BR112018075821A2 - método para produzir propanal em uma reação. - Google Patents
método para produzir propanal em uma reação.Info
- Publication number
- BR112018075821A2 BR112018075821A2 BR112018075821-3A BR112018075821A BR112018075821A2 BR 112018075821 A2 BR112018075821 A2 BR 112018075821A2 BR 112018075821 A BR112018075821 A BR 112018075821A BR 112018075821 A2 BR112018075821 A2 BR 112018075821A2
- Authority
- BR
- Brazil
- Prior art keywords
- reactor
- reaction
- water
- synthesis gas
- propanal
- Prior art date
Links
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 title abstract 6
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000007789 gas Substances 0.000 abstract 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- 230000015572 biosynthetic process Effects 0.000 abstract 4
- 238000003786 synthesis reaction Methods 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 238000006073 displacement reaction Methods 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010574 gas phase reaction Methods 0.000 abstract 1
- 238000005691 oxidative coupling reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/008—Pyrolysis reactions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/04—Ethylene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
- C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
a presente invenção fornece métodos para produzir propanal em uma reação que compreende o acoplamento oxidativo de metano (ocm) e oxigênio como uma corrente de reagente em uma reação em fase gasosa, de preferência, na presença de água ou vapor, para formar etileno, etano, dióxido de carbono (co2), água e gás de síntese (co e h2) em um primeiro reator como uma corrente de etileno e, então, formar propanal em um segundo reator alimentando-se o segundo reator com a corrente de etileno e o gás de síntese do primeiro reator na fase gasosa e hidroformilando-se na presença de um catalisador para uma reação de deslocamento de água. no método, a razão entre h2 e co no gás de síntese é mantida coalimentando-se o primeiro reator ou o segundo reator com vapor para gerar h2 adicional no gás de síntese ou formando-se co no segundo reator a partir da reação de deslocamento de água alimentando-se o segundo reator com o co2 da corrente de etileno.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662356786P | 2016-06-30 | 2016-06-30 | |
| US62/356,786 | 2016-06-30 | ||
| PCT/US2017/037159 WO2018005074A1 (en) | 2016-06-30 | 2017-06-13 | Process for the conversion of methane into propanal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112018075821A2 true BR112018075821A2 (pt) | 2019-03-26 |
| BR112018075821B1 BR112018075821B1 (pt) | 2022-11-16 |
Family
ID=59216020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112018075821-3A BR112018075821B1 (pt) | 2016-06-30 | 2017-06-13 | Método para produzir propanal em uma reação |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10519087B2 (pt) |
| EP (1) | EP3478631B1 (pt) |
| JP (1) | JP6920023B2 (pt) |
| KR (1) | KR102379397B1 (pt) |
| CN (1) | CN109311666B (pt) |
| BR (1) | BR112018075821B1 (pt) |
| CA (1) | CA3029396A1 (pt) |
| MX (1) | MX2018015552A (pt) |
| SA (1) | SA518400731B1 (pt) |
| SG (1) | SG11201811444YA (pt) |
| WO (1) | WO2018005074A1 (pt) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018005074A1 (en) | 2016-06-30 | 2018-01-04 | Dow Global Technologies Llc | Process for the conversion of methane into propanal |
| EP3976732A4 (en) | 2019-05-24 | 2023-05-17 | Eastman Chemical Company | MIXING SMALL QUANTITIES OF PYROLYTIC OIL INTO A LIQUID STREAM WHICH IS PROCESSED INTO A GAS CRACKER |
| US20220289655A1 (en) * | 2019-05-24 | 2022-09-15 | Eastman Chemical Company | Recycle content propionaldehyde |
| US11365357B2 (en) | 2019-05-24 | 2022-06-21 | Eastman Chemical Company | Cracking C8+ fraction of pyoil |
| DE102019119543A1 (de) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Verfahren und Anlage zur Herstellung einer Zielverbindung |
| DE102019119540A1 (de) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Verfahren und Anlage zur Herstellung einer Zielverbindung |
| DE102019119562A1 (de) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Verfahren und Anlage zur Herstellung einer Zielverbindung |
| US11945998B2 (en) | 2019-10-31 | 2024-04-02 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| US11319262B2 (en) | 2019-10-31 | 2022-05-03 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| EP4054997A4 (en) | 2019-11-07 | 2024-02-21 | Eastman Chem Co | ALPHA-OLEFINS AND FAT ALCOHOLS WITH RECYCLING CONTENT |
| US20220363616A1 (en) * | 2019-11-07 | 2022-11-17 | Eastman Chemical Company | Recycle content propanol |
| EP3922621B1 (de) | 2020-06-10 | 2023-08-30 | Linde GmbH | Prozess zur herstellung von propylen |
| EP4015495A1 (de) * | 2020-12-18 | 2022-06-22 | Linde GmbH | Verfahren und anlage zur herstellung einer zielverbindung |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE215523T1 (de) | 1995-01-18 | 2002-04-15 | Exxonmobil Chem Patents Inc | Sauerstoffenthaltende verbindungen und verfahren zu deren herstellung |
| WO1997036848A1 (en) * | 1996-04-01 | 1997-10-09 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for the manufacture of methylmercaptopropanal |
| CN1298859A (zh) * | 1999-12-09 | 2001-06-13 | 中国科学院成都有机化学研究所 | 一种天然气旋焰乙炔炉余热喷油产混合气的使用方法 |
| CN100551884C (zh) * | 2005-12-02 | 2009-10-21 | 四川大学 | 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法 |
| WO2010133461A1 (de) * | 2009-05-20 | 2010-11-25 | Basf Se | Anlage und verfahren zur herstellung von höherwertigen kohlenwasserstoffen aus methan |
| US8604254B2 (en) * | 2009-11-11 | 2013-12-10 | Dow Global Technologies Llc | Reductive hydroformylation of an alkylene to an alkanol |
| DE102010030209A1 (de) | 2010-06-17 | 2011-12-22 | Evonik Oxeno Gmbh | Energieeffiziente Synthese von aliphatischen Adelhyden aus Alkanen und Kohlendioxid |
| CN102442894B (zh) * | 2010-09-30 | 2014-08-06 | 中国石油化工股份有限公司 | 一种利用炼厂干气中乙烯制备丙醛的方法 |
| CA2828727A1 (en) | 2011-03-02 | 2012-09-07 | Mark Allen Nunley | Methods for integrated natural gas purification and products produced therefrom |
| US9012694B2 (en) * | 2011-12-27 | 2015-04-21 | Shell Oil Company | Process for the production of alcohols |
| AU2013355038B2 (en) | 2012-12-07 | 2017-11-02 | Lummus Technology Llc | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
| US20140274671A1 (en) | 2013-03-15 | 2014-09-18 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
| JP6474794B2 (ja) * | 2013-09-30 | 2019-02-27 | ダウ グローバル テクノロジーズ エルエルシー | アルカン酸アルキルの気相生成 |
| US20160237003A1 (en) * | 2013-10-16 | 2016-08-18 | Saudi Basic Industries Corporation | Method for converting methane to ethylene |
| WO2015080218A1 (ja) | 2013-11-29 | 2015-06-04 | Dic株式会社 | 重合性化合物、組成物、重合体、光学異方体、液晶表示素子及び有機ｅｌ素子 |
| WO2018005074A1 (en) | 2016-06-30 | 2018-01-04 | Dow Global Technologies Llc | Process for the conversion of methane into propanal |
-
2017
- 2017-06-13 WO PCT/US2017/037159 patent/WO2018005074A1/en unknown
- 2017-06-13 KR KR1020197001767A patent/KR102379397B1/ko active IP Right Grant
- 2017-06-13 US US16/304,469 patent/US10519087B2/en active Active
- 2017-06-13 BR BR112018075821-3A patent/BR112018075821B1/pt active IP Right Grant
- 2017-06-13 CN CN201780039024.XA patent/CN109311666B/zh active Active
- 2017-06-13 CA CA3029396A patent/CA3029396A1/en active Pending
- 2017-06-13 EP EP17733247.5A patent/EP3478631B1/en active Active
- 2017-06-13 JP JP2018565774A patent/JP6920023B2/ja active Active
- 2017-06-13 MX MX2018015552A patent/MX2018015552A/es unknown
- 2017-06-13 SG SG11201811444YA patent/SG11201811444YA/en unknown
-
2018
- 2018-12-23 SA SA518400731A patent/SA518400731B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN109311666B (zh) | 2022-07-19 |
| MX2018015552A (es) | 2019-06-06 |
| JP6920023B2 (ja) | 2021-08-18 |
| US10519087B2 (en) | 2019-12-31 |
| WO2018005074A1 (en) | 2018-01-04 |
| KR20190024967A (ko) | 2019-03-08 |
| CN109311666A (zh) | 2019-02-05 |
| JP2019519547A (ja) | 2019-07-11 |
| KR102379397B1 (ko) | 2022-03-28 |
| SG11201811444YA (en) | 2019-01-30 |
| EP3478631A1 (en) | 2019-05-08 |
| CA3029396A1 (en) | 2018-01-04 |
| SA518400731B1 (ar) | 2021-12-12 |
| EP3478631B1 (en) | 2020-04-22 |
| US20190292122A1 (en) | 2019-09-26 |
| BR112018075821B1 (pt) | 2022-11-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06W | Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette] | ||
| B350 | Update of information on the portal [chapter 15.35 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 13/06/2017, OBSERVADAS AS CONDICOES LEGAIS |