BR112015023718A2 - síntese seletiva de acrilato de 2-octila pela esterificação catalisada por ácido de 2-octanol e ácido acrílico - Google Patents

síntese seletiva de acrilato de 2-octila pela esterificação catalisada por ácido de 2-octanol e ácido acrílico

Info

Publication number
BR112015023718A2
BR112015023718A2 BR112015023718A BR112015023718A BR112015023718A2 BR 112015023718 A2 BR112015023718 A2 BR 112015023718A2 BR 112015023718 A BR112015023718 A BR 112015023718A BR 112015023718 A BR112015023718 A BR 112015023718A BR 112015023718 A2 BR112015023718 A2 BR 112015023718A2
Authority
BR
Brazil
Prior art keywords
acid
octanol
octyl acrylate
acrylic acid
selective synthesis
Prior art date
Application number
BR112015023718A
Other languages
English (en)
Other versions
BR112015023718B1 (pt
Inventor
E Hutt Aaron
L Colby Joshua
A Clem Tabitha
D Spawn Terrence
T Teply Wade
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of BR112015023718A2 publication Critical patent/BR112015023718A2/pt
Publication of BR112015023718B1 publication Critical patent/BR112015023718B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

resumo “síntese seletiva de acrilato de 2-octila pela esterificação catalisada por ácido de 2-octanol e ácido acrílico” um método para produzir acrilato de 2-octila, compreendendo reagir 2-octanol com ácido acrílico na presença de um catalisador ácido e água adicionada é descrito. o 2-octanol pode ser derivado de recursos renováveis, como óleo de rícino. o método é eficiente e fornece seletividade para acrilato de 2-octila.
BR112015023718-5A 2013-03-15 2014-03-04 método para produzir acrilato de 2-octila e método de fabricação de um adesivo BR112015023718B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361789297P 2013-03-15 2013-03-15
US61/789,297 2013-03-15
PCT/US2014/020213 WO2014149669A1 (en) 2013-03-15 2014-03-04 Selective synthesis of 2-octyl acrylate by acid catalyzed esterification of 2-octanol and acrylic acid

Publications (2)

Publication Number Publication Date
BR112015023718A2 true BR112015023718A2 (pt) 2017-07-18
BR112015023718B1 BR112015023718B1 (pt) 2020-10-13

Family

ID=50382626

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015023718-5A BR112015023718B1 (pt) 2013-03-15 2014-03-04 método para produzir acrilato de 2-octila e método de fabricação de um adesivo

Country Status (6)

Country Link
US (1) US9604902B2 (pt)
EP (1) EP2970094B1 (pt)
KR (1) KR102231180B1 (pt)
CN (1) CN105073704A (pt)
BR (1) BR112015023718B1 (pt)
WO (1) WO2014149669A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4155330A1 (en) * 2022-09-13 2023-03-29 Basf Se Pressure-sensitive adhesive composition comprising a dispersed pressure-sensitive adhesive polymer formed by emulsion polymerization of 2-octyl acrylate, styrene, hydroxyalkyl acrylate, monomers having at least one acid group in specific amounts and optionally further monomers
WO2023249130A2 (ja) * 2022-11-18 2023-12-28 株式会社日本触媒 （メタ）アクリル酸エステルの製造方法
WO2023249129A2 (ja) * 2022-11-18 2023-12-28 株式会社日本触媒 （メタ）アクリル酸エステルの製造方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619979A (en) 1984-03-28 1986-10-28 Minnesota Mining And Manufacturing Company Continuous free radial polymerization in a wiped-surface reactor
US4843134A (en) 1984-03-28 1989-06-27 Minnesota Mining And Manufacturing Company Acrylate pressure-sensitive adhesives containing insolubles
US4737559A (en) 1986-05-19 1988-04-12 Minnesota Mining And Manufacturing Co. Pressure-sensitive adhesive crosslinked by copolymerizable aromatic ketone monomers
JPS6317844A (ja) 1986-07-09 1988-01-25 Nippon Shokubai Kagaku Kogyo Co Ltd 不飽和カルボン酸エステルの製造方法
KR950004548B1 (ko) * 1989-10-27 1995-05-02 대우전자주식회사 포탄신관조립용 클림핑(Crimping) 장치
US5804610A (en) 1994-09-09 1998-09-08 Minnesota Mining And Manufacturing Company Methods of making packaged viscoelastic compositions
US5637646A (en) 1995-12-14 1997-06-10 Minnesota Mining And Manufacturing Company Bulk radical polymerization using a batch reactor
KR100363927B1 (ko) * 1996-12-16 2003-02-19 니폰 쇼쿠바이 컴파니 리미티드 카르복실산에스테르의제조방법및거기에사용된수지분리조
US6893718B2 (en) 2002-05-20 2005-05-17 3M Innovative Properties Company Pressure sensitive adhesive composition, articles made therewith and method of use
US7385020B2 (en) 2006-10-13 2008-06-10 3M Innovative Properties Company 2-octyl (meth)acrylate adhesive composition
JP2011508804A (ja) * 2007-12-18 2011-03-17 スリーエム イノベイティブ プロパティズ カンパニー 微粒子感圧接着剤組成物
US20100151241A1 (en) * 2008-04-14 2010-06-17 3M Innovative Properties Company 2-Octyl (Meth)acrylate Adhesive Composition
US20120329898A1 (en) * 2008-04-14 2012-12-27 3M Innovative Properties Company 2-octyl (meth)acrylate adhesive composition
DE102008040221A1 (de) * 2008-07-07 2010-01-14 Evonik Röhm Gmbh Verfahren zur Herstellung von (Meth)acrylsäureestern
JP5932834B2 (ja) 2010-12-21 2016-06-08 スリーエム イノベイティブ プロパティズ カンパニー 二級アルキル（メタ）アクリレート由来のポリマー
JP6173308B2 (ja) 2011-07-06 2017-08-02 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ （メタ）アクリル酸エステルの製造方法

Also Published As

Publication number Publication date
BR112015023718B1 (pt) 2020-10-13
EP2970094B1 (en) 2018-12-19
CN105073704A (zh) 2015-11-18
US20160002140A1 (en) 2016-01-07
WO2014149669A1 (en) 2014-09-25
KR20150130416A (ko) 2015-11-23
US9604902B2 (en) 2017-03-28
KR102231180B1 (ko) 2021-03-24
EP2970094A1 (en) 2016-01-20

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 04/03/2014, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 8A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2661 DE 04-01-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.