EA201291227A1 - Катализатор ароматизации метана, способ изготовления и способ использования катализатора - Google Patents

Катализатор ароматизации метана, способ изготовления и способ использования катализатора

Info

Publication number
EA201291227A1
EA201291227A1 EA201291227A EA201291227A EA201291227A1 EA 201291227 A1 EA201291227 A1 EA 201291227A1 EA 201291227 A EA201291227 A EA 201291227A EA 201291227 A EA201291227 A EA 201291227A EA 201291227 A1 EA201291227 A1 EA 201291227A1
Authority
EA
Eurasian Patent Office
Prior art keywords
catalyst
methane
manufacturing
metal
aromation
Prior art date
Application number
EA201291227A
Other languages
English (en)
Inventor
Петер Танев Танев
Армин Др. Де Ланге Оливейра
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of EA201291227A1 publication Critical patent/EA201291227A1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C07C2523/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

В настоящем документе описан катализатор конверсии метана в ароматические углеводороды. Катализатор содержит активный металл или его соединение и неорганический оксидный носитель, где активный металл добавляют к носителю в форме оксалата металла. Полученный из оксалата металла катализатор проявляет превосходную активность при конверсии обогащенного метаном исходного материала в ароматические продукты по сравнению с катализаторами, полученными из не содержащих оксалаты металлов предшественников. Также описаны способ изготовления катализатора и способ использования катализатора.
EA201291227A 2010-05-12 2011-05-11 Катализатор ароматизации метана, способ изготовления и способ использования катализатора EA201291227A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33399510P 2010-05-12 2010-05-12
PCT/US2011/036053 WO2011143303A2 (en) 2010-05-12 2011-05-11 Methane aromatization catalyst, method of making and method of using the catalyst

Publications (1)

Publication Number Publication Date
EA201291227A1 true EA201291227A1 (ru) 2013-05-30

Family

ID=44914954

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201291227A EA201291227A1 (ru) 2010-05-12 2011-05-11 Катализатор ароматизации метана, способ изготовления и способ использования катализатора

Country Status (6)

Country Link
US (2) US9079169B2 (ru)
CN (1) CN102883811B (ru)
BR (1) BR112012028770A2 (ru)
EA (1) EA201291227A1 (ru)
SG (1) SG185117A1 (ru)
WO (1) WO2011143303A2 (ru)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2825185A1 (en) * 2011-01-26 2012-08-02 Shell Internationale Research Maarschappij B.V. A zinc-containing methane aromatization catalyst, method of making and method of using the catalyst
CN102921453B (zh) * 2012-10-25 2014-10-29 浙江工业大学 一种低温制备甲烷无氧芳构化催化剂的方法
CN103934016B (zh) * 2013-01-23 2016-08-17 中国石油化工股份有限公司 Mo/分子筛负载型催化剂制备方法
RU2525117C1 (ru) * 2013-03-28 2014-08-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ активации молибден-цеолитного катализатора ароматизации метана
CN103736517B (zh) * 2013-12-27 2016-03-23 陕西延长石油（集团）有限责任公司碳氢高效利用技术研究中心 一种甲烷制芳烃催化剂的活化方法
CN103736518B (zh) * 2013-12-27 2016-07-13 西北大学 一种甲烷制芳烃催化剂在循环流化反应系统中的活化方法
KR101985861B1 (ko) 2017-08-21 2019-06-04 서울대학교산학협력단 메탄 및 프로판 공동 반응물의 직접 탈수소방향족화 반응을 위한 중형기공성 hzsm-11에 담지된 금속 산화물 촉매의 제조 방법 및 상기 촉매를 이용한 btx 제조 방법
WO2019211727A1 (en) * 2018-04-30 2019-11-07 Sabic Global Technologies B.V. Process for activating an aromatizaton catalyst
CN115672387B (zh) * 2022-10-26 2024-03-19 中国石油大学(北京) 一种甲烷无氧芳构化催化剂及其制备方法和应用

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2889287A (en) 1954-10-04 1959-06-02 California Research Corp Catalyst and method of catalyst preparation
US3042628A (en) 1957-11-04 1962-07-03 Engelhard Ind Inc Production of alumina and catalyst containing same
US3763256A (en) 1972-06-07 1973-10-02 Universal Oil Prod Co Dimerization of styrene compounds
US3997431A (en) 1972-08-09 1976-12-14 Gulf Research & Development Company Hydrodesulfurization process employing a titanium promoted catalyst
US3912660A (en) * 1973-12-26 1975-10-14 Amax Inc Method for making high surface area molybdenum metal
US4374045A (en) * 1980-05-27 1983-02-15 Mobil Oil Corporation Group IB metal modified zeolite catalysts
GB8726925D0 (en) 1987-11-18 1987-12-23 Shell Int Research Catalyst systems
FR2666249B1 (fr) * 1990-09-03 1994-07-22 Inst Francais Du Petrole Catalyseur et procede d'aromatisation des hydrocarbures contenant 2 a 4 atomes de carbone par molecule.
CN1223403C (zh) * 2000-07-19 2005-10-19 中国石油天然气股份有限公司兰州炼化分公司 一种新基质型抗重金属裂化催化剂及其制备方法
US20050113614A1 (en) 2003-11-24 2005-05-26 Lowe David M. Catalyst and process for selective hydrogenation
US7186871B2 (en) * 2003-12-30 2007-03-06 Saudi Basic Industries Corporation Process for alkane aromatization using platinum-zeolite catalyst
DE102004005997A1 (de) * 2004-02-06 2005-09-01 Hte Ag The High Throughput Experimentation Company Mit Eisenoxid stabilisierter Edelmetall-Katalysator zur Entfernung von Schadstoffen aus Abgasen von Mager-Motoren
JP2007534477A (ja) * 2004-04-26 2007-11-29 ハーテーエー・アクチェンゲゼルシャフト・ザ・ハイ・スループット・イクスペリメンテイション・カンパニー 酸素リッチな排ガスから一酸化炭素および炭化水素を同時除去するための触媒、ならびにその製造方法
US7235507B2 (en) * 2004-08-14 2007-06-26 Sud-Chemie Inc. Catalyst for purifying diesel engine exhaust emissions
WO2006068814A2 (en) 2004-12-22 2006-06-29 Exxonmobil Chemical Patents, Inc. Production of aromatic hydrocarbons from methane
US7683227B2 (en) 2004-12-22 2010-03-23 Exxonmobil Chemical Patents Inc. Production of aromatic hydrocarbons from methane
JP5255845B2 (ja) 2004-12-22 2013-08-07 エクソンモービル・ケミカル・パテンツ・インク メタンからのアルキル化芳香族炭化水素の製造
WO2007123523A1 (en) 2006-04-21 2007-11-01 Exxonmobil Chemical Patents Inc. Production of aromatic hydrocarbons from methane
JP3835765B2 (ja) * 2005-02-10 2006-10-18 勝 市川 芳香族炭化水素を製造する方法
US20090286678A1 (en) 2005-05-02 2009-11-19 Symyx Technologies, Inc. High Surface Area Metal And Metal Oxide Materials and Methods of Making the Same
BRPI0706770A2 (pt) * 2006-01-31 2011-04-05 Asahi Kasei Chemicals Corp catalisador moldado contendo zeólito, e, processo para produzir um composto de hidrocarboneto aromático
RU2459789C2 (ru) 2006-04-21 2012-08-27 Эксонмобил Кемикэл Пейтентс Инк. Получение ароматических соединений из метана
WO2007127026A2 (en) * 2006-04-21 2007-11-08 Exxonmobil Chemical Patents Inc. Production of aromatics from methane
US7893308B2 (en) 2006-08-25 2011-02-22 Exxonmobil Chemical Patents Inc. Production of aromatics from methane
AU2008236524B2 (en) 2007-04-04 2010-11-25 Exxonmobil Chemical Patents Inc. Production of aromatics from methane
WO2009014867A1 (en) 2007-07-24 2009-01-29 Exxonmobil Chemical Patents Inc. Production of aromatics from aliphatics
WO2009020045A1 (ja) 2007-08-03 2009-02-12 Mitsui Chemicals, Inc. 芳香族炭化水素の製造方法
EP2229349B1 (en) 2007-12-05 2012-12-26 Dow Global Technologies LLC Continuous process for oxygen-free conversion of methane
JP5236013B2 (ja) * 2008-01-16 2013-07-17 エイジェンシー フォー サイエンス，テクノロジー アンド リサーチ 触媒の調製及びかかる触媒を使用する方法
AU2009215655B2 (en) * 2008-02-20 2012-03-15 Shell Internationale Research Maatschappij B.V. Process for the conversion of ethane to aromatic hydrocarbons
WO2009106474A2 (en) 2008-02-25 2009-09-03 Olaf Timpe Phase-enriched movtenb mixed oxide catalyst and methods for the preparation thereof
EP2276566A1 (de) * 2008-04-08 2011-01-26 Basf Se Katalysator zur dehydroaromatisierung von methan und methanhaltigen gemischen
US20110160508A1 (en) * 2008-05-21 2011-06-30 Ding Ma Production of aromatics from methane
JP5564769B2 (ja) * 2008-08-12 2014-08-06 株式会社明電舎 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法

Also Published As

Publication number Publication date
US9079169B2 (en) 2015-07-14
US20120123176A1 (en) 2012-05-17
SG185117A1 (en) 2012-12-28
BR112012028770A2 (pt) 2017-07-11
US20150274610A1 (en) 2015-10-01
WO2011143303A3 (en) 2012-04-12
CN102883811A (zh) 2013-01-16
WO2011143303A2 (en) 2011-11-17
CN102883811B (zh) 2016-05-04

Similar Documents

Publication Publication Date Title
EA201291227A1 (ru) Катализатор ароматизации метана, способ изготовления и способ использования катализатора
EA201391757A1 (ru) Катализаторы для нефтехимического катализа
BR112012030016A2 (pt) catalisadores em forma de nanofio
EA201491067A1 (ru) Катализаторы из нанопроволоки и способы их применения и получения
WO2011041184A3 (en) Production of aromatics from methane
EP2579985A4 (en) NOX MEMORY CATALYST WITH IMPROVED HYDROCARBON FLUORATIVE ACTIVITY
PL2611535T3 (pl) Katalizator do silników spalinowych na ubogą mieszankę o ulepszonej aktywności utleniania no
EA201400487A1 (ru) Способы получения и формирования нанесенных активных металлических катализаторов и предшественников
BR112013018701A2 (pt) catalisador de aromatização de metano, e, processos para preparar um catalisador de aromatização de metano e para produzir hidrocarbonetos aromáticos
MX2016004991A (es) Diseño de catalizador para motores de combustion diesel de servicio pesado.
WO2012166472A3 (en) Production of propene
EA201201581A1 (ru) Твердый основный катализатор
MX345473B (es) Catalizadores de oxidación diesel, sistemas y métodos de tratamiento.
MX2014002190A (es) Soporte de catalizador y catalizadores preparados a partir del mismo.
BRPI0907160A2 (pt) Catalisador para converter óleo bruto inferior contendo ácido, processos para preparar o mesmo e para converter cataliticamente o óleo bruto inferior contendo ácido com uso do catalisador de conversão
MY171816A (en) Process for preparing fisher-tropsch catalyst
EA200901058A1 (ru) Получение катализаторов синтеза фишера-тропша
EP2611536A4 (en) CATALYST FOR LOW-MIXED GASOLINE ENGINE WITH ENHANCED NH3 FORMATION
EA201590075A1 (ru) Носители катализатора на основе карбида кремния, покрытого tio, для синтеза фишера-тропша
BR112014031391A2 (pt) catalisador para a conversão de oxigenados em olefinas, processo para a preparação de um catalizador, processo para converter oxigenados em olefinas e uso de catalizador.
BR112012022580A2 (pt) sistema catalisador para catálise heterogênea de uma reação de conversão de composto orgânico e métodos de uso
EA201290615A1 (ru) Установка и способ адиабатической конверсии метана
BR112012022985A2 (pt) catalisador heterogêneo quiral por reação de nitroaldol assimétrica.
WO2009138204A3 (de) Verfahren zur herstellung einer platinkatalysator-vorstufe
EA201791650A1 (ru) Способ синтеза углеводородов