CN100551884C - 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法 - Google Patents
一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法 Download PDFInfo
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- CN100551884C CN100551884C CNB2005100221861A CN200510022186A CN100551884C CN 100551884 C CN100551884 C CN 100551884C CN B2005100221861 A CNB2005100221861 A CN B2005100221861A CN 200510022186 A CN200510022186 A CN 200510022186A CN 100551884 C CN100551884 C CN 100551884C
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- methane
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- oxidation coupling
- propionic aldehyde
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实施例号 | 甲烷转化率 | CO+C<sub>2</sub>H<sub>4</sub>选择性 | CO+C<sub>2</sub>H<sub>4</sub>收率 | CO/H<sub>2</sub>/C<sub>2</sub>H<sub>4</sub>摩尔比 | C<sub>2</sub>H<sub>4</sub>/C<sub>2</sub>H<sub>6</sub>摩尔比 |
1 | 21.4 | 62.1 | 13.3 | 1.2∶1∶1.1 | 3.1 |
2 | 10.6 | 56.2 | 6.0 | 0.9∶1∶1.1 | 1.6 |
3 | 19.9 | 68.3 | 13.6 | 1.0∶1∶0.9 | 3.4 |
4 | 19.1 | 72.3 | 13.8 | 1.1∶1∶0.8 | 4.9 |
5 | 13.5 | 69.8 | 9.4 | 2.1∶1∶1.2 | 2.0 |
6 | 16.6 | 62.9 | 10.4 | 1.4∶1∶1.1 | 2.2 |
7 | 5.0 | 64.4 | 3.2 | 1.3∶1∶0.4 | ∞ |
8 | 22.8 | 68.3 | 15.6 | 1.5∶1∶1.5 | 4.0 |
9 | 19.6 | 70.6 | 13.8 | 2.2∶1∶0.7 | 3.0 |
10 | 17.9 | 79.0 | 14.1 | 1.3∶1∶0.4 | 6.1 |
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CNB2005100221861A CN100551884C (zh) | 2005-12-02 | 2005-12-02 | 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法 |
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CNB2005100221861A CN100551884C (zh) | 2005-12-02 | 2005-12-02 | 一种由甲烷氧化偶联和气相氧化耦合制取丙醛原料的方法 |
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CN1978409A CN1978409A (zh) | 2007-06-13 |
CN100551884C true CN100551884C (zh) | 2009-10-21 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106986736A (zh) * | 2016-01-21 | 2017-07-28 | 中国石化工程建设有限公司 | 一种烃类生产工艺和烃类生产装置 |
CN107108401A (zh) * | 2014-12-09 | 2017-08-29 | 沙特基础工业全球技术公司 | 通过将甲烷氧化偶联与甲烷干重整反应组合而生产乙烯和合成气的方法 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120065412A1 (en) * | 2009-05-20 | 2012-03-15 | Basf Se | System and process for producing higher-value hydrocarbons from methane |
CN102093157A (zh) * | 2009-12-09 | 2011-06-15 | 中国科学院兰州化学物理研究所 | 甲烷直接转化制乙烯及合成气的联合工艺过程 |
CN106278786B (zh) * | 2015-05-21 | 2019-08-06 | 中国科学院大连化学物理研究所 | 一种烷烃与co2生产氢甲酰化原料的方法 |
JP6920023B2 (ja) * | 2016-06-30 | 2021-08-18 | ダウ グローバル テクノロジーズ エルエルシー | メタンのプロパナールへの転化方法 |
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2005
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107108401A (zh) * | 2014-12-09 | 2017-08-29 | 沙特基础工业全球技术公司 | 通过将甲烷氧化偶联与甲烷干重整反应组合而生产乙烯和合成气的方法 |
CN106986736A (zh) * | 2016-01-21 | 2017-07-28 | 中国石化工程建设有限公司 | 一种烃类生产工艺和烃类生产装置 |
CN106986736B (zh) * | 2016-01-21 | 2019-06-25 | 中国石化工程建设有限公司 | 一种烃类生产工艺和烃类生产装置 |
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Assignee: Sichuan Shenlian Biotech Co.,Ltd. Assignor: Sichuan University Contract fulfillment period: 2009.10.30 to 2014.10.30 contract change Contract record no.: 2009510000156 Denomination of invention: Method for preparing propyladehyde raw material by methane oxidation coupling and gas-phase oxidation coupling Granted publication date: 20091021 License type: Exclusive license Record date: 20091116 |
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