BR112015014106A2 - politióis como catalisadores de isomerização cis/trans para compostos insaturados - Google Patents

politióis como catalisadores de isomerização cis/trans para compostos insaturados

Info

Publication number
BR112015014106A2
BR112015014106A2 BR112015014106A BR112015014106A BR112015014106A2 BR 112015014106 A2 BR112015014106 A2 BR 112015014106A2 BR 112015014106 A BR112015014106 A BR 112015014106A BR 112015014106 A BR112015014106 A BR 112015014106A BR 112015014106 A2 BR112015014106 A2 BR 112015014106A2
Authority
BR
Brazil
Prior art keywords
unsaturated
cis
trans isomerization
polythiols
unsaturated compounds
Prior art date
Application number
BR112015014106A
Other languages
English (en)
Other versions
BR112015014106B1 (pt
Inventor
Greiner Nadine
Tobias STEMMLER René
Original Assignee
Dsm Ip Assets Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dsm Ip Assets Bv filed Critical Dsm Ip Assets Bv
Publication of BR112015014106A2 publication Critical patent/BR112015014106A2/pt
Publication of BR112015014106B1 publication Critical patent/BR112015014106B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/30—Compounds having groups
    • C07C43/313—Compounds having groups containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
    • C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0217—Mercaptans or thiols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/24—Thiols, sulfides, hydropolysulfides, or polysulfides having thio groups bound to carbon atoms of six-membered aromatic rings
    • C07C321/28—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to carbon atoms of six-membered aromatic rings
    • C07C321/30—Sulfides having the sulfur atom of at least one thio group bound to two carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/60—Preparation of compounds having groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)

Abstract

resumo politióis como catalisadores de isomerização cis/trans para compostos insaturados a presente invenção refere-se a um processo de uma isomerização cis/trans de um composto insaturado a sendo selecionado a partir do grupo que consiste em cetonas insaturadas, cetais insaturados, aldeídos insaturados, acetais insaturados, ácidos carboxílicos insaturados, ésteres de um ácido carboxílico insaturado e amidas de um ácido carboxílico insaturado utilizando poliol como catalisador de isomerização cis/trans. observou-se que a isomerização é muito eficiente e rápida.
BR112015014106-4A 2012-12-18 2013-12-18 processo de uma isomerização cis/trans de um composto insaturado, processos de produção de isômeros cis e trans, composição, cetal ou acetal e uso de um politiol BR112015014106B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12197798.7 2012-12-18
EP12197798 2012-12-18
PCT/IB2013/061082 WO2014097171A1 (en) 2012-12-18 2013-12-18 Polythiols as cis/trans isomerization catalysts for unsaturated compounds

Publications (2)

Publication Number Publication Date
BR112015014106A2 true BR112015014106A2 (pt) 2017-07-11
BR112015014106B1 BR112015014106B1 (pt) 2020-11-17

Family

ID=47500975

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015014106-4A BR112015014106B1 (pt) 2012-12-18 2013-12-18 processo de uma isomerização cis/trans de um composto insaturado, processos de produção de isômeros cis e trans, composição, cetal ou acetal e uso de um politiol

Country Status (8)

Country Link
US (1) US9765002B2 (pt)
EP (1) EP2935186B1 (pt)
JP (1) JP6442782B2 (pt)
CN (1) CN104884419B (pt)
BR (1) BR112015014106B1 (pt)
EA (1) EA028500B1 (pt)
MY (1) MY170265A (pt)
WO (1) WO2014097171A1 (pt)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9611200B2 (en) * 2012-12-18 2017-04-04 Dsm Ip Assets B.V. (6R,10R)-6,10,14-trimetylpentadecan-2-one prepared from 6,10,14 trimetylpentadeca-5,9,13-trien-2-one or 6,10,14-trimetylpentadeca-5,9-dien-2-one
JP6390048B2 (ja) * 2012-12-18 2018-09-19 ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． 組み合わされた不斉水素化によって特定の生成物を定量的に得るためのｅ／ｚ異性体の混合物の使用
JP6690080B2 (ja) * 2012-12-18 2020-04-28 ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． 不飽和化合物のためのシス／トランス異性化触媒としての一酸化窒素
CN107879914B (zh) * 2017-11-24 2020-11-20 万华化学集团股份有限公司 一种高效精馏柠檬醛制备橙花醛的方法及用于该方法的催化剂
CN111153765B (zh) * 2019-12-21 2020-10-20 南京汉欣医药科技有限公司 不同顺反异构体比例维生素k1及其中间体卤代植物醇的制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5820948B2 (ja) 1974-09-02 1983-04-26 株式会社クラレ デルタ ４ ，デルタ ８− トランスフアルネシルサクサン マタハ ソノエステルルイ ノ セイゾウホウ
JPS5132511A (en) * 1974-09-10 1976-03-19 Kuraray Co Ritsutaikiseisareta geraniruaseton no seizohoho
US4028385A (en) * 1974-09-02 1977-06-07 Kuraray Co., Ltd. Process for preparing stereospecific farnesylacetic acid and ester thereof
GB1479272A (en) 1974-12-23 1977-07-13 Kuraray Co Process for preparing a stereospecific farnesol
CH620891A5 (en) * 1975-12-19 1980-12-31 Teijin Ltd Isomerisation process
US4338170A (en) * 1979-06-14 1982-07-06 Nissan Chemical Industries, Ltd. Isomerization of β-γ-unsaturated alcohol or its ester
JPS5665832A (en) * 1979-11-02 1981-06-03 Nissan Chem Ind Ltd Isomerization of beta-gamma unsaturated alcohol
JPS55167236A (en) * 1979-06-14 1980-12-26 Nissan Chem Ind Ltd Isomerization of beta-alpha unsaturated alcohol
JPS5665843A (en) * 1979-11-02 1981-06-03 Nissan Chem Ind Ltd Isomerization of beta-gamma unsaturated ester
JPS5615232A (en) * 1979-07-14 1981-02-14 Nissan Chem Ind Ltd Production of terpene aldehyde
US5908957A (en) * 1997-02-14 1999-06-01 Roche Vitamins Inc. Isomerization process
RU2238957C2 (ru) 1999-04-26 2004-10-27 Акцо Нобель Н.В. Композиция, включающая соединения с функциональными меркаптогруппами
CN100564372C (zh) 2004-08-19 2009-12-02 帝斯曼知识产权资产管理有限公司 用于精馏高沸点的对空气和/或温度敏感的有用产品的混合物的方法
JP6690080B2 (ja) * 2012-12-18 2020-04-28 ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． 不飽和化合物のためのシス／トランス異性化触媒としての一酸化窒素

Also Published As

Publication number Publication date
EA028500B1 (ru) 2017-11-30
EP2935186A1 (en) 2015-10-28
WO2014097171A1 (en) 2014-06-26
BR112015014106B1 (pt) 2020-11-17
EA201500647A1 (ru) 2015-11-30
US20150315113A1 (en) 2015-11-05
JP6442782B2 (ja) 2018-12-26
JP2016506396A (ja) 2016-03-03
US9765002B2 (en) 2017-09-19
CN104884419A (zh) 2015-09-02
MY170265A (en) 2019-07-15
CN104884419B (zh) 2018-03-23
EP2935186B1 (en) 2020-03-25

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Legal Events

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B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 18/12/2013, OBSERVADAS AS CONDICOES LEGAIS.