MX2015014652A - Continuous process for the manufacture of highly-branched polymers based on c3-c8 monoethylenically unsaturated mono- or dicarboxylic acid or on the anhydrides and salts thereof. - Google Patents

Continuous process for the manufacture of highly-branched polymers based on c3-c8 monoethylenically unsaturated mono- or dicarboxylic acid or on the anhydrides and salts thereof.

Info

Publication number
MX2015014652A
MX2015014652A MX2015014652A MX2015014652A MX2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A MX 2015014652 A MX2015014652 A MX 2015014652A
Authority
MX
Mexico
Prior art keywords
anhydrides
salts
highly
manufacture
dicarboxylic acid
Prior art date
Application number
MX2015014652A
Other languages
Spanish (es)
Other versions
MX361798B (en
Inventor
Helmut Witteler
Aaron Flores-Figueroa
Christian Schwede
Christian Schade
Faissal-Ali El-Toufaili
Gledison Fonseca
Michaela Heussler
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2015014652A publication Critical patent/MX2015014652A/en
Publication of MX361798B publication Critical patent/MX361798B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00788—Three-dimensional assemblies, i.e. the reactor comprising a form other than a stack of plates
    • B01J2219/00792—One or more tube-shaped elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00889—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00891—Feeding or evacuation
    • B01J2219/00894—More than two inlets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/04—Acids; Metal salts or ammonium salts thereof
    • C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/10—Esters
    • C08F120/12—Esters of monohydric alcohols or phenols
    • C08F120/14—Methyl esters, e.g. methyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

The present invention relates to a continuous process for the manufacture of highly-branched homo- or copolymers of C3-C8 ethylenically unsaturated mono- or dicarboxylic acid as well as the anhydrides and salts thereof (monomer A) by means of free-radical polymerization of monomer A and optionally water-soluble, monethylenically unsaturated comonomers (monomer B) in an aqueous medium in the presence of at least one water-soluble initiator, wherein the polymerization takes place in at least one tubular reactor segment.
MX2015014652A 2013-04-16 2014-04-07 Continuous process for the manufacture of highly-branched polymers based on c3-c8 monoethylenically unsaturated mono- or dicarboxylic acid or on the anhydrides and salts thereof. MX361798B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13163900 2013-04-16
PCT/EP2014/056891 WO2014170149A1 (en) 2013-04-16 2014-04-07 Continuous process for the manufacture of highly-branched polymers based on c3-c8 monoethylenically unsaturated mono- or dicarboxylic acid or on the anhydrides and salts thereof

Publications (2)

Publication Number Publication Date
MX2015014652A true MX2015014652A (en) 2016-03-01
MX361798B MX361798B (en) 2018-12-17

Family

ID=48128152

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015014652A MX361798B (en) 2013-04-16 2014-04-07 Continuous process for the manufacture of highly-branched polymers based on c3-c8 monoethylenically unsaturated mono- or dicarboxylic acid or on the anhydrides and salts thereof.

Country Status (10)

Country Link
US (1) US9481742B2 (en)
EP (1) EP2986648A1 (en)
JP (1) JP2016515657A (en)
KR (1) KR20150143680A (en)
CN (1) CN105143276B (en)
BR (1) BR112015024241A2 (en)
CA (1) CA2899723A1 (en)
MX (1) MX361798B (en)
RU (1) RU2678304C2 (en)
WO (1) WO2014170149A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9434793B1 (en) * 2015-07-24 2016-09-06 Technology Investment & Development, LLC Continuous adiabatic inverse emulsion polymerization process
US10479851B2 (en) 2015-07-24 2019-11-19 Base Se Preparation of N-vinyl carboxamides in a series of reactor units
US11078418B2 (en) 2016-07-05 2021-08-03 Basf Se Corrosion inhibitors for fuels and lubricants
EP3497138A1 (en) * 2016-08-10 2019-06-19 Basf Se A process for the preparation of a polymer composition
EP4292699A1 (en) * 2022-06-17 2023-12-20 Fluitec Invest AG Apparatus and method for carrying out a non-selective chemical reaction
CN115181200B (en) * 2022-07-06 2023-11-07 中国石油天然气股份有限公司 Preparation method of C4-C8 alpha-mono-olefin-maleic anhydride copolymer
CN115181201B (en) * 2022-07-06 2023-10-24 中国石油天然气股份有限公司 Copolymerization method of C4-C8 alpha-mono-olefin and maleic anhydride
CN115850543B (en) * 2022-09-21 2024-02-06 青岛大学 Anionic polymerization continuous polymerization process for methyl methacrylate

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4196272A (en) * 1978-11-27 1980-04-01 Nalco Chemical Company Continuous process for the preparation of an acrylic acid-methyl acrylate copolymer in a tubular reactor
JPH07100776B2 (en) * 1986-08-12 1995-11-01 藤倉化成株式会社 Thermosetting acrylic resin paint
US5268437A (en) * 1992-01-22 1993-12-07 Rohm And Haas Company High temperature aqueous polymerization process
DE4337481A1 (en) * 1993-11-03 1995-05-04 Basf Ag Radically crosslinkable copolymers
BE1009976A3 (en) * 1996-01-19 1997-11-04 Dsm Nv Highly branched polymers.
DE19816886C2 (en) * 1998-04-17 2001-06-07 Axiva Gmbh Process and device for the continuous production of polymers
ATE248345T1 (en) 1999-07-07 2003-09-15 Fluitec Georg Ag HEAT EXCHANGE DEVICE
DE10333922B4 (en) 2003-07-25 2005-11-17 Wella Ag Components for static micromixers, micromixers constructed therefrom and their use for mixing, dispersing or for carrying out chemical reactions
JP4820186B2 (en) * 2005-03-02 2011-11-24 勲 持田 Method for producing coking binder
CA2725418C (en) 2008-05-02 2016-07-12 Basf Se Method and device for the continuous production of polymers by radical polymerization
JP5591465B2 (en) * 2008-10-30 2014-09-17 丸善石油化学株式会社 Method for producing copolymer solution for semiconductor lithography having uniform concentration
ES2572763T3 (en) * 2009-11-04 2016-06-02 Basf Se Process for the preparation of aqueous solutions of poly (acrylic acid)
WO2011121124A1 (en) * 2010-04-01 2011-10-06 Dsm Ip Assets B.V. Process for continuous emulsion polymerization
EP2570180A1 (en) * 2011-09-15 2013-03-20 Bayer MaterialScience AG Method for a continuous radical polymerization using microreactors

Also Published As

Publication number Publication date
BR112015024241A2 (en) 2017-07-18
KR20150143680A (en) 2015-12-23
US9481742B2 (en) 2016-11-01
RU2678304C2 (en) 2019-01-25
CN105143276B (en) 2018-05-25
WO2014170149A1 (en) 2014-10-23
EP2986648A1 (en) 2016-02-24
RU2015148820A (en) 2017-05-19
US20160075801A1 (en) 2016-03-17
MX361798B (en) 2018-12-17
JP2016515657A (en) 2016-05-30
CA2899723A1 (en) 2014-10-23
CN105143276A (en) 2015-12-09

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