MX2013000065A - Proceso para la manufactura de olefinas fluoradas. - Google Patents
Proceso para la manufactura de olefinas fluoradas.Info
- Publication number
- MX2013000065A MX2013000065A MX2013000065A MX2013000065A MX2013000065A MX 2013000065 A MX2013000065 A MX 2013000065A MX 2013000065 A MX2013000065 A MX 2013000065A MX 2013000065 A MX2013000065 A MX 2013000065A MX 2013000065 A MX2013000065 A MX 2013000065A
- Authority
- MX
- Mexico
- Prior art keywords
- formula
- compound
- metal
- group
- reaction
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 36
- 150000001336 alkenes Chemical class 0.000 title description 7
- 238000004519 manufacturing process Methods 0.000 title description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 72
- 150000001875 compounds Chemical class 0.000 claims abstract description 64
- 238000006356 dehydrogenation reaction Methods 0.000 claims abstract description 32
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical compound FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 claims abstract description 11
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims description 88
- 229910052751 metal Inorganic materials 0.000 claims description 38
- 239000002184 metal Substances 0.000 claims description 38
- 229910001512 metal fluoride Inorganic materials 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 11
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 229910000510 noble metal Inorganic materials 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 6
- 150000002222 fluorine compounds Chemical class 0.000 claims description 6
- 239000007800 oxidant agent Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 229910052741 iridium Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 abstract description 14
- 150000004812 organic fluorine compounds Chemical class 0.000 abstract description 5
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 description 15
- 230000003197 catalytic effect Effects 0.000 description 15
- 238000005796 dehydrofluorination reaction Methods 0.000 description 11
- 239000000843 powder Substances 0.000 description 10
- 239000007795 chemical reaction product Substances 0.000 description 9
- 239000000725 suspension Substances 0.000 description 9
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000001354 calcination Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 239000003518 caustics Substances 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 238000005984 hydrogenation reaction Methods 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZDCWZRQSHBQRGN-UHFFFAOYSA-N 1,1,1,2,3-pentafluoropropane Chemical compound FCC(F)C(F)(F)F ZDCWZRQSHBQRGN-UHFFFAOYSA-N 0.000 description 2
- INEMUVRCEAELBK-UHFFFAOYSA-N 1,1,1,2-tetrafluoropropane Chemical compound CC(F)C(F)(F)F INEMUVRCEAELBK-UHFFFAOYSA-N 0.000 description 2
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 2
- 238000010574 gas phase reaction Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- FDOPVENYMZRARC-UHFFFAOYSA-N 1,1,1,2,2-pentafluoropropane Chemical class CC(F)(F)C(F)(F)F FDOPVENYMZRARC-UHFFFAOYSA-N 0.000 description 1
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
- PFFGXVGPSGJOBV-UHFFFAOYSA-N 1,1,1,3-tetrafluoropropane Chemical compound FCCC(F)(F)F PFFGXVGPSGJOBV-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 229910000792 Monel Inorganic materials 0.000 description 1
- 229910002666 PdCl2 Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006704 dehydrohalogenation reaction Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
- C07C17/04—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
- C07C17/354—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
- C07C17/357—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by dehydrogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/822,365 US8513474B2 (en) | 2010-06-24 | 2010-06-24 | Process for the manufacture of fluorinated olefins |
| PCT/US2011/041323 WO2011163285A2 (en) | 2010-06-24 | 2011-06-22 | Process for the manufacture of fluorinated olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2013000065A true MX2013000065A (es) | 2013-02-15 |
Family
ID=45353142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013000065A MX2013000065A (es) | 2010-06-24 | 2011-06-22 | Proceso para la manufactura de olefinas fluoradas. |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US8513474B2 (enExample) |
| EP (3) | EP2585424B1 (enExample) |
| JP (3) | JP5886841B2 (enExample) |
| CN (2) | CN105037077B (enExample) |
| ES (2) | ES2890024T3 (enExample) |
| HR (1) | HRP20211696T1 (enExample) |
| HU (1) | HUE056296T2 (enExample) |
| MX (1) | MX2013000065A (enExample) |
| PL (1) | PL3269698T3 (enExample) |
| PT (1) | PT3269698T (enExample) |
| SI (1) | SI3269698T1 (enExample) |
| WO (1) | WO2011163285A2 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9187386B2 (en) * | 2013-05-23 | 2015-11-17 | The Chemours Company Fc, Llc | Catalytic process of making 1,3,3,3-tetrafluoropropene |
| WO2016025288A1 (en) | 2014-08-14 | 2016-02-18 | The Chemours Company Fc, Llc | Process for the production of e-1,3,3,3-tetrafluoropropene (hfc-1234ze) by dehydrofluorinatiokl |
| JP6052340B2 (ja) * | 2015-05-29 | 2016-12-27 | ダイキン工業株式会社 | 含フッ素化合物含有組成物の製造方法 |
| CN112811978B (zh) * | 2021-04-22 | 2021-07-16 | 泉州宇极新材料科技有限公司 | Z-1,3,3,3-四氟丙烯的制备方法 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2500920A (en) | 1946-07-16 | 1950-03-21 | Phillips Petroleum Co | Process and catalyst for dehydrogenation of hydrocarbons |
| US2757128A (en) | 1951-04-27 | 1956-07-31 | Exxon Research Engineering Co | Low pressure hydrogenation and hydrogen regeneration of the catalyst |
| US3140925A (en) | 1960-05-19 | 1964-07-14 | California Research Corp | Hydrocarbon conversion catalyst |
| JPH0717550B2 (ja) * | 1986-09-30 | 1995-03-01 | 旭化成工業株式会社 | フルオロベンゼンの製造法 |
| CA2019914C (en) | 1989-07-06 | 1999-06-08 | Maher Yousef Elsheikh | Dehydrofluorination and dehydrogenation of fluorinated alkanes |
| CA2019913A1 (en) * | 1990-06-08 | 1991-12-08 | Michael S. Bolmer | Production of vinylidene fluoride from 1,1-difluoroethane |
| US5087777A (en) * | 1990-12-04 | 1992-02-11 | Allied-Signal Inc. | Partially fluorinated alkenes having a tertiary structure |
| ID22582A (id) | 1998-05-18 | 1999-11-18 | Nippon Catalytic Chem Ind | Katalis dehidrogenasi oksidasi alkana rendah dan proses untuk memproduksi olefin |
| US20050124840A1 (en) | 2003-12-05 | 2005-06-09 | Conocophillips Company | Process for the production of olefins from alkanes with carbon monoxide co-feed and/or recycle |
| US7026520B1 (en) | 2004-12-09 | 2006-04-11 | Honeywell International Inc. | Catalytic conversion of hydrofluoroalkanol to hydrofluoroalkene |
| WO2007019358A2 (en) | 2005-08-05 | 2007-02-15 | E. I. Du Pont De Nemours And Company | Process for the preparation of 1,3,3,3-tetrafluoropropene and/or 1,1,3,3,3-pentafluoropropene |
| US7560602B2 (en) * | 2005-11-03 | 2009-07-14 | Honeywell International Inc. | Process for manufacture of fluorinated olefins |
| US7335804B2 (en) | 2005-11-03 | 2008-02-26 | Honeywell International Inc. | Direct conversion of HCFC 225ca/cb mixture |
| US8766020B2 (en) * | 2008-07-31 | 2014-07-01 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| EP2028172B1 (en) | 2006-06-13 | 2014-11-05 | Central Glass Co., Ltd. | Method for producing 1,3,3,3-tetrafluoropropene |
| EP2041054B1 (en) | 2006-07-13 | 2014-08-27 | E.I. Du Pont De Nemours And Company | Catalytic production processes for making 1,2,3,3,3-pentafluoropropene |
| ES2447037T3 (es) | 2006-09-05 | 2014-03-11 | E.I. Du Pont De Nemours And Company | Procedimiento de fabricación de 2,3,3,3-tetrafluoropropeno |
| US7420094B2 (en) | 2006-09-05 | 2008-09-02 | E.I. Du Pont De Nemours And Company | Catalytic isomerization processes of 1,3,3,3-tetrafluoropropene for making 2,3,3,3-tetrafluoropropene |
| GB0806422D0 (en) | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
| US8013194B2 (en) * | 2008-03-14 | 2011-09-06 | Honeywell International Inc. | Process for the manufacture of fluorinated olefins |
| CN101535222B (zh) | 2006-10-31 | 2013-02-06 | 纳幕尔杜邦公司 | 氟丙烷和卤代丙烯的制备方法 |
| EP2185489B1 (en) | 2007-09-11 | 2013-03-20 | Daikin Industries, Ltd. | Process for producing 2,3,3,3-tetrafluoropropene |
| US8044250B2 (en) | 2007-11-16 | 2011-10-25 | Honeywell International Inc. | Manufacture of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2-tetrafluoropropane via catalytic hydrogenation |
| GB0801209D0 (en) | 2008-01-23 | 2008-02-27 | Ineos Fluor Holdings Ltd | Process |
| GB0806389D0 (en) | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
| GB0806419D0 (en) | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
| CN102015956B (zh) | 2008-05-07 | 2014-06-11 | 纳幕尔杜邦公司 | 包含1,1,1,2,3-五氟丙烷或2,3,3,3-四氟丙烯的组合物 |
| GB0808836D0 (en) | 2008-05-15 | 2008-06-18 | Ineos Fluor Ltd | Process |
| FR2946644B1 (fr) | 2009-06-12 | 2011-10-14 | Arkema France | Procede de fabrication du pentafluoropropane. |
| FR2948362B1 (fr) | 2009-07-23 | 2012-03-23 | Arkema France | Procede de preparation de composes fluores |
| US8129574B2 (en) | 2009-08-31 | 2012-03-06 | Honeywell International Inc. | Hydrogenation process for fluorocarbons |
| US8158549B2 (en) | 2009-09-04 | 2012-04-17 | Honeywell International Inc. | Catalysts for fluoroolefins hydrogenation |
| US8486293B2 (en) * | 2009-10-30 | 2013-07-16 | E I Du Pont De Nemours And Company | Hydrogen fluoride-HFC-254eb azeotrope and its uses |
-
2010
- 2010-06-24 US US12/822,365 patent/US8513474B2/en active Active
-
2011
- 2011-06-22 PL PL17170975T patent/PL3269698T3/pl unknown
- 2011-06-22 EP EP11798788.3A patent/EP2585424B1/en not_active Not-in-force
- 2011-06-22 PT PT171709751T patent/PT3269698T/pt unknown
- 2011-06-22 WO PCT/US2011/041323 patent/WO2011163285A2/en not_active Ceased
- 2011-06-22 SI SI201132008T patent/SI3269698T1/sl unknown
- 2011-06-22 HR HRP20211696TT patent/HRP20211696T1/hr unknown
- 2011-06-22 CN CN201510355950.0A patent/CN105037077B/zh not_active Expired - Fee Related
- 2011-06-22 CN CN201180040537.5A patent/CN103038198B/zh not_active Expired - Fee Related
- 2011-06-22 ES ES17170975T patent/ES2890024T3/es active Active
- 2011-06-22 JP JP2013516706A patent/JP5886841B2/ja active Active
- 2011-06-22 ES ES11798788.3T patent/ES2632189T3/es active Active
- 2011-06-22 HU HUE17170975A patent/HUE056296T2/hu unknown
- 2011-06-22 EP EP17170975.1A patent/EP3269698B1/en active Active
- 2011-06-22 EP EP21178869.0A patent/EP3915967A1/en active Pending
- 2011-06-22 MX MX2013000065A patent/MX2013000065A/es active IP Right Grant
-
2013
- 2013-07-17 US US13/944,207 patent/US8940948B2/en active Active
-
2015
- 2015-11-26 JP JP2015230340A patent/JP2016074702A/ja active Pending
-
2017
- 2017-04-24 JP JP2017085023A patent/JP6367418B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103038198A (zh) | 2013-04-10 |
| HRP20211696T1 (hr) | 2022-03-04 |
| CN103038198B (zh) | 2015-11-25 |
| EP3269698B1 (en) | 2021-08-04 |
| JP2017200907A (ja) | 2017-11-09 |
| US8940948B2 (en) | 2015-01-27 |
| WO2011163285A3 (en) | 2012-03-29 |
| JP6367418B2 (ja) | 2018-08-01 |
| JP2013529640A (ja) | 2013-07-22 |
| CN105037077B (zh) | 2017-12-22 |
| ES2890024T3 (es) | 2022-01-17 |
| US20110319674A1 (en) | 2011-12-29 |
| US8513474B2 (en) | 2013-08-20 |
| EP2585424A4 (en) | 2014-01-08 |
| EP3915967A1 (en) | 2021-12-01 |
| PL3269698T3 (pl) | 2022-01-17 |
| US20130303808A1 (en) | 2013-11-14 |
| EP2585424B1 (en) | 2017-05-17 |
| EP2585424A2 (en) | 2013-05-01 |
| ES2632189T3 (es) | 2017-09-11 |
| WO2011163285A2 (en) | 2011-12-29 |
| EP3269698A1 (en) | 2018-01-17 |
| CN105037077A (zh) | 2015-11-11 |
| PT3269698T (pt) | 2021-09-08 |
| JP2016074702A (ja) | 2016-05-12 |
| SI3269698T1 (sl) | 2021-11-30 |
| JP5886841B2 (ja) | 2016-03-16 |
| HUE056296T2 (hu) | 2022-02-28 |
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