MX2016008060A - Sintesis de eteres de isohexida y carbonatos. - Google Patents

Sintesis de eteres de isohexida y carbonatos.

Info

Publication number
MX2016008060A
MX2016008060A MX2016008060A MX2016008060A MX2016008060A MX 2016008060 A MX2016008060 A MX 2016008060A MX 2016008060 A MX2016008060 A MX 2016008060A MX 2016008060 A MX2016008060 A MX 2016008060A MX 2016008060 A MX2016008060 A MX 2016008060A
Authority
MX
Mexico
Prior art keywords
isohexide
carbonates
alkylation
ethers
carbonate
Prior art date
Application number
MX2016008060A
Other languages
English (en)
Inventor
Stensrud Kenneth
Venkitasubramanian Padmesh
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2016008060A publication Critical patent/MX2016008060A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/30—General preparatory processes using carbonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un método fácil y directo de alquilación de alcoholes de anhidorazúcar (isohexidas) usando un reactivo de carbonato. El método de alquilación implica: a) poner en contacto, en una solución, una isohexida con un carbonato de dialquilo, dialilo, o diarilo, y la solución incluye una base de brØnsted; y b) producir al menos un éter alquílico o carbonato de alquilo del compuesto de isohexida. La reacción de alquilación se realiza in situ, es decir, sin un catalizador extrínseco. De acuerdo con el método, se pueden sintetizar diversos éteres y carbonatos.
MX2016008060A 2013-12-20 2014-12-05 Sintesis de eteres de isohexida y carbonatos. MX2016008060A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361918795P 2013-12-20 2013-12-20
PCT/US2014/068809 WO2015094716A1 (en) 2013-12-20 2014-12-05 Synthesis of isohexide ethers and carbonates

Publications (1)

Publication Number Publication Date
MX2016008060A true MX2016008060A (es) 2017-02-27

Family

ID=53403506

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016008060A MX2016008060A (es) 2013-12-20 2014-12-05 Sintesis de eteres de isohexida y carbonatos.

Country Status (10)

Country Link
US (2) US20170002019A1 (es)
EP (1) EP3083638A4 (es)
JP (1) JP2017501147A (es)
KR (1) KR20160101055A (es)
CN (1) CN105873934A (es)
AU (1) AU2014366986A1 (es)
BR (1) BR112016014276A2 (es)
CA (1) CA2934447A1 (es)
MX (1) MX2016008060A (es)
WO (1) WO2015094716A1 (es)

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US10407540B2 (en) * 2015-09-08 2019-09-10 Ppg Industries Ohio, Inc. Composition for optical articles and optical articles made therewith
KR102160368B1 (ko) * 2016-08-16 2020-09-25 피피지 인더스트리즈 오하이오 인코포레이티드 광학 물품용 중합가능 조성물
CN111349492B (zh) * 2020-02-28 2021-05-25 浙江糖能科技有限公司 2,5-四氢呋喃二甲醇脂肪酸二酯在柴油添加剂的应用
KR102152693B1 (ko) * 2020-02-28 2020-09-08 주식회사 삼양사 수율이 개선된 무수당 알코올의 디에테르 제조 방법
CN114409668B (zh) * 2022-01-20 2023-06-30 上海交通大学医学院附属第九人民医院 一种异山梨醇衍生物及基于异山梨醇结构的窝沟封闭剂

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US3219529A (en) * 1962-10-04 1965-11-23 American Cyanamid Co Stable tetracycline solutions
DE3421072A1 (de) * 1984-06-06 1985-12-12 Heinrich Mack Nachf., 7918 Illertissen 1,4:3,6-dianhydro-hexit-derivate, verfahren zu ihrer herstellung und ihre verwendung als arzneimittel
US4585649A (en) * 1984-12-21 1986-04-29 Ici Americas Inc. Dentifrice formulation and method of treating teeth, mouth and throat therewith to reduce plaque accumulation and irritation
DE3521809A1 (de) * 1985-06-19 1987-01-02 Ruetgerswerke Ag Verfahren zur herstellung von 2,5-dialkyl-1,4
EP0312040B1 (en) * 1987-10-13 1992-06-03 J. URIACH & CIA. S.A. 2,4-disubstituted derivatives of tetrahydrofuran
US4770871A (en) * 1987-11-06 1988-09-13 Ici Americas Inc. Process for the preparation of dianhydrosorbitol ethers
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IT1286527B1 (it) * 1996-12-05 1998-07-15 Enichem Spa Procedimento per la sintesi di 2-idrossi-4-alchilossi benzofenone
FR2821352B1 (fr) * 2001-02-23 2003-04-25 Poudres & Explosifs Ste Nale Procede de synthese de mono-ethers d'aryle et d'alkyle
KR20040035864A (ko) * 2001-09-24 2004-04-29 코닌클리케 필립스 일렉트로닉스 엔.브이. 이소소르바이드 유도체
CN1241888C (zh) * 2003-12-26 2006-02-15 南京林业大学 丙二醇二甲醚的合成方法
WO2006072599A2 (en) * 2005-01-10 2006-07-13 Glaxo Group Limited Androstane 17-alpha carbonate derivatives for use in the treatment of allergic and inflammatory conditions
WO2007089455A1 (en) * 2006-01-27 2007-08-09 E. I. Du Pont De Nemours And Company Fluoroalkenyl derivatives as insecticides and nematicides
WO2009120703A2 (en) * 2008-03-24 2009-10-01 Archer Daniels Midland Co. Method for preparation of anhydrosugar ethers
BRPI0803522A2 (pt) * 2008-09-17 2010-06-15 Petroleo Brasileiro Sa composições de combustìvel do ciclo diesel contendo dianidrohexitóis e derivados
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Also Published As

Publication number Publication date
EP3083638A1 (en) 2016-10-26
JP2017501147A (ja) 2017-01-12
KR20160101055A (ko) 2016-08-24
CA2934447A1 (en) 2015-06-25
AU2014366986A1 (en) 2016-06-30
CN105873934A (zh) 2016-08-17
EP3083638A4 (en) 2017-05-03
US20170001971A1 (en) 2017-01-05
BR112016014276A2 (pt) 2017-08-08
US20170002019A1 (en) 2017-01-05
US9890131B2 (en) 2018-02-13
WO2015094716A1 (en) 2015-06-25

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