2016-07-13 | 西北大学 | 一种甲烷制芳烃催化剂在循环流化反应系统中的活化方法 |
KR101985861B1 (ko) | 2017-08-21 | 2019-06-04 | 서울대학교산학협력단 | 메탄 및 프로판 공동 반응물의 직접 탈수소방향족화 반응을 위한 중형기공성 hzsm-11에 담지된 금속 산화물 촉매의 제조 방법 및 상기 촉매를 이용한 btx 제조 방법 |
WO2019211727A1 (en) * | 2018-04-30 | 2019-11-07 | Sabic Global Technologies B.V. | Process for activating an aromatizaton catalyst |
CN115672387B (zh) * | 2022-10-26 | 2024-03-19 | 中国石油大学(北京) | 一种甲烷无氧芳构化催化剂及其制备方法和应用 |
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EP2276566A1 (de) * | 2008-04-08 | 2011-01-26 | Basf Se | Katalysator zur dehydroaromatisierung von methan und methanhaltigen gemischen |
US20110160508A1 (en) * | 2008-05-21 | 2011-06-30 | Ding Ma | Production of aromatics from methane |
JP5564769B2 (ja) * | 2008-08-12 | 2014-08-06 | 株式会社明電舎 | 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 |
-
2011
- 2011-05-11 US US13/105,499 patent/US9079169B2/en active Active
- 2011-05-11 CN CN201180023495.4A patent/CN102883811B/zh active Active
- 2011-05-11 EA EA201291227A patent/EA201291227A1/ru unknown
- 2011-05-11 SG SG2012080602A patent/SG185117A1/en unknown
- 2011-05-11 WO PCT/US2011/036053 patent/WO2011143303A2/en active Application Filing
- 2011-05-11 BR BR112012028770A patent/BR112012028770A2/pt not_active IP Right Cessation
-
2015
- 2015-06-10 US US14/735,447 patent/US20150274610A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US9079169B2 (en) | 2015-07-14 |
US20120123176A1 (en) | 2012-05-17 |
SG185117A1 (en) | 2012-12-28 |
BR112012028770A2 (pt) | 2017-07-11 |
US20150274610A1 (en) | 2015-10-01 |
WO2011143303A3 (en) | 2012-04-12 |
CN102883811A (zh) | 2013-01-16 |
WO2011143303A2 (en) | 2011-11-17 |
CN102883811B (zh) | 2016-05-04 |
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