MX2021013200A - Metodo de preparacion de un catalizador. - Google Patents
Metodo de preparacion de un catalizador.Info
- Publication number
- MX2021013200A MX2021013200A MX2021013200A MX2021013200A MX2021013200A MX 2021013200 A MX2021013200 A MX 2021013200A MX 2021013200 A MX2021013200 A MX 2021013200A MX 2021013200 A MX2021013200 A MX 2021013200A MX 2021013200 A MX2021013200 A MX 2021013200A
- Authority
- MX
- Mexico
- Prior art keywords
- support
- catalyst
- calcined
- iii
- preparing
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- -1 alkaline earth metal aluminate Chemical class 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 102000002322 Egg Proteins Human genes 0.000 abstract 1
- 108010000912 Egg Proteins Proteins 0.000 abstract 1
- 239000003929 acidic solution Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 210000003278 egg shell Anatomy 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0063—Granulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0213—Preparation of the impregnating solution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/12—Oxidising
- B01J37/14—Oxidising with gases containing free oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/001—Calcining
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Abstract
Se describe un método para preparar un catalizador de cáscara de huevo que comprende las etapas de: (i) preparar un soporte catalizador de aluminato de metal alcalinotérreo formado y calcinado, (ii) tratar el soporte de aluminato de metal alcalinotérreo formado y calcinado con un gas que contiene vapor de agua para formar un soporte hidratado, (iii) con o sin una etapa de secado intermedio, impregnar el soporte hidratado con una solución ácida que contiene uno o más compuestos de metal catalítico y secar el soporte impregnado, (iv) calcinar el soporte impregnado seco, para formar un catalizador calcinado que tiene un óxido de metal catalítico concentrado en la superficie del soporte y (v) opcionalmente repetir las etapas (ii), (iii) y (iv).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1907062.2A GB201907062D0 (en) | 2019-05-20 | 2019-05-20 | Catalyst preparation method |
PCT/GB2020/051053 WO2020234561A1 (en) | 2019-05-20 | 2020-04-30 | Catalyst preparation method |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2021013200A true MX2021013200A (es) | 2021-12-10 |
Family
ID=67385078
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2021013200A MX2021013200A (es) | 2019-05-20 | 2020-04-30 | Metodo de preparacion de un catalizador. |
Country Status (7)
Country | Link |
---|---|
US (1) | US11958040B2 (es) |
EP (1) | EP3972734A1 (es) |
JP (1) | JP7506095B2 (es) |
CN (1) | CN113710361B (es) |
GB (2) | GB201907062D0 (es) |
MX (1) | MX2021013200A (es) |
WO (1) | WO2020234561A1 (es) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021138728A1 (pt) * | 2020-01-08 | 2021-07-15 | Petróleo Brasileiro S.A. - Petrobras | Método de preparo de catalisador de reforma a vapor, catalisador e seu uso |
GB202103658D0 (en) * | 2021-03-17 | 2021-04-28 | Johnson Matthey Plc | Catalyst activation |
GB202301101D0 (en) | 2023-01-26 | 2023-03-15 | Johnson Matthey Plc | Steam reforming catalyst and process |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB640455A (en) * | 1946-03-04 | 1950-07-19 | Otto Reitlinger | Improvements in catalytic contact masses |
EP0029321B1 (en) | 1979-11-20 | 1983-09-21 | Imperial Chemical Industries Plc | Hydrogenation catalyst material, a precursor thereto, method of making the latter and use of the catalyst for selective hydrogenation |
US4317746A (en) | 1980-11-28 | 1982-03-02 | Union Oil Company Of California | Hydrotreating catalysts |
GB8501526D0 (en) | 1985-01-22 | 1985-02-20 | Ici Plc | Catalyst |
JP2818171B2 (ja) | 1988-09-09 | 1998-10-30 | 東洋シーシーアイ株式会社 | 炭化水素の水蒸気改質反応用触媒及びその製造方法 |
SU1780208A1 (ru) * | 1990-02-05 | 1995-11-10 | Новомосковский Филиал Государственного Научно-Исследовательского И Проектного Института Азотной Промышленности И Продуктов Органического Синтеза | Способ приготовления катализатора для конверсии углеводородов |
CN1133496C (zh) * | 1998-11-25 | 2004-01-07 | 中国科学院大连化学物理研究所 | 一种抗积炭甲烷无氧芳构化催化剂及制备方法 |
US7176159B1 (en) * | 2001-08-15 | 2007-02-13 | Iowa State University Research Foundation, Inc. | Catalyst and sorbent material for the production of hydrogen |
US7767619B2 (en) | 2004-07-09 | 2010-08-03 | Sud-Chemie Inc. | Promoted calcium-aluminate supported catalysts for synthesis gas generation |
FR2875419B1 (fr) | 2004-09-22 | 2007-02-23 | Inst Francais Du Petrole | Catalyseur alumino-silicate dope et procede ameliore de traitement de charges hydrocarbonees |
JP4981561B2 (ja) | 2007-07-17 | 2012-07-25 | 住友化学株式会社 | マグネシアスピネル成形体の製造方法 |
CN101602016B (zh) * | 2008-06-12 | 2012-10-10 | 中国石油化工股份有限公司 | 水热稳定性的层状复合载体 |
GB0816705D0 (en) | 2008-09-12 | 2008-10-22 | Johnson Matthey Plc | Shaped heterogeneous catalysts |
GB0816703D0 (en) | 2008-09-12 | 2008-10-22 | Johnson Matthey Plc | Shaped heterogeneous catalysts |
GB0905222D0 (en) * | 2009-03-26 | 2009-05-13 | Johnson Matthey Plc | Method for producing a supported metal nitrate |
GB0907539D0 (en) * | 2009-05-01 | 2009-06-10 | Johnson Matthey Plc | Catalyst preparation method |
DE102009020729A1 (de) * | 2009-05-11 | 2010-11-18 | Symrise Gmbh & Co. Kg | Verwendung von Benzoesäure-Derivaten als Antioxidationsmittel |
CN103068723B (zh) | 2010-03-19 | 2016-02-10 | 赫多特普索化工设备公司 | 重整催化剂 |
GB201018152D0 (en) | 2010-10-27 | 2010-12-08 | Johnson Matthey Plc | Catalyst preparation method |
GB201102502D0 (en) * | 2011-02-14 | 2011-03-30 | Johnson Matthey Plc | Catalysts for use in reforming processes |
GB201117738D0 (en) * | 2011-10-14 | 2011-11-23 | Johnson Matthey Plc | Cobalt catalyst |
CN103785403A (zh) * | 2012-11-01 | 2014-05-14 | 中国石油化工股份有限公司 | 一种高活性加氢脱金属催化剂的制备方法 |
FR3033267B1 (fr) | 2015-03-05 | 2017-03-10 | Ifp Energies Now | Catalyseur comprenant de l'or disperse et du palladium et son application en hydrogenation selective |
CN106669846B (zh) * | 2015-11-09 | 2019-05-21 | 中国石油化工股份有限公司 | 一种脱金属催化剂载体的制备方法 |
RU2630956C1 (ru) * | 2016-09-06 | 2017-09-15 | Виталий Юрьевич Хатьков | Способ получения оксидно-никелевого катализатора |
CN108855162B (zh) * | 2017-05-11 | 2021-03-23 | 北京旭阳科技有限公司 | 一种制备催化剂的方法、由该方法制备的催化剂以及使用该催化剂制备甘油单甲醚的方法 |
CN109382096B (zh) * | 2017-08-14 | 2021-10-08 | 中国石油化工股份有限公司 | 钌基催化剂及其制备方法和费托合成方法 |
-
2019
- 2019-05-20 GB GBGB1907062.2A patent/GB201907062D0/en not_active Ceased
-
2020
- 2020-04-30 EP EP20724550.7A patent/EP3972734A1/en active Pending
- 2020-04-30 GB GB2006393.9A patent/GB2586305B/en active Active
- 2020-04-30 MX MX2021013200A patent/MX2021013200A/es unknown
- 2020-04-30 CN CN202080029457.9A patent/CN113710361B/zh active Active
- 2020-04-30 US US17/595,360 patent/US11958040B2/en active Active
- 2020-04-30 WO PCT/GB2020/051053 patent/WO2020234561A1/en active Application Filing
- 2020-04-30 JP JP2021568214A patent/JP7506095B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
GB2586305B (en) | 2021-10-06 |
JP2022533125A (ja) | 2022-07-21 |
WO2020234561A1 (en) | 2020-11-26 |
JP7506095B2 (ja) | 2024-06-25 |
CN113710361A (zh) | 2021-11-26 |
EP3972734A1 (en) | 2022-03-30 |
US11958040B2 (en) | 2024-04-16 |
GB201907062D0 (en) | 2019-07-03 |
GB2586305A (en) | 2021-02-17 |
US20220184582A1 (en) | 2022-06-16 |
GB202006393D0 (en) | 2020-06-17 |
CN113710361B (zh) | 2023-09-26 |
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