WO2011085951A8 - Oligomerization of olefins - Google Patents

Oligomerization of olefins Download PDF

Info

Publication number
WO2011085951A8
WO2011085951A8 PCT/EP2011/000050 EP2011000050W WO2011085951A8 WO 2011085951 A8 WO2011085951 A8 WO 2011085951A8 EP 2011000050 W EP2011000050 W EP 2011000050W WO 2011085951 A8 WO2011085951 A8 WO 2011085951A8
Authority
WO
WIPO (PCT)
Prior art keywords
oligomerization
olefins
organometalliccomplex
didendate
nitogen
Prior art date
Application number
PCT/EP2011/000050
Other languages
French (fr)
Other versions
WO2011085951A1 (en
Inventor
Katrin Schuhen
Reynald Chevalier
Sandro Gambarotta
Sebastiano Licciulli
Khalid Albahily
Indira Thapa
Robbert Duchateau
Original Assignee
Basell Polyolefine Gmbh
University Of Ottawa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh, University Of Ottawa filed Critical Basell Polyolefine Gmbh
Publication of WO2011085951A1 publication Critical patent/WO2011085951A1/en
Publication of WO2011085951A8 publication Critical patent/WO2011085951A8/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

The invention deals with oligomerization, especially tetramerization of olefins by use of a catalyst system comprising an organometalliccomplex of an element of group 3 to 10 of the Periodic Table of the Elements and a didendate nitogen comprising ligand.
PCT/EP2011/000050 2010-01-15 2011-01-08 Oligomerization of olefins WO2011085951A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP10000346.6 2010-01-15
EP10000346 2010-01-15
US34108710P 2010-03-26 2010-03-26
US61/341,087 2010-03-26

Publications (2)

Publication Number Publication Date
WO2011085951A1 WO2011085951A1 (en) 2011-07-21
WO2011085951A8 true WO2011085951A8 (en) 2011-09-01

Family

ID=44303849

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/000050 WO2011085951A1 (en) 2010-01-15 2011-01-08 Oligomerization of olefins

Country Status (1)

Country Link
WO (1) WO2011085951A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9410081B2 (en) 2012-10-15 2016-08-09 East China University Of Science And Technology Luminescent materials
CN108558933B (en) * 2018-03-10 2019-06-18 苏州和颂生化科技有限公司 One kind has the exploitation and application of the aromatic amine material of charge storage

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3635937A (en) 1969-11-05 1972-01-18 Shell Oil Co Ethylene polymerization
US3676523A (en) 1971-07-16 1972-07-11 Shell Oil Co Alpha-olefin production
US5811618A (en) 1991-10-16 1998-09-22 Amoco Corporation Ethylene trimerization
US7053160B1 (en) 1998-11-25 2006-05-30 Basell Polyolefine Gmbh Metallocene monohalogenides
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
US6900152B2 (en) 2000-09-29 2005-05-31 Tosoh Corporation Catalyst for trimerization of ethylene and process for trimerizing ethylene using the catalyst
WO2003004158A2 (en) 2001-07-02 2003-01-16 Sasol Technology (Proprietary) Limited Catalyst comprising chromium and a ligand comprising a substituted cyclopentadiene and its use for trimerising olefins
WO2003053890A1 (en) 2001-12-20 2003-07-03 Sasol Technology (Pty) Ltd Trimerisation and oligomerisation of olefins using a chromium based catalyst
CN100548947C (en) 2002-12-20 2009-10-14 Sasol技术股份有限公司 Four of alkene gathers
WO2009006979A2 (en) 2007-07-11 2009-01-15 Linde Ag Catalyst composition and process for di-, tri- and/or tetramerization of ethylene

Also Published As

Publication number Publication date
WO2011085951A1 (en) 2011-07-21

Similar Documents

Publication Publication Date Title
IN2014DN05988A (en)
WO2016044428A3 (en) Catalysts for oxidative coupling of methane and oxidative dehydrogenation of ehtane
EP3471877A4 (en) Palladium diesel oxidation catalyst
EP2987783A4 (en) Ligand compound, catalyst system for olefin oligomerization, and olefin oligomerization method using same
EP3083049A4 (en) Manganese-containing diesel oxidation catalyst
EP3083044A4 (en) Manganese-containing diesel oxidation catalyst
EP3691782A4 (en) Scr catalyst compositions, catalysts, and catalyst systems incorporating such catalysts
EP3059263A4 (en) Spherical carriers for olefin polymerization catalyst, catalyst components, catalyst, and preparation methods therefor
MX2018006987A (en) Olefin metathesis catalysts.
EP3689457A4 (en) Exhaust-gas purifying catalyst
BR112013015812A2 (en) use of a product obtainable by the reaction of a fatty acid or acid mixture, product obtainable by the reaction of a fatty acid or acid mixture and method for producing a product.
EP2420519A4 (en) Catalyst component used for olefin polymerization, process for preparing the same, and catalyst containing the same
EP3045463A4 (en) Ligand compound, catalyst system for olefin oligomerization, and olefin oligomerization method using the same
EP2617739A4 (en) Catalyst carrier for olefin polymerization, solid catalyst component and catalyst
EP2987797A4 (en) Ligand compound, catalyst system for oligomerizing olefin, and method for oligomerizing olefin using same
EP3689454A4 (en) Honeycomb catalyst
EP3689453A4 (en) Honeycomb catalyst
MX2017015580A (en) Processes for preparing metallocene-based catalyst systems in cyclohexene.
EP3600659B8 (en) Selective catalytic reduction catalyst
EP2803670A4 (en) Ligand compound, chromium compound, and catalyst system comprising same
LT2658885T (en) Solid catalyst component, catalyst comprising said solid component, and process for the (co)polymerization of alpha-olefins
WO2011085951A8 (en) Oligomerization of olefins
GB201020119D0 (en) Pharamaceutical and other compositions, e.g. for the skin, comprising emulsifying ointment and water
NO20101795A1 (en) Ship hull, as well as ships including the mentioned ship hull
EP2985287A4 (en) Ligand compound, catalyst system for olefin oligomerization, and olefin oligomerization method using same

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11700992

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase in:

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 11700992

Country of ref document: EP

Kind code of ref document: A1