SG11201811444YA - Process for the conversion of methane into propanal - Google Patents
Process for the conversion of methane into propanalInfo
- Publication number
- SG11201811444YA SG11201811444YA SG11201811444YA SG11201811444YA SG11201811444YA SG 11201811444Y A SG11201811444Y A SG 11201811444YA SG 11201811444Y A SG11201811444Y A SG 11201811444YA SG 11201811444Y A SG11201811444Y A SG 11201811444YA SG 11201811444Y A SG11201811444Y A SG 11201811444YA
- Authority
- SG
- Singapore
- Prior art keywords
- reactor
- international
- dowweg
- terneuzen
- herbert
- Prior art date
Links
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 title abstract 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract 6
- 238000006243 chemical reaction Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 3
- 239000001569 carbon dioxide Substances 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000005516 engineering process Methods 0.000 abstract 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000010574 gas phase reaction Methods 0.000 abstract 1
- 230000008520 organization Effects 0.000 abstract 1
- 238000005691 oxidative coupling reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/008—Pyrolysis reactions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/04—Ethylene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
- C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
Abstract
INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 111111101111 0111010101111101111101 0 011111111111111111111111111111111111111111 Organization International Bureau (10) International Publication Number (43) International Publication Date ......0\"\" WO 2018/005074 Al 04 January 2018 (04.01.2018) W I PO I PCT (51) International Patent Classification: TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, C01B 3/48 (2006.01) C07C 11/04 (2006.01) KM, ML, MR, NE, SN, TD, TG). C07C 45/50 (2006.01) C07C 47/02 (2006.01) C07C 2/82 (2006.01) Published: (21) International Application Number: — with international search report (Art. 21(3)) PCT/US2017/037159 (22) International Filing Date: 13 June 2017 (13.06.2017) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/356,786 30 June 2016 (30.06.2016) US (71) Applicant: DOW GLOBAL TECHNOLOGIES LLC [US/US]; 2040 Dow Center, Midland, MI 48674 (US). (72) Inventors: CORTHALS, Steven L.F.; Herbert H. Dowweg 5, 4530 AA Terneuzen (NL). DAVIDIAN, — Thomas; Herbert H. Dowweg 5, 4542 NM Terneuzen (NL). BUDRONI, Gerolamo; Herbert H. Dowweg 5, 4530 AA — = Terneuzen (NL). GROENENDIJK, Peter E.; Herbert H. Dowweg 5, 4542 NM Terneuzen (NL). = (74) Agent: MERRIAM, Andrew; Dow Global Technologies — LLC, 2040 Dow Center, Midland, Michigan 48674 (US). — = (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, = AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, = DE, DJ, DK, DM, DO, CA, CH, CL, CN, CO, CR, CU, CZ, = DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, = HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, = MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, = OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, _ TH, TJ, TM, TN, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, = TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every = kind of regional protection available): ARIPO (BW, GH, = KE, LR, LS, MW, MZ, NA, RW, TZ, GM, SD, SL, ST, SZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, = — TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, = EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, 1-1 ..! (54) Title: PROCESS FOR THE CONVERSION OF METHANE INTO PROPANAL 7 r (57) : The present invention provides methods for making propanal in a reaction comprising the oxidative coupling of methane © (OCM) and oxygen as a reactant stream in a gas phase reaction, preferably in the presence of water or steam, to form ethylene, ethane, In carbon dioxide (CO2), water and syngas (CO and H2) in a first reactor as an ethylene stream, and then forming propanal in a second reactor by feeding to the second reactor the ethylene stream with the syngas from the first reactor in the gas phase and hydroformylating 0 ---- in the presence of a catalyst for a water shift reaction. In the method, the ratio of H2 to CO in the syngas is maintained by either co- GC , 1 feeding steam into the first reactor or the second reactor to generate additional H2 in the syngas, or by forming CO in the second reactor 0 from the water shift reaction by feeding the CO2 from the ethylene stream into the second reactor. ei O
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662356786P | 2016-06-30 | 2016-06-30 | |
| PCT/US2017/037159 WO2018005074A1 (en) | 2016-06-30 | 2017-06-13 | Process for the conversion of methane into propanal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SG11201811444YA true SG11201811444YA (en) | 2019-01-30 |
Family
ID=59216020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG11201811444YA SG11201811444YA (en) | 2016-06-30 | 2017-06-13 | Process for the conversion of methane into propanal |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10519087B2 (en) |
| EP (1) | EP3478631B1 (en) |
| JP (1) | JP6920023B2 (en) |
| KR (1) | KR102379397B1 (en) |
| CN (1) | CN109311666B (en) |
| BR (1) | BR112018075821B1 (en) |
| CA (1) | CA3029396A1 (en) |
| MX (1) | MX2018015552A (en) |
| SA (1) | SA518400731B1 (en) |
| SG (1) | SG11201811444YA (en) |
| WO (1) | WO2018005074A1 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG11201811444YA (en) | 2016-06-30 | 2019-01-30 | Dow Global Technologies Llc | Process for the conversion of methane into propanal |
| CN113993977A (en) | 2019-05-24 | 2022-01-28 | 伊士曼化工公司 | Mixing a small amount of pyrolysis oil into the liquid flow entering the gas cracker for processing |
| US11365357B2 (en) | 2019-05-24 | 2022-06-21 | Eastman Chemical Company | Cracking C8+ fraction of pyoil |
| EP3976573A4 (en) * | 2019-05-24 | 2023-07-05 | Eastman Chemical Company | Recycle content propionaldehyde |
| DE102019119540A1 (en) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Method and system for establishing a target connection |
| DE102019119543A1 (en) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Method and system for establishing a target connection |
| DE102019119562A1 (en) * | 2019-07-18 | 2021-01-21 | Linde Gmbh | Method and system for establishing a target connection |
| US11319262B2 (en) | 2019-10-31 | 2022-05-03 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| US11945998B2 (en) | 2019-10-31 | 2024-04-02 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
| CN114728869A (en) * | 2019-11-07 | 2022-07-08 | 伊士曼化工公司 | Recovering the propanol component |
| US11939534B2 (en) | 2019-11-07 | 2024-03-26 | Eastman Chemical Company | Recycle content alpha olefins and fatty alcohols |
| EP3922621B1 (en) | 2020-06-10 | 2023-08-30 | Linde GmbH | Process for manufacturing propylene |
| EP4015495A1 (en) * | 2020-12-18 | 2022-06-22 | Linde GmbH | Method and system for producing a target connection |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE180763T1 (en) | 1995-01-18 | 1999-06-15 | Exxon Chemical Ltd | HYDROFORMYLATION PROCESS |
| MXPA98008036A (en) * | 1996-04-01 | 2004-10-14 | Union Carbide Chem Plastic | Processes for the manufacture of methylmercaptopropanal. |
| CN1298859A (en) * | 1999-12-09 | 2001-06-13 | 中国科学院成都有机化学研究所 | Application method of gas mixture prepared by using afterheat of natural gas flame spinning acetylene generator and spraying oil |
| CN100551884C (en) * | 2005-12-02 | 2009-10-21 | 四川大学 | A kind of method of producing the propionic aldehyde raw material by methane oxidation coupling and gaseous oxidation coupling |
| EP2432772A1 (en) * | 2009-05-20 | 2012-03-28 | Basf Se | System and method for producing superior hydrocarbons from methane |
| CN102686546B (en) * | 2009-11-11 | 2015-08-19 | 陶氏环球技术有限责任公司 | The hydroformylation that reduced by alkene is converted into alkanol |
| DE102010030209A1 (en) | 2010-06-17 | 2011-12-22 | Evonik Oxeno Gmbh | Energy-efficient synthesis of aliphatic adhehydrates from alkanes and carbon dioxide |
| CN102442894B (en) * | 2010-09-30 | 2014-08-06 | 中国石油化工股份有限公司 | Method for preparing propionic aldehyde from ethylene in refinery dry gas |
| WO2012118888A2 (en) | 2011-03-02 | 2012-09-07 | Aither Chemicals, Llc | Methods for integrated natural gas purification and products produced therefrom |
| CN104136401A (en) | 2011-12-27 | 2014-11-05 | 国际壳牌研究有限公司 | Process for the production of alcohols |
| AU2013355038B2 (en) | 2012-12-07 | 2017-11-02 | Lummus Technology Llc | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
| EP2969184A4 (en) | 2013-03-15 | 2016-12-21 | Siluria Technologies Inc | Catalysts for petrochemical catalysis |
| CA2924806C (en) | 2013-09-30 | 2021-10-19 | Dow Global Technologies Llc | Gas phase production of alkyl alkanoate |
| US20160237003A1 (en) * | 2013-10-16 | 2016-08-18 | Saudi Basic Industries Corporation | Method for converting methane to ethylene |
| JP5822098B1 (en) | 2013-11-29 | 2015-11-24 | Dic株式会社 | Polymerizable compound, composition, polymer, optical anisotropic body, liquid crystal display device and organic EL device |
| SG11201811444YA (en) | 2016-06-30 | 2019-01-30 | Dow Global Technologies Llc | Process for the conversion of methane into propanal |
-
2017
- 2017-06-13 SG SG11201811444YA patent/SG11201811444YA/en unknown
- 2017-06-13 CN CN201780039024.XA patent/CN109311666B/en active Active
- 2017-06-13 EP EP17733247.5A patent/EP3478631B1/en active Active
- 2017-06-13 JP JP2018565774A patent/JP6920023B2/en active Active
- 2017-06-13 MX MX2018015552A patent/MX2018015552A/en unknown
- 2017-06-13 BR BR112018075821-3A patent/BR112018075821B1/en active IP Right Grant
- 2017-06-13 CA CA3029396A patent/CA3029396A1/en active Pending
- 2017-06-13 WO PCT/US2017/037159 patent/WO2018005074A1/en unknown
- 2017-06-13 KR KR1020197001767A patent/KR102379397B1/en active IP Right Grant
- 2017-06-13 US US16/304,469 patent/US10519087B2/en active Active
-
2018
- 2018-12-23 SA SA518400731A patent/SA518400731B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US10519087B2 (en) | 2019-12-31 |
| JP2019519547A (en) | 2019-07-11 |
| WO2018005074A1 (en) | 2018-01-04 |
| JP6920023B2 (en) | 2021-08-18 |
| BR112018075821B1 (en) | 2022-11-16 |
| US20190292122A1 (en) | 2019-09-26 |
| CN109311666B (en) | 2022-07-19 |
| CA3029396A1 (en) | 2018-01-04 |
| KR102379397B1 (en) | 2022-03-28 |
| EP3478631B1 (en) | 2020-04-22 |
| CN109311666A (en) | 2019-02-05 |
| MX2018015552A (en) | 2019-06-06 |
| KR20190024967A (en) | 2019-03-08 |
| SA518400731B1 (en) | 2021-12-12 |
| BR112018075821A2 (en) | 2019-03-26 |
| EP3478631A1 (en) | 2019-05-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SG11201811444YA (en) | Process for the conversion of methane into propanal | |
| SG11201908414YA (en) | Catalyst system for multi-block copolymer formation | |
| SG11201907469YA (en) | Method and cell line for production of polyketides in yeast | |
| SG11201901946RA (en) | Reformer tube having a structured catalyst and improved heat balance | |
| CL2017002195A1 (en) | Method to produce methane from biomass. | |
| SG11201806398YA (en) | Optimized factor viii genes | |
| CA3078742A1 (en) | A method for generating synthesis gas for ammonia production | |
| CA2910356C (en) | A process for producing ammonia synthesis gas with high temperature shift and low steam-to-carbon ratio | |
| SG11201901909QA (en) | Acid aromatization catalyst with improved activity and stability | |
| SG11201407635XA (en) | Generation of functional and durable endothelial cells from human amniotic fluid-derived cells | |
| SG11201808587YA (en) | A method and system for operating one or more tugboats | |
| SG11201807949WA (en) | Engineered immunoglobulins with altered fcrn binding | |
| SG11201903008YA (en) | Hla-restricted vgll1 peptides and use thereof | |
| SG11201811258UA (en) | Process for the production of a dna vaccine for cancer immunotherapy | |
| SG11201807062RA (en) | Anti-tnfalpha-antibodies and functional fragments thereof | |
| SG11201903179WA (en) | Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols | |
| SG11201811685TA (en) | Corrosion-protected reformer tube with internal heat exchange | |
| SG11201805494WA (en) | Mutated von willebrand factor | |
| SG11201901938YA (en) | Method of producing a methanation catalyst | |
| SG11201901966XA (en) | Steam reforming system and process | |
| SG11201805953YA (en) | Method and apparatus for removing carbon dioxide from flue gas | |
| SG11201806883PA (en) | Biological removal of micropollutants from wastewater | |
| SG11201408788QA (en) | Process for preparing ethylene and/or propylene | |
| SG11201808126PA (en) | Subsea remotely operated vehicle (rov) hub | |
| SG11201906313SA (en) | A polypeptide linker for preparing multispecific antibodies |