MX373757B - Composición catalizadora y proceso para la oligomerización de etileno. - Google Patents

Composición catalizadora y proceso para la oligomerización de etileno.

Info

Publication number
MX373757B
MX373757B MX2016001079A MX2016001079A MX373757B MX 373757 B MX373757 B MX 373757B MX 2016001079 A MX2016001079 A MX 2016001079A MX 2016001079 A MX2016001079 A MX 2016001079A MX 373757 B MX373757 B MX 373757B
Authority
MX
Mexico
Prior art keywords
sub
catalyst composition
oligomerization
ethylene
ring system
Prior art date
Application number
MX2016001079A
Other languages
English (en)
Other versions
MX2016001079A (es
Inventor
Abdullah Al-Qahtani
Andreas Meiswinkle
Anina Woehl
Bernd H Mueller
Heinz Boelt
Marco Harff
Mohammed H Al-Hazmi
Normen Peulecke
Uwe Rosenthal
Wolfgang Mueller
Original Assignee
Linde Ag
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde Ag, Saudi Basic Ind Corp filed Critical Linde Ag
Publication of MX2016001079A publication Critical patent/MX2016001079A/es
Publication of MX373757B publication Critical patent/MX373757B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1885—Ligands comprising two different formal oxidation states of phosphorus in one at least bidentate ligand, e.g. phosphite/phosphinite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Una composición catalizadora que incluye: (a) un compuesto de cromo; (b) un ligando de la estructura general (A) R1R2P-N (R3)-P (R4) -NR5R6 o (B) R1R2P-N (R3)-p (XR7) R8 o R1R2P-N(R3)-P(XR7)2, con X = O o S, en donde R1, R2, R3, R4, R5, R6, R7 y R8 son independientemente alquilo C1-C10, arilo C6-C20, cicloalquilo C3-C10, aralquilo, alquilarilo o trialquilsililo o cualquier derivado cíclico de (A) y (B), en donde al menos uno de los átomos de P o de N de la unidad PNPN o de la unidad PNP es un miembro del sistema de anillo, estando formado el sistema de anillo por uno o más compuestos constituyentes de las estructuras (A) o (B) por sustitución; y (c) un activador o un co-catalizador; y un proceso para tri- y/o tetramerización.
MX2016001079A 2013-07-29 2014-07-28 Composición catalizadora y proceso para la oligomerización de etileno. MX373757B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13178362.3A EP2832445A1 (en) 2013-07-29 2013-07-29 Catalyst composition and process for oligomerization of ethylene
US201462008237P 2014-06-05 2014-06-05
PCT/IB2014/063485 WO2015015402A2 (en) 2013-07-29 2014-07-28 Catalyst composition and process for oligomerization of ethylene

Publications (2)

Publication Number Publication Date
MX2016001079A MX2016001079A (es) 2016-04-25
MX373757B true MX373757B (es) 2020-04-23

Family

ID=48874924

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016001079A MX373757B (es) 2013-07-29 2014-07-28 Composición catalizadora y proceso para la oligomerización de etileno.

Country Status (13)

Country Link
US (4) US9561500B2 (es)
EP (1) EP2832445A1 (es)
JP (1) JP6175192B2 (es)
KR (1) KR102268302B1 (es)
CN (2) CN108295900A (es)
BR (1) BR112016001705A2 (es)
CA (1) CA2916919C (es)
MX (1) MX373757B (es)
MY (1) MY172628A (es)
RU (1) RU2647863C2 (es)
SG (1) SG11201510819VA (es)
TW (1) TWI561305B (es)
WO (1) WO2015015402A2 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2832445A1 (en) 2013-07-29 2015-02-04 Linde AG Catalyst composition and process for oligomerization of ethylene
KR101679515B1 (ko) 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
KR102545533B1 (ko) * 2016-05-27 2023-06-21 에스케이이노베이션 주식회사 올리고머화 촉매 및 이를 이용한 에틸렌 올리고머의 제조방법
SG11201900267YA (en) 2016-07-15 2019-02-27 Sibur Holding Public Joint Stock Co Method of oligomerization of olefins
KR101880810B1 (ko) * 2016-09-21 2018-07-23 롯데케미칼 주식회사 올레핀 올리고머 제조방법
EP3880359A1 (en) * 2018-11-12 2021-09-22 SABIC Global Technologies B.V. Ligands for production of 1-hexene in chromium assisted ethylene oligomerization process
ES2943660T3 (es) * 2018-11-12 2023-06-15 Sabic Global Technologies Bv Ligandos para la producción de 1-octeno en el proceso de oligomerización de etileno asistido por cromo
CN111889142B (zh) * 2020-07-23 2023-02-07 天津科技大学 一种乙烯选择性齐聚的催化剂体系、反应方法及其应用
CN112473741B (zh) * 2020-10-22 2023-09-01 杭州小菱科技有限公司 一种乙烯齐聚催化剂体系及其制备方法与用途
US20250050317A1 (en) 2021-12-23 2025-02-13 Sabic Global Technologies B.V. Catalyst composition for oligomerization reaction

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0016895D0 (en) * 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
US7361623B2 (en) 2001-12-20 2008-04-22 Sasol Technology (Pty) Ltd. Trimerisation and oligomerisation of olefins using a chromium based catalyst
JP2006511625A (ja) * 2002-12-20 2006-04-06 サソル テクノロジー （ピーティーワイ） リミテッド オレフィンの四量体化
US7297832B2 (en) * 2002-12-20 2007-11-20 Sasol Technology (Pty) Limited Tetramerization of olefins
US7525009B2 (en) * 2002-12-20 2009-04-28 Sasol Technology (Pty) Limited Trimerisation of olefins
ATE457196T1 (de) 2002-12-20 2010-02-15 Sasol Tech Pty Ltd Trimerisierung von olefinen
US7323611B2 (en) 2005-06-28 2008-01-29 Sumitomo Chemical Company Limited Process for producing olefin oligomer
CN100443178C (zh) * 2006-03-10 2008-12-17 中国石油天然气股份有限公司 一种乙烯低聚的催化剂组合物及其应用
CA2673186C (en) * 2006-12-22 2015-02-17 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
KR101241656B1 (ko) 2007-07-11 2013-03-11 린데 악티엔게젤샤프트 촉매 조성물 및 에틸렌의 이량체화, 삼량체화 및/또는 사량체화를 위한 공정
EP2106854B1 (en) * 2008-04-04 2011-05-25 Saudi Basic Industries Corporation Catalyst for oligomerization of ethylene, method for preparation thereof and process for oligomerization using it
ES2371218T3 (es) 2009-04-09 2011-12-28 Saudi Basic Industries Corporation Composición de catalizador y procedimiento para la oligomerización de etileno.
ES2409707T3 (es) * 2011-02-16 2013-06-27 Linde Ag Procedimiento de preparación de una composición catalítica para oligomerización de etileno y unidad de preformación de composición de catalizador respectiva
CA2765429C (en) * 2012-01-25 2019-12-31 Nova Chemicals Corporation P-n-p ligand
EP2832445A1 (en) 2013-07-29 2015-02-04 Linde AG Catalyst composition and process for oligomerization of ethylene

Also Published As

Publication number Publication date
MX2016001079A (es) 2016-04-25
US20220241764A1 (en) 2022-08-04
EP2832445A1 (en) 2015-02-04
CN108295900A (zh) 2018-07-20
RU2016104650A (ru) 2017-08-31
TW201519949A (zh) 2015-06-01
US20170128925A1 (en) 2017-05-11
JP6175192B2 (ja) 2017-08-02
MY172628A (en) 2019-12-06
US20190210011A1 (en) 2019-07-11
TWI561305B (en) 2016-12-11
SG11201510819VA (en) 2016-02-26
WO2015015402A3 (en) 2015-07-16
WO2015015402A2 (en) 2015-02-05
JP2016529098A (ja) 2016-09-23
KR102268302B1 (ko) 2021-06-23
CN105408019A (zh) 2016-03-16
KR20160037181A (ko) 2016-04-05
US20160167033A1 (en) 2016-06-16
RU2647863C2 (ru) 2018-03-21
CA2916919C (en) 2018-05-01
BR112016001705A2 (pt) 2017-09-19
US10265690B2 (en) 2019-04-23
US9561500B2 (en) 2017-02-07
CN105408019B (zh) 2019-06-28
CA2916919A1 (en) 2015-02-05

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