MX2012001522A - Metodo y aparato para producir una corriente que contiene hidrocarburo tratado para uso como alimentacion en una planta de hidrogeno que tiene un reformador de vapor de metano. - Google Patents

Metodo y aparato para producir una corriente que contiene hidrocarburo tratado para uso como alimentacion en una planta de hidrogeno que tiene un reformador de vapor de metano.

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Publication number
MX2012001522A
MX2012001522A MX2012001522A MX2012001522A MX2012001522A MX 2012001522 A MX2012001522 A MX 2012001522A MX 2012001522 A MX2012001522 A MX 2012001522A MX 2012001522 A MX2012001522 A MX 2012001522A MX 2012001522 A MX2012001522 A MX 2012001522A
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Mexico
Prior art keywords
olefins
reactor
hydrogenation
hydrotreater
promoting
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MX2012001522A
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English (en)
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Raymond Francis Drnevich
Vasilis Papavassiliou
Troy M Raybold
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Praxair Technology Inc
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Publication of MX2012001522A publication Critical patent/MX2012001522A/es

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/02Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by hydrogenation
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
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    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
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    • C01B2203/045Purification by catalytic desulfurisation
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    • C01B2203/0465Composition of the impurity
    • C01B2203/0485Composition of the impurity the impurity being a sulfur compound
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    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
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    • C01B2203/0894Generation of steam
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    • C01B2203/10Catalysts for performing the hydrogen forming reactions
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    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
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    • C01B2203/169Controlling the feed
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1025Natural gas
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10G2300/1088Olefins
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    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
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    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/207Acid gases, e.g. H2S, COS, SO2, HCN

Abstract

La presente invención proporciona un método y aparato para producir una corriente que contiene hidrocarburo tratado para uso como una alimentación de un reformador de vapor de metano de una planta de hidrógeno. De acuerdo con este método, las cantidades de olefinas y especies de sulfuro orgánico dentro de una alimentación no tratada son disminuidas en un reactor que es operado sea en modo de hidrogenación para hidrogenar las olefinas en hidrocarburos saturados o un modo pre-reformador en el cual el hidrocarburo que contiene dos o más átomos de carbono incluyendo las olefinas son reaccionadas con oxígeno y el vapor para formar hidrocarburos saturados, metano, hidrógeno adicional y monóxido de carbono. El reactor es configurado y opera en una velocidad de espacio suficientemente alta que el deslizamiento de olefina y especies orgánicas ocurre y son posteriormente tratados en un hidrotratador. El reactor contiene un catalizador capaz de promover tanto la reacción de hidrogenación como la de oxidación y el hidrotratador contiene un catalizador que es capaz de únicamente promover las reacciones de hidrogenación.
MX2012001522A 2009-08-04 2010-07-16 Metodo y aparato para producir una corriente que contiene hidrocarburo tratado para uso como alimentacion en una planta de hidrogeno que tiene un reformador de vapor de metano. MX2012001522A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/535,051 US8409427B2 (en) 2009-08-04 2009-08-04 Hydrocarbon treatment method and apparatus
PCT/US2010/042273 WO2011016970A2 (en) 2009-08-04 2010-07-16 Hydrocarbon treatment method and apparatus

Publications (1)

Publication Number Publication Date
MX2012001522A true MX2012001522A (es) 2012-02-29

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MX2012001522A MX2012001522A (es) 2009-08-04 2010-07-16 Metodo y aparato para producir una corriente que contiene hidrocarburo tratado para uso como alimentacion en una planta de hidrogeno que tiene un reformador de vapor de metano.

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Country Link
US (1) US8409427B2 (es)
EP (1) EP2462205B1 (es)
KR (1) KR101753425B1 (es)
CN (1) CN102471705B (es)
BR (1) BR112012002315A2 (es)
CA (1) CA2769916C (es)
ES (1) ES2638455T3 (es)
MX (1) MX2012001522A (es)
WO (1) WO2011016970A2 (es)

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EP3330221B1 (de) * 2016-12-05 2019-09-11 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Verfahren und vorrichtung zum herstellen eines feedstroms für eine dampfreformierungsanlage
EP3330220B1 (de) 2016-12-05 2019-08-07 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Verfahren zum herstellen eines feedstroms für eine dampfreformierungsanlage
CN111411001B (zh) * 2020-04-20 2020-12-29 广东石油化工学院 一种用于甲烷转化的促进装置及其促进方法

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WO2011016970A3 (en) 2011-12-29
KR20120089441A (ko) 2012-08-10
WO2011016970A2 (en) 2011-02-10
US20110034745A1 (en) 2011-02-10
CA2769916C (en) 2017-08-15
BR112012002315A2 (pt) 2016-05-31
EP2462205A2 (en) 2012-06-13
CN102471705A (zh) 2012-05-23
KR101753425B1 (ko) 2017-07-03
US8409427B2 (en) 2013-04-02
CN102471705B (zh) 2014-10-29
EP2462205B1 (en) 2017-05-31
ES2638455T3 (es) 2017-10-20
CA2769916A1 (en) 2011-02-10

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