MX2015014652A - Proceso continuo para la preparacion de polimeros muy ramificados en base a acido mono- o dicarboxilico c3-c8 etilenicamente insaturado o sus anhidridos y sales. - Google Patents

Proceso continuo para la preparacion de polimeros muy ramificados en base a acido mono- o dicarboxilico c3-c8 etilenicamente insaturado o sus anhidridos y sales.

Info

Publication number
MX2015014652A
MX2015014652A MX2015014652A MX2015014652A MX2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A
Authority
MX
Mexico
Prior art keywords
anhydrides
salts
highly
manufacture
dicarboxylic acid
Prior art date
Application number
MX2015014652A
Other languages
English (en)
Other versions
MX361798B (es
Inventor
Helmut Witteler
Aaron Flores-Figueroa
Christian Schwede
Christian Schade
Faissal-Ali El-Toufaili
Gledison Fonseca
Michaela Heussler
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2015014652A publication Critical patent/MX2015014652A/es
Publication of MX361798B publication Critical patent/MX361798B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00788—Three-dimensional assemblies, i.e. the reactor comprising a form other than a stack of plates
    • B01J2219/00792—One or more tube-shaped elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00889—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00891—Feeding or evacuation
    • B01J2219/00894—More than two inlets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/04—Acids; Metal salts or ammonium salts thereof
    • C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/10—Esters
    • C08F120/12—Esters of monohydric alcohols or phenols
    • C08F120/14—Methyl esters, e.g. methyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

La presente invención se refiere a un proceso continuo para la preparación de horno- o copolímeros muy ramificados de ácido mono- o dicarboxílico C3-C8 etilénicarnente insaturado, así como sus anhídridos y sales (monómero A) por medio de polimerización de radicales libres de monómero A y opcionalmente comonómeros solubles en agua, monetilénicamente insaturados (monómero B) en un medio acuoso en presencia de al menos un iniciador soluble en agua, en donde la polimerización tiene lugar en al menos un segmento del reactor tubular.
MX2015014652A 2013-04-16 2014-04-07 Proceso continuo para la preparación de polímeros muy ramificados en base a ácido mono- o dicarboxílico c3-c8 etilénicamente insaturado o sus anhídridos y sales. MX361798B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13163900 2013-04-16
PCT/EP2014/056891 WO2014170149A1 (en) 2013-04-16 2014-04-07 Continuous process for the manufacture of highly-branched polymers based on c3-c8 monoethylenically unsaturated mono- or dicarboxylic acid or on the anhydrides and salts thereof

Publications (2)

Publication Number Publication Date
MX2015014652A true MX2015014652A (es) 2016-03-01
MX361798B MX361798B (es) 2018-12-17

Family

ID=48128152

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015014652A MX361798B (es) 2013-04-16 2014-04-07 Proceso continuo para la preparación de polímeros muy ramificados en base a ácido mono- o dicarboxílico c3-c8 etilénicamente insaturado o sus anhídridos y sales.

Country Status (10)

Country Link
US (1) US9481742B2 (es)
EP (1) EP2986648A1 (es)
JP (1) JP2016515657A (es)
KR (1) KR20150143680A (es)
CN (1) CN105143276B (es)
BR (1) BR112015024241A2 (es)
CA (1) CA2899723A1 (es)
MX (1) MX361798B (es)
RU (1) RU2678304C2 (es)
WO (1) WO2014170149A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107849175B (zh) * 2015-07-24 2020-12-04 巴斯夫欧洲公司 在反应器单元系列中制备n-乙烯基羧酰胺
US9434793B1 (en) * 2015-07-24 2016-09-06 Technology Investment & Development, LLC Continuous adiabatic inverse emulsion polymerization process
WO2018007191A1 (de) 2016-07-05 2018-01-11 Basf Se Verwendung von korrosionsinhibitoren für kraft- und schmierstoffe
RU2019106490A (ru) * 2016-08-10 2020-09-11 Басф Се Способ получения полимерной композиции
EP3921385B1 (en) * 2019-02-08 2025-07-30 TouGas Oilfield Solutions GmbH Manufacturing method for inverse emulsion polymer
CN116239734B (zh) * 2021-12-07 2025-10-28 中国石油化工股份有限公司 利用微反应器制备星型嵌段共聚物的方法及应用
EP4292699A1 (de) * 2022-06-17 2023-12-20 Fluitec Invest AG Vorrichtung und verfahren zur durchführung einer nicht-selektiven chemischen reaktion
CN115181201B (zh) * 2022-07-06 2023-10-24 中国石油天然气股份有限公司 一种C4-C8α-单烯烃与马来酸酐的共聚方法
CN115181200B (zh) * 2022-07-06 2023-11-07 中国石油天然气股份有限公司 一种C4-C8α-单烯烃—马来酸酐共聚物的制备方法
CN115850543B (zh) * 2022-09-21 2024-02-06 青岛大学 一种甲基丙烯酸甲酯阴离子聚合连续聚合工艺

Family Cites Families (14)

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US4196272A (en) * 1978-11-27 1980-04-01 Nalco Chemical Company Continuous process for the preparation of an acrylic acid-methyl acrylate copolymer in a tubular reactor
JPH07100776B2 (ja) * 1986-08-12 1995-11-01 藤倉化成株式会社 熱硬化性アクリル樹脂塗料
US5268437A (en) * 1992-01-22 1993-12-07 Rohm And Haas Company High temperature aqueous polymerization process
DE4337481A1 (de) * 1993-11-03 1995-05-04 Basf Ag Radikalisch vernetzbare Copolymerisate
BE1009976A3 (nl) * 1996-01-19 1997-11-04 Dsm Nv Sterk vertakte polymeren.
DE19816886C2 (de) * 1998-04-17 2001-06-07 Axiva Gmbh Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polymerisaten
EP1067352B1 (de) 1999-07-07 2003-08-27 Fluitec Georg AG Vorrichtung für den Wärmetausch
DE10333922B4 (de) 2003-07-25 2005-11-17 Wella Ag Bauteile für statische Mikromischer, daraus aufgebaute Mikromischer und deren Verwendung zum Mischen, zum Dispergieren oder zur Durchführung chemischer Reaktionen
JP4820186B2 (ja) * 2005-03-02 2011-11-24 勲 持田 コークス用粘結材の製造方法
WO2009133186A1 (de) 2008-05-02 2009-11-05 Basf Se Verfahren und vorrichtung zur kontinuierlichen herstellung von polymerisaten durch radikalische polymerisation
JP5591465B2 (ja) * 2008-10-30 2014-09-17 丸善石油化学株式会社 濃度が均一な半導体リソグラフィー用共重合体溶液の製造方法
BR112012010699A2 (pt) 2009-11-04 2016-03-29 Basf Se processo para preparar soluções aquosas de homo- ou copolímeros de ácido acrílico
JP5945829B2 (ja) * 2010-04-01 2016-07-05 ディーピーエックス ファイン ケミカルズ オーストリア ゲーエムベーハー ウント ツェーオー カーゲー 連続乳化重合方法
EP2570180A1 (en) * 2011-09-15 2013-03-20 Bayer MaterialScience AG Method for a continuous radical polymerization using microreactors

Also Published As

Publication number Publication date
BR112015024241A2 (pt) 2017-07-18
RU2678304C2 (ru) 2019-01-25
WO2014170149A1 (en) 2014-10-23
JP2016515657A (ja) 2016-05-30
CN105143276A (zh) 2015-12-09
US9481742B2 (en) 2016-11-01
CA2899723A1 (en) 2014-10-23
CN105143276B (zh) 2018-05-25
RU2015148820A (ru) 2017-05-19
KR20150143680A (ko) 2015-12-23
US20160075801A1 (en) 2016-03-17
EP2986648A1 (en) 2016-02-24
MX361798B (es) 2018-12-17

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