BR112016014276A2 - Método de alquilação de um composto anidro-açúcar; composto éter; composto alquilado isohexídeo; e composto carbonato - Google Patents
Método de alquilação de um composto anidro-açúcar; composto éter; composto alquilado isohexídeo; e composto carbonatoInfo
- Publication number
- BR112016014276A2 BR112016014276A2 BR112016014276A BR112016014276A BR112016014276A2 BR 112016014276 A2 BR112016014276 A2 BR 112016014276A2 BR 112016014276 A BR112016014276 A BR 112016014276A BR 112016014276 A BR112016014276 A BR 112016014276A BR 112016014276 A2 BR112016014276 A2 BR 112016014276A2
- Authority
- BR
- Brazil
- Prior art keywords
- compound
- isohexide
- carbonate
- alkylation
- anhydro
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/12—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/30—General preparatory processes using carbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
MÉTODO DE ALQUILAÇÃO DE UM COMPOSTO ANIDRO-AÇÚCAR; COMPOSTO ÉTER; COMPOSTO ALQUILADO ISOHEXÍDEO; E COMPOSTO CARBONATO. É descrito um método simples e direto para alquilação de álcoois de anidro-açúcar (isohexídeos) usando um reagente carbonato. O método de alquilação envolve a) pôr em contato em uma solução de um isohexídeo com um carbonato de dialquila, dialila, ou diarila, e a solução inclui uma base de Brønsted; e b) produzir, tanto, um éter de alquila ou carbonato de alquila do composto isohexídeo. A reação de alquilação é in situ, ou seja, realizada sem um catalisador extrínseco. De acordo com o método, é possível sintetizar vários éteres e carbonatos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361918795P | 2013-12-20 | 2013-12-20 | |
PCT/US2014/068809 WO2015094716A1 (en) | 2013-12-20 | 2014-12-05 | Synthesis of isohexide ethers and carbonates |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112016014276A2 true BR112016014276A2 (pt) | 2017-08-08 |
Family
ID=53403506
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112016014276A BR112016014276A2 (pt) | 2013-12-20 | 2014-12-05 | Método de alquilação de um composto anidro-açúcar; composto éter; composto alquilado isohexídeo; e composto carbonato |
Country Status (10)
Country | Link |
---|---|
US (2) | US20170002019A1 (pt) |
EP (1) | EP3083638A4 (pt) |
JP (1) | JP2017501147A (pt) |
KR (1) | KR20160101055A (pt) |
CN (1) | CN105873934A (pt) |
AU (1) | AU2014366986A1 (pt) |
BR (1) | BR112016014276A2 (pt) |
CA (1) | CA2934447A1 (pt) |
MX (1) | MX2016008060A (pt) |
WO (1) | WO2015094716A1 (pt) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10407540B2 (en) | 2015-09-08 | 2019-09-10 | Ppg Industries Ohio, Inc. | Composition for optical articles and optical articles made therewith |
MX2019001840A (es) * | 2016-08-16 | 2019-05-09 | Ppg Ind Ohio Inc | Composicion polimerizable para articulos opticos. |
CN111349492B (zh) * | 2020-02-28 | 2021-05-25 | 浙江糖能科技有限公司 | 2,5-四氢呋喃二甲醇脂肪酸二酯在柴油添加剂的应用 |
KR102152693B1 (ko) * | 2020-02-28 | 2020-09-08 | 주식회사 삼양사 | 수율이 개선된 무수당 알코올의 디에테르 제조 방법 |
CN114409668B (zh) * | 2022-01-20 | 2023-06-30 | 上海交通大学医学院附属第九人民医院 | 一种异山梨醇衍生物及基于异山梨醇结构的窝沟封闭剂 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
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US3219529A (en) * | 1962-10-04 | 1965-11-23 | American Cyanamid Co | Stable tetracycline solutions |
DE3421072A1 (de) * | 1984-06-06 | 1985-12-12 | Heinrich Mack Nachf., 7918 Illertissen | 1,4:3,6-dianhydro-hexit-derivate, verfahren zu ihrer herstellung und ihre verwendung als arzneimittel |
US4585649A (en) * | 1984-12-21 | 1986-04-29 | Ici Americas Inc. | Dentifrice formulation and method of treating teeth, mouth and throat therewith to reduce plaque accumulation and irritation |
DE3521809A1 (de) * | 1985-06-19 | 1987-01-02 | Ruetgerswerke Ag | Verfahren zur herstellung von 2,5-dialkyl-1,4 |
US4997843A (en) * | 1987-10-13 | 1991-03-05 | J Uriach & Cia S.A. | 2,4-disubstituted derivatives of tetrahydrofuran useful for the treatment of PAF mediated illnesses |
US4770871A (en) * | 1987-11-06 | 1988-09-13 | Ici Americas Inc. | Process for the preparation of dianhydrosorbitol ethers |
CN1128749A (zh) * | 1995-02-07 | 1996-08-14 | 胜一化工股份有限公司 | 丙二醇单烷基醚酯化合物及其制法 |
IT1286527B1 (it) * | 1996-12-05 | 1998-07-15 | Enichem Spa | Procedimento per la sintesi di 2-idrossi-4-alchilossi benzofenone |
FR2821352B1 (fr) * | 2001-02-23 | 2003-04-25 | Poudres & Explosifs Ste Nale | Procede de synthese de mono-ethers d'aryle et d'alkyle |
WO2003027119A1 (en) * | 2001-09-24 | 2003-04-03 | Koninklijke Philips Electronics N.V. | Isosorbide derivatives |
CN1241888C (zh) * | 2003-12-26 | 2006-02-15 | 南京林业大学 | 丙二醇二甲醚的合成方法 |
US7579335B2 (en) * | 2005-01-10 | 2009-08-25 | Glaxo Group Limited | Androstane 17α-carbonate derivatives for use in the treatment of allergic and inflammatory conditions |
WO2007089455A1 (en) * | 2006-01-27 | 2007-08-09 | E. I. Du Pont De Nemours And Company | Fluoroalkenyl derivatives as insecticides and nematicides |
WO2009120703A2 (en) * | 2008-03-24 | 2009-10-01 | Archer Daniels Midland Co. | Method for preparation of anhydrosugar ethers |
BRPI0803522A2 (pt) * | 2008-09-17 | 2010-06-15 | Petroleo Brasileiro Sa | composições de combustìvel do ciclo diesel contendo dianidrohexitóis e derivados |
CN101475469A (zh) * | 2009-01-20 | 2009-07-08 | 南京林业大学 | 二元醇醚酯的合成方法 |
FR2950892B1 (fr) * | 2009-10-01 | 2011-11-18 | Roquette Freres | Procede de preparation de di(alkylcarbonate) de dianhydrohexitol |
US9090550B2 (en) * | 2010-07-30 | 2015-07-28 | Archer Daniels Midland Company | Microwave assisted synthesis of dehydrated sugar derivatives hydroxymethylfurfural, levulinic acid, anhydrosugar alcohols, and ethers thereof |
GB201202381D0 (en) * | 2012-02-13 | 2012-03-28 | Univ Bangor | Method for preparing a herbicidal compound |
JP6010970B2 (ja) * | 2012-03-29 | 2016-10-19 | 東洋インキScホールディングス株式会社 | 硬化性樹脂組成物およびそれを用いてなる塗料および樹脂被覆金属板 |
US20170355658A1 (en) * | 2014-12-18 | 2017-12-14 | Archer Daniels Midland Company | Co2-mediated etherification of bio-based diols |
-
2014
- 2014-12-05 BR BR112016014276A patent/BR112016014276A2/pt not_active Application Discontinuation
- 2014-12-05 WO PCT/US2014/068809 patent/WO2015094716A1/en active Application Filing
- 2014-12-05 EP EP14872517.9A patent/EP3083638A4/en not_active Withdrawn
- 2014-12-05 CN CN201480071561.9A patent/CN105873934A/zh active Pending
- 2014-12-05 MX MX2016008060A patent/MX2016008060A/es unknown
- 2014-12-05 JP JP2016538562A patent/JP2017501147A/ja active Pending
- 2014-12-05 KR KR1020167019149A patent/KR20160101055A/ko not_active Application Discontinuation
- 2014-12-05 US US15/102,297 patent/US20170002019A1/en not_active Abandoned
- 2014-12-05 AU AU2014366986A patent/AU2014366986A1/en not_active Abandoned
- 2014-12-05 CA CA2934447A patent/CA2934447A1/en not_active Abandoned
- 2014-12-19 US US15/102,298 patent/US9890131B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP3083638A4 (en) | 2017-05-03 |
US20170002019A1 (en) | 2017-01-05 |
EP3083638A1 (en) | 2016-10-26 |
US20170001971A1 (en) | 2017-01-05 |
US9890131B2 (en) | 2018-02-13 |
KR20160101055A (ko) | 2016-08-24 |
JP2017501147A (ja) | 2017-01-12 |
AU2014366986A1 (en) | 2016-06-30 |
WO2015094716A1 (en) | 2015-06-25 |
MX2016008060A (es) | 2017-02-27 |
CN105873934A (zh) | 2016-08-17 |
CA2934447A1 (en) | 2015-06-25 |
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Legal Events
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B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
B11Y | Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette] |