MX373379B - Catalizador y proceso para oxicloración de etileno en dicloroetano. - Google Patents

Catalizador y proceso para oxicloración de etileno en dicloroetano.

Info

Publication number
MX373379B
MX373379B MX2015009957A MX2015009957A MX373379B MX 373379 B MX373379 B MX 373379B MX 2015009957 A MX2015009957 A MX 2015009957A MX 2015009957 A MX2015009957 A MX 2015009957A MX 373379 B MX373379 B MX 373379B
Authority
MX
Mexico
Prior art keywords
catalyst
dichloroethane
ethylene
aqueous solution
oxychloration
Prior art date
Application number
MX2015009957A
Other languages
English (en)
Other versions
MX2015009957A (es
Inventor
Keith Kramer
Original Assignee
Oxy Vinyls Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxy Vinyls Lp filed Critical Oxy Vinyls Lp
Publication of MX2015009957A publication Critical patent/MX2015009957A/es
Publication of MX373379B publication Critical patent/MX373379B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
    • C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

En un proceso de oxicloración del tipo donde el etileno se convierte en 1,2- dicloroetano en presencia de un catalizador con soporte de cobre, la mejora comprende: el uso de un catalizador con soporte preparado mediante (i) impregnación, en la primera etapa, de un soporte de alúmina con una primera solución acuosa que incluye cobre, un metal alcalinotérreo y un metal alcalino para, de esta forma, formar un primer componente del catalizador; y (ii) impregnar, en una etapa posterior, el primer componente catalizador con una segunda solución acuosa que incluye cobre y un metal alcalinotérreo, donde la segunda solución acuosa se encuentra sustancialmente desprovisto de un metal alcalino, para formar, de esta manera, el catalizador con soporte.
MX2015009957A 2013-03-15 2014-03-17 Catalizador y proceso para oxicloración de etileno en dicloroetano. MX373379B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361798872P 2013-03-15 2013-03-15
PCT/US2014/030233 WO2014145463A2 (en) 2013-03-15 2014-03-17 Catalyst and process for oxychlorination of ethylene to dichloroethane

Publications (2)

Publication Number Publication Date
MX2015009957A MX2015009957A (es) 2015-10-29
MX373379B true MX373379B (es) 2020-07-03

Family

ID=50686179

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015009957A MX373379B (es) 2013-03-15 2014-03-17 Catalizador y proceso para oxicloración de etileno en dicloroetano.

Country Status (12)

Country Link
US (3) US10981150B2 (es)
EP (1) EP2969192B1 (es)
JP (2) JP6509807B2 (es)
KR (1) KR102183954B1 (es)
CN (1) CN105073255B (es)
BR (1) BR112015023277B1 (es)
HR (1) HRP20260039T1 (es)
MX (1) MX373379B (es)
MY (1) MY187937A (es)
PT (1) PT2969192T (es)
RU (1) RU2664116C2 (es)
WO (1) WO2014145463A2 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102183954B1 (ko) * 2013-03-15 2020-11-30 옥시 비닐스, 엘.피. 에틸렌의 디클로로에탄으로의 옥시염소화를 위한 촉매 및 방법
CN106588559B (zh) * 2016-12-14 2020-06-05 厦门中科易工化学科技有限公司 一种用于制备1,2-二氯乙烷的乙烯氯化剂及其用途和1,2-二氯乙烷的制备方法
CN111565838B (zh) 2018-02-23 2023-09-26 株式会社Lg化学 用于烃的氧氯化工艺的催化剂、其制备方法和使用该催化剂制备烃的氧氯化化合物的方法
CN118748989A (zh) 2022-01-19 2024-10-08 氧乙烯有限合伙公司 氧氯化工艺

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2125748A5 (es) 1971-02-19 1972-09-29 Pechiney Saint Gobain
GB8829706D0 (en) * 1988-12-20 1989-02-15 Ici Plc Oxychlorination catalyst composition
DE69104178T2 (de) * 1991-01-11 1995-05-04 Solvay Oxychlorierung katalytischer Zusammensetzung und Verfahren für die Oxychlorierung von Ethylen unter Verwendung dieser Zusammensetzung.
US5292703A (en) 1992-07-28 1994-03-08 The Geon Company Catalyst and process for oxychlorination of ethylene to EDC
TWI255736B (en) * 2002-02-05 2006-06-01 Basf Ag A catalyst composition for the oxychlorination of ethylene and its use
ITMI20030630A1 (it) 2003-03-31 2004-10-01 Sued Chemie Mt Srl Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano.
ITMI20042317A1 (it) * 2004-12-02 2005-03-02 Sued Chemie Mt Srl Catalizzatori per l'ossiclorurazione dell'etilene a 1,2-dicloroetano
BRPI0520135A2 (pt) 2005-05-12 2009-08-18 Solvay catalisador de oxicloração, processo de oxicloração de um hidrocarboneto, alumina, e, uso em um processo de oxicloração
EP1917102A1 (en) * 2005-08-18 2008-05-07 Albemarle Netherlands B.V. Catalytic oxychlorination
TWI341218B (en) 2005-11-14 2011-05-01 Oxy Vinyls Lp Catalyst compositions and process for oxychlorination
EP2070898B1 (de) 2007-12-03 2013-02-20 Basf Se Katalysator zur Oxichlorierung
US9248434B2 (en) * 2012-11-06 2016-02-02 Basf Corporation Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane
KR102183954B1 (ko) * 2013-03-15 2020-11-30 옥시 비닐스, 엘.피. 에틸렌의 디클로로에탄으로의 옥시염소화를 위한 촉매 및 방법

Also Published As

Publication number Publication date
RU2664116C2 (ru) 2018-08-15
KR102183954B1 (ko) 2020-11-30
WO2014145463A3 (en) 2014-12-04
EP2969192A2 (en) 2016-01-20
PT2969192T (pt) 2026-01-23
JP2016518968A (ja) 2016-06-30
CN105073255B (zh) 2017-12-12
JP6509807B2 (ja) 2019-05-08
US9073046B2 (en) 2015-07-07
KR20150131139A (ko) 2015-11-24
US20140275661A1 (en) 2014-09-18
WO2014145463A2 (en) 2014-09-18
EP2969192B1 (en) 2025-11-05
US20210237038A1 (en) 2021-08-05
MY187937A (en) 2021-10-29
JP2019122959A (ja) 2019-07-25
HRP20260039T1 (hr) 2026-02-27
RU2015140998A (ru) 2017-04-24
US10981150B2 (en) 2021-04-20
BR112015023277B1 (pt) 2021-06-01
BR112015023277A2 (pt) 2017-07-18
MX2015009957A (es) 2015-10-29
US20160023191A1 (en) 2016-01-28
CN105073255A (zh) 2015-11-18

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