MX361798B - Proceso continuo para la preparación de polímeros muy ramificados en base a ácido mono- o dicarboxílico c3-c8 etilénicamente insaturado o sus anhídridos y sales. - Google Patents
Proceso continuo para la preparación de polímeros muy ramificados en base a ácido mono- o dicarboxílico c3-c8 etilénicamente insaturado o sus anhídridos y sales.Info
- Publication number
- MX361798B MX361798B MX2015014652A MX2015014652A MX361798B MX 361798 B MX361798 B MX 361798B MX 2015014652 A MX2015014652 A MX 2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A MX 361798 B MX361798 B MX 361798B
- Authority
- MX
- Mexico
- Prior art keywords
- anhydrides
- salts
- highly
- manufacture
- dicarboxylic acid
- Prior art date
Links
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 title abstract 2
- 150000008064 anhydrides Chemical class 0.000 title abstract 2
- 238000010924 continuous production Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 title abstract 2
- 150000003839 salts Chemical class 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 3
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00788—Three-dimensional assemblies, i.e. the reactor comprising a form other than a stack of plates
- B01J2219/00792—One or more tube-shaped elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00889—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00891—Feeding or evacuation
- B01J2219/00894—More than two inlets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
- C08F120/14—Methyl esters, e.g. methyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Abstract
La presente invención se refiere a un proceso continuo para la preparación de horno- o copolímeros muy ramificados de ácido mono- o dicarboxílico C3-C8 etilénicarnente insaturado, así como sus anhídridos y sales (monómero A) por medio de polimerización de radicales libres de monómero A y opcionalmente comonómeros solubles en agua, monetilénicamente insaturados (monómero B) en un medio acuoso en presencia de al menos un iniciador soluble en agua, en donde la polimerización tiene lugar en al menos un segmento del reactor tubular.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13163900 | 2013-04-16 | ||
PCT/EP2014/056891 WO2014170149A1 (en) | 2013-04-16 | 2014-04-07 | Continuous process for the manufacture of highly-branched polymers based on c3-c8 monoethylenically unsaturated mono- or dicarboxylic acid or on the anhydrides and salts thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2015014652A MX2015014652A (es) | 2016-03-01 |
MX361798B true MX361798B (es) | 2018-12-17 |
Family
ID=48128152
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015014652A MX361798B (es) | 2013-04-16 | 2014-04-07 | Proceso continuo para la preparación de polímeros muy ramificados en base a ácido mono- o dicarboxílico c3-c8 etilénicamente insaturado o sus anhídridos y sales. |
Country Status (10)
Country | Link |
---|---|
US (1) | US9481742B2 (es) |
EP (1) | EP2986648A1 (es) |
JP (1) | JP2016515657A (es) |
KR (1) | KR20150143680A (es) |
CN (1) | CN105143276B (es) |
BR (1) | BR112015024241A2 (es) |
CA (1) | CA2899723A1 (es) |
MX (1) | MX361798B (es) |
RU (1) | RU2678304C2 (es) |
WO (1) | WO2014170149A1 (es) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3325521A4 (en) * | 2015-07-24 | 2019-01-23 | Basf Se | PREPARATION OF N-VINYLCARBOXYLAMIDES IN SERIES OF REACTOR UNITS |
US9434793B1 (en) * | 2015-07-24 | 2016-09-06 | Technology Investment & Development, LLC | Continuous adiabatic inverse emulsion polymerization process |
PT3481920T (pt) | 2016-07-05 | 2021-11-10 | Basf Se | Utilização de inibidores de corrosão para combustíveis e lubrificantes |
EP3497138A1 (en) * | 2016-08-10 | 2019-06-19 | Basf Se | A process for the preparation of a polymer composition |
EP4292699A1 (de) * | 2022-06-17 | 2023-12-20 | Fluitec Invest AG | Vorrichtung und verfahren zur durchführung einer nicht-selektiven chemischen reaktion |
CN115181200B (zh) * | 2022-07-06 | 2023-11-07 | 中国石油天然气股份有限公司 | 一种C4-C8α-单烯烃—马来酸酐共聚物的制备方法 |
CN115181201B (zh) * | 2022-07-06 | 2023-10-24 | 中国石油天然气股份有限公司 | 一种C4-C8α-单烯烃与马来酸酐的共聚方法 |
CN115850543B (zh) * | 2022-09-21 | 2024-02-06 | 青岛大学 | 一种甲基丙烯酸甲酯阴离子聚合连续聚合工艺 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4196272A (en) * | 1978-11-27 | 1980-04-01 | Nalco Chemical Company | Continuous process for the preparation of an acrylic acid-methyl acrylate copolymer in a tubular reactor |
JPH07100776B2 (ja) * | 1986-08-12 | 1995-11-01 | 藤倉化成株式会社 | 熱硬化性アクリル樹脂塗料 |
US5268437A (en) * | 1992-01-22 | 1993-12-07 | Rohm And Haas Company | High temperature aqueous polymerization process |
DE4337481A1 (de) * | 1993-11-03 | 1995-05-04 | Basf Ag | Radikalisch vernetzbare Copolymerisate |
BE1009976A3 (nl) * | 1996-01-19 | 1997-11-04 | Dsm Nv | Sterk vertakte polymeren. |
DE19816886C2 (de) * | 1998-04-17 | 2001-06-07 | Axiva Gmbh | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polymerisaten |
DE50003420D1 (de) | 1999-07-07 | 2003-10-02 | Fluitec Georg Ag Winterthur | Vorrichtung für den Wärmetausch |
DE10333922B4 (de) | 2003-07-25 | 2005-11-17 | Wella Ag | Bauteile für statische Mikromischer, daraus aufgebaute Mikromischer und deren Verwendung zum Mischen, zum Dispergieren oder zur Durchführung chemischer Reaktionen |
JP4820186B2 (ja) * | 2005-03-02 | 2011-11-24 | 勲 持田 | コークス用粘結材の製造方法 |
MX328675B (es) * | 2008-05-02 | 2015-03-20 | Basf Se | Metodo y dispositivo para la produccion continua de polimeros mediante polimerizacion de radicales. |
JP5591465B2 (ja) * | 2008-10-30 | 2014-09-17 | 丸善石油化学株式会社 | 濃度が均一な半導体リソグラフィー用共重合体溶液の製造方法 |
KR101783494B1 (ko) * | 2009-11-04 | 2017-09-29 | 바스프 에스이 | 폴리아크릴산 수용액의 제조 방법 |
EP2552970B1 (en) * | 2010-04-01 | 2014-07-30 | DSM IP Assets B.V. | Process for continuous emulsion polymerization |
EP2570180A1 (en) * | 2011-09-15 | 2013-03-20 | Bayer MaterialScience AG | Method for a continuous radical polymerization using microreactors |
-
2014
- 2014-04-07 CN CN201480021517.7A patent/CN105143276B/zh not_active Expired - Fee Related
- 2014-04-07 JP JP2016508081A patent/JP2016515657A/ja active Pending
- 2014-04-07 RU RU2015148820A patent/RU2678304C2/ru not_active IP Right Cessation
- 2014-04-07 BR BR112015024241A patent/BR112015024241A2/pt active Search and Examination
- 2014-04-07 KR KR1020157032416A patent/KR20150143680A/ko active IP Right Grant
- 2014-04-07 WO PCT/EP2014/056891 patent/WO2014170149A1/en active Application Filing
- 2014-04-07 EP EP14717716.6A patent/EP2986648A1/en not_active Withdrawn
- 2014-04-07 MX MX2015014652A patent/MX361798B/es active IP Right Grant
- 2014-04-07 CA CA2899723A patent/CA2899723A1/en not_active Abandoned
- 2014-04-07 US US14/784,305 patent/US9481742B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
JP2016515657A (ja) | 2016-05-30 |
WO2014170149A1 (en) | 2014-10-23 |
RU2678304C2 (ru) | 2019-01-25 |
US20160075801A1 (en) | 2016-03-17 |
KR20150143680A (ko) | 2015-12-23 |
US9481742B2 (en) | 2016-11-01 |
CA2899723A1 (en) | 2014-10-23 |
MX2015014652A (es) | 2016-03-01 |
RU2015148820A (ru) | 2017-05-19 |
BR112015024241A2 (pt) | 2017-07-18 |
CN105143276B (zh) | 2018-05-25 |
CN105143276A (zh) | 2015-12-09 |
EP2986648A1 (en) | 2016-02-24 |
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Legal Events
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FG | Grant or registration |