EA201891683A1 - Способы получения углерода и водорода из природного газа и других углеводородов - Google Patents

Способы получения углерода и водорода из природного газа и других углеводородов

Info

Publication number
EA201891683A1
EA201891683A1 EA201891683A EA201891683A EA201891683A1 EA 201891683 A1 EA201891683 A1 EA 201891683A1 EA 201891683 A EA201891683 A EA 201891683A EA 201891683 A EA201891683 A EA 201891683A EA 201891683 A1 EA201891683 A1 EA 201891683A1
Authority
EA
Eurasian Patent Office
Prior art keywords
natural gas
hydrogen
hydrocarbons
methods
producing carbon
Prior art date
Application number
EA201891683A
Other languages
English (en)
Inventor
Альфред Х. Стиллер
Original Assignee
Вест Верджиния Юниверсити Ресеч Корпорейшен
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Вест Верджиния Юниверсити Ресеч Корпорейшен filed Critical Вест Верджиния Юниверсити Ресеч Корпорейшен
Publication of EA201891683A1 publication Critical patent/EA201891683A1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C01B32/205—Preparation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0272—Processes for making hydrogen or synthesis gas containing a decomposition step containing a non-catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ получения элементарного углерода и газообразного водорода непосредственно из углеводорода (например, природного газа или метана) с использованием химической реакции или серий реакций. В одном аспекте, другие вещества, которые были включены, такие как, например, элементарный магний, остаются неизменными и действуют в качестве катализатора.
EA201891683A 2016-02-01 2017-01-25 Способы получения углерода и водорода из природного газа и других углеводородов EA201891683A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662289566P 2016-02-01 2016-02-01
PCT/US2017/014955 WO2017136205A1 (en) 2016-02-01 2017-01-25 Methods for production of carbon and hydrogen from natural gas and other hydrocarbons

Publications (1)

Publication Number Publication Date
EA201891683A1 true EA201891683A1 (ru) 2019-02-28

Family

ID=58054503

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201891683A EA201891683A1 (ru) 2016-02-01 2017-01-25 Способы получения углерода и водорода из природного газа и других углеводородов

Country Status (17)

Country Link
US (3) US10207922B2 (ru)
EP (1) EP3411141A1 (ru)
JP (1) JP2019504758A (ru)
KR (1) KR20180111864A (ru)
CN (1) CN108698021A (ru)
AR (1) AR107486A1 (ru)
AU (1) AU2017214286B2 (ru)
BR (1) BR112018015655A2 (ru)
CA (1) CA3013204A1 (ru)
CO (1) CO2018008014A2 (ru)
EA (1) EA201891683A1 (ru)
IL (1) IL260848A (ru)
MX (1) MX2018009385A (ru)
SG (1) SG11201806447XA (ru)
TW (1) TW201800332A (ru)
WO (1) WO2017136205A1 (ru)
ZA (1) ZA201805119B (ru)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11814285B2 (en) 2017-11-16 2023-11-14 The Regents Of The University Of California Simultaneous reaction and separation of chemicals
CA3096297A1 (en) * 2018-04-09 2019-10-17 Shell Internationale Research Maatschappij B.V. Pyrolysis of methane with a molten salt based catalyst system
JP7315578B2 (ja) * 2018-04-09 2023-07-26 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 水素および炭素生成物を生成するプロセス
WO2019226416A1 (en) * 2018-05-21 2019-11-28 The Regents Of The University Of California Natural gas conversion to chemicals and power with molten salts
CN109569473B (zh) * 2018-11-21 2020-11-24 太原理工大学 一种液态金属催化烃生产氢气和炭黑的装置及方法
BR112021012136B1 (pt) * 2018-12-21 2023-10-31 Performance Nanocarbon,Inc. Método para produzir um grafeno ou material semelhante ao grafeno
EP3693337A1 (en) * 2019-02-05 2020-08-12 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk Onderzoek TNO Use of molten salt to separate carbon from a molten metal catalyst
CA3151402A1 (en) * 2019-09-19 2021-03-25 Bernard De Waal ESTERHUYSE Furnace, fluid feed component, fluid reforming system and method of reforming a fluid
US11685651B2 (en) 2019-10-25 2023-06-27 Mark Kevin Robertson Catalytic decomposition of hydrocarbons for the production of hydrogen and carbon
JP7353172B2 (ja) * 2019-12-27 2023-09-29 三菱重工業株式会社 水素及びカーボンを製造する方法
CN115515895A (zh) * 2020-05-19 2022-12-23 国立大学法人静冈大学 反应系统、捕集固体碳的方法、制造含氢气气体的方法、催化剂组及固体碳捕集用催化剂
KR102590997B1 (ko) * 2021-10-13 2023-10-19 한국화학연구원 탄화수소 촉매 열분해 반응을 위한 2개 층 이상의 용융물을 포함하는 기포탑 반응기

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2760847A (en) * 1951-11-13 1956-08-28 Houdry Process Corp Production of hydrogen and carbon
US4317659A (en) * 1980-01-24 1982-03-02 Westinghouse Electric Corp. Production of hydrogen, acetylene and ammonia gases from lithium reaction with hydrocarbon materials
US5767165A (en) * 1995-03-16 1998-06-16 Steinberg; Meyer Method for converting natural gas and carbon dioxide to methanol and reducing CO2 emissions
US6218326B1 (en) * 1998-07-29 2001-04-17 University Of Iowa Research Foundation Supported molten-metal catalysts
WO2001046067A1 (en) 1999-12-21 2001-06-28 Bechtel Bwxt Idaho, Llc Hydrogen and elemental carbon production from natural gas and other hydrocarbons
US6670058B2 (en) 2000-04-05 2003-12-30 University Of Central Florida Thermocatalytic process for CO2-free production of hydrogen and carbon from hydrocarbons
JP2004074584A (ja) 2002-08-19 2004-03-11 Sony Corp 可逆性多色記録媒体、及びこれを用いた記録方法
US7001586B2 (en) 2003-09-23 2006-02-21 Catalytic Materials, Llc CO-free hydrogen from decomposition of methane
US6995115B2 (en) 2003-09-23 2006-02-07 Catalytic Materials, Llc Catalyst for the generation of CO-free hydrogen from methane
EP1623957B1 (de) 2005-02-10 2008-02-06 Electrovac AG Verfahren und Vorrichtung zur Herstellung von Wasserstoff
AT502901B1 (de) 2005-10-31 2009-08-15 Electrovac Ag Vorrichtung zur wasserstoffherstellung
CN100439238C (zh) * 2005-12-14 2008-12-03 微宏科技（湖州）有限公司 金属镁及其掺杂其他金属的混合物催化分解碳氢化合物制氢
US8092778B2 (en) 2007-01-24 2012-01-10 Eden Energy Ltd. Method for producing a hydrogen enriched fuel and carbon nanotubes using microwave assisted methane decomposition on catalyst
US9764958B2 (en) 2013-03-15 2017-09-19 West Virginia University Research Corporation Process for pure carbon production, compositions, and methods thereof
WO2016064713A2 (en) 2014-10-21 2016-04-28 West Virginia University Research Corporation Methods and apparatuses for production of carbon, carbide electrodes, and carbon compositions

Also Published As

Publication number Publication date
EP3411141A1 (en) 2018-12-12
TW201800332A (zh) 2018-01-01
CA3013204A1 (en) 2017-08-10
US20170217772A1 (en) 2017-08-03
CN108698021A (zh) 2018-10-23
US20210114869A1 (en) 2021-04-22
BR112018015655A2 (pt) 2018-12-26
SG11201806447XA (en) 2018-08-30
KR20180111864A (ko) 2018-10-11
CO2018008014A2 (es) 2018-08-10
JP2019504758A (ja) 2019-02-21
MX2018009385A (es) 2018-09-05
IL260848A (en) 2018-11-29
ZA201805119B (en) 2019-10-30
US10906807B2 (en) 2021-02-02
US20190241433A1 (en) 2019-08-08
AR107486A1 (es) 2018-05-02
US10207922B2 (en) 2019-02-19
AU2017214286B2 (en) 2021-03-11
WO2017136205A1 (en) 2017-08-10
AU2017214286A1 (en) 2018-08-16

Similar Documents

Publication Publication Date Title
EA201891683A1 (ru) Способы получения углерода и водорода из природного газа и других углеводородов
PH12014501550B1 (en) Process and system for generating synthesis gas
SA521421462B1 (ar) الاقتران المؤكسد لطرق وأنظمة الميثان
CR20130574A (es) Aparato y método para la eliminación de alquitrán del gas de síntesis
WO2015081122A3 (en) Reactors and systems for oxidative coupling of methane
EA201891590A1 (ru) Способ получения водорода in-situ из подземных углеводородных пластов
EA201691756A1 (ru) Способ получения синтез-газа
MX2012001522A (es) Metodo y aparato para producir una corriente que contiene hidrocarburo tratado para uso como alimentacion en una planta de hidrogeno que tiene un reformador de vapor de metano.
EA201891404A1 (ru) Способ получения диоксида углерода для синтеза мочевины
EA201791893A1 (ru) Связывание диоксида углерода посредством гидроксида магния и регенерация гидроксида магния
EA201790133A1 (ru) Способ конверсии природного газа в более высокомолекулярный углеводород (углеводороды)
EA201590045A1 (ru) Способ реформинга углеводородов и способ инициирования процесса газ-в-жидкость
MY174114A (en) Processing vacuum residuum and vacuum gas oil in ebullated bed reactor systems
MX2015000363A (es) Tioeterificacion de mercaptanos en mezclas de hidrocarburos c4.
PH12018502739A1 (en) Method for producing dna library and method for analyzing genomic dna using the dna library
EA201691890A1 (ru) Катализатор
EA201691757A1 (ru) Способ получения синтез-газа
MY193764A (en) Micro-reactor and method implementation for methanation
EA201791288A1 (ru) Способ фишера-тропша, проводимый с применением восстановленного катализатора на основе кобальта
EA201792668A1 (ru) Установка, способ и катализатор осушки и очистки газообразного углеводородного сырья от сероводорода и/или меркаптанов
EA201390624A1 (ru) Конверсия природного газа
MY162887A (en) Method for starting up bubble-column-type slurry-bed reactor, start-up solvent, and method for producing hydrocarbon oil
IL234196B (en) Transportable liquid produced from natural gas
EA201791195A1 (ru) Способ получения lpg и btx
EA201790467A1 (ru) Способ функционализации гетероалканов и аренов