SG11201901946RA - Reformer tube having a structured catalyst and improved heat balance - Google Patents
Reformer tube having a structured catalyst and improved heat balanceInfo
- Publication number
- SG11201901946RA SG11201901946RA SG11201901946RA SG11201901946RA SG11201901946RA SG 11201901946R A SG11201901946R A SG 11201901946RA SG 11201901946R A SG11201901946R A SG 11201901946RA SG 11201901946R A SG11201901946R A SG 11201901946RA SG 11201901946R A SG11201901946R A SG 11201901946RA
- Authority
- SG
- Singapore
- Prior art keywords
- international
- structured catalyst
- pct
- structured
- catalyst
- Prior art date
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- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
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- B01J19/246—Stationary reactors without moving elements inside provoking a loop type movement of the reactants internally, i.e. the mixture circulating inside the vessel such that the upward stream is separated physically from the downward stream(s)
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- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 111111101111 0 1110101011111 011101 0 01111111111111111111111111101111111011110111111 Organization International Bureau (10) International Publication Number (43) International Publication Date .....0\"\"\" WO 2018/050291 Al 22 March 2018 (22.03.2018) WIP0 I PCT (51) International Patent Classification: (74) Agent: DROPSCH, Holger; AIR LIQUIDE C01B 3/38 (2006.01) B01J 8/02 (2006.01) FORSCHUNG UND ENTWICKLUNG GMBH, Gwinner- B01J 19/32 (2006.01) strasse 27-33, 60388 Frankfurt am Main (DE). (21) International Application Number: (81) Designated States (unless otherwise indicated, for every PCT/EP2017/025252 kind of national protection available): AE, AG, AL, AM, (22) International Filing Date: AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, 05 September 2017 (05.09.2017) CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, (25) Filing Language: English HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, (26) Publication Language: English KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, (30) Priority Data: OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, 16400041.6 14 September 2016 (14.09.2016) EP SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (71) Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PRO- (84) Designated States (unless otherwise indicated, for every CEDES GEORGES CLAUDE [FR/FR]; 75 Quai d'Orsay, kind of regional protection available): ARIPO (BW, GH, 75007 Paris (FR). GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, (72) Inventors: ULBER, Dieter; Kastanienstr. 10, 61449 Stein-TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, — bach (DE). GARY, Daniel; 2, allee d'Anjou, 78180 Mon-EE, ES, FL FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, tigny Bretonneux (FR). PROST, Laurent; 3 me Fernand — MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, = Leger, 91190 Gif-sur-Yvette (FR). TADIELLO, Jean- TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, Philippe; Woogstrasse 30C, 60431 Frankfurt am Main KM, ML, MR, NE, SN, TD, TG). (DE). BASIN, Marie; 34 me du General Leclerc, 78000 — Versailles (FR). = = (54) Title: REFORMER TUBE HAVING A STRUCTURED CATALYST AND IMPROVED HEAT BALANCE (57) : A reformer tube for producing synthesis gas by steam reforming = = of hydrocarbon- containing feed gases, in which a structured stream reforming = = = = _ = F T rriai IW WI t ttft , riti Sis,ii fi l l ri t i,\" I I mm catalyst is used, is proposed. According to the invention, a heat exchanger tube is arranged in the interior of the structured catalyst, with the feed gas stream flowing firstly through the structured catalyst and subsequently in countercurrent through the heat exchanger tube. This improves the heat exchange between the synthesis gas product stream and the structured catalyst and the feed gas stream flowing A through it, especially in the radial direction. 12 10 1-1 3 B 1 1 11 C:7 13 N 14 C kin © —.... Fig. 1 00 ,-1 © ei C [Continued on next page] WO 2018/050291 Al MIDEDIMOMOIDEIROHOINIEN0011010MMOIllii0VOIMIE Published: — with international search report (Art. 21(3))
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16400041.6A EP3296255A1 (en) | 2016-09-14 | 2016-09-14 | Reformer tube with structured catalyst and improved temperature control |
PCT/EP2017/025252 WO2018050291A1 (en) | 2016-09-14 | 2017-09-05 | Reformer tube having a structured catalyst and improved heat balance |
Publications (1)
Publication Number | Publication Date |
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SG11201901946RA true SG11201901946RA (en) | 2019-04-29 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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SG11201901946RA SG11201901946RA (en) | 2016-09-14 | 2017-09-05 | Reformer tube having a structured catalyst and improved heat balance |
Country Status (11)
Country | Link |
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US (1) | US11351517B2 (en) |
EP (1) | EP3296255A1 (en) |
KR (1) | KR102415731B1 (en) |
CN (2) | CN107812499B (en) |
AU (1) | AU2017326121B2 (en) |
CA (1) | CA3036416A1 (en) |
DE (1) | DE102016120167A1 (en) |
EA (1) | EA039256B1 (en) |
MX (1) | MX2019002852A (en) |
SG (1) | SG11201901946RA (en) |
WO (1) | WO2018050291A1 (en) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3296255A1 (en) * | 2016-09-14 | 2018-03-21 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Reformer tube with structured catalyst and improved temperature control |
EP3538746A1 (en) | 2016-11-09 | 2019-09-18 | 8 Rivers Capital, LLC | Systems and methods for power production with integrated production of hydrogen |
ES2739686T3 (en) | 2016-12-19 | 2020-02-03 | Air Liquide | Reformer tube protected against corrosion, with internal heat exchange |
KR102651575B1 (en) | 2017-11-09 | 2024-03-27 | 8 리버스 캐피탈, 엘엘씨 | Systems and methods for production and separation of hydrogen and carbon dioxide |
US11207649B2 (en) * | 2018-03-14 | 2021-12-28 | West Biofuels, Llc | Synthesis gas reactor tubes and reactors and related systems and processes |
US10822233B2 (en) * | 2018-05-11 | 2020-11-03 | Doosan Fuel Cell America, Inc. | Reformer including catalyst in an inlet plenum |
KR20220020842A (en) | 2019-06-13 | 2022-02-21 | 8 리버스 캐피탈, 엘엘씨 | Power production with co-generation of additional products |
US20220212928A1 (en) | 2019-07-03 | 2022-07-07 | Haldor Topsøe A/S | Combination of structured catalyst elements and pellets |
CN114173918A (en) | 2019-09-03 | 2022-03-11 | 托普索公司 | Reformer with supported reformer tubes |
EP3798180A1 (en) * | 2019-09-26 | 2021-03-31 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Reformer tube with improved heat transfer |
CN112705149B (en) * | 2019-10-25 | 2022-10-21 | 中国石油化工股份有限公司 | Quartz reactor with liner |
CN110790232B (en) * | 2019-12-04 | 2024-09-03 | 清华大学 | Catalytic reforming device for liquid fuel |
US11433367B2 (en) * | 2020-01-21 | 2022-09-06 | Zoneflow Reactor Technologies, LLC | Support structure for structured catalyst packings |
NO347023B1 (en) * | 2021-03-16 | 2023-04-17 | Minox Tech As | Device with variable volume for treatment of gases and liquids |
EP4155259A1 (en) * | 2021-09-22 | 2023-03-29 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Method for producing synthesis gas with reduced steam export |
CA3238610A1 (en) | 2021-11-18 | 2023-05-25 | Rodney John Allam | Apparatus for hydrogen production |
TW202408654A (en) * | 2022-05-04 | 2024-03-01 | 英商強生麥特公司 | Chemical flow-reactor |
CN114984899B (en) * | 2022-06-20 | 2024-02-13 | 山东祥桓环境科技有限公司 | Powder material heat exchange reaction device and system |
EP4389693A1 (en) * | 2022-12-23 | 2024-06-26 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for producing synthesis gas product comprising hydrogen |
Family Cites Families (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3215502A (en) * | 1962-07-30 | 1965-11-02 | Chemical Construction Corp | Reformer furnace |
US3419362A (en) * | 1965-06-25 | 1968-12-31 | Chemical Construction Corp | Fluid heater |
US3607125A (en) * | 1968-12-30 | 1971-09-21 | Gen Electric | Reformer tube construction |
US3682605A (en) * | 1969-07-15 | 1972-08-08 | Tokyo Heat Treating Co | Method and apparatus for soot controlling in a thermal decomposition of a hydrocarbon gas |
US3958951A (en) * | 1974-04-09 | 1976-05-25 | Stone & Webster Engineering Corporation | Convective power reformer equipment and system |
DE3068525D1 (en) * | 1979-09-06 | 1984-08-16 | Ici Plc | A process and apparatus for catalytically reacting steam with a hydrocarbon in endothermic conditions |
MX168335B (en) * | 1982-08-12 | 1993-05-17 | Mitsubishi Heavy Ind Ltd | IMPROVED APPARATUS FOR REFORMING FUEL |
GB8609099D0 (en) * | 1986-04-15 | 1986-05-21 | British Petroleum Co Plc | Production of synthesis gas |
GB2201903B (en) * | 1987-03-03 | 1990-11-28 | Shell Int Research | Apparatus and process suitable for producing hydrogen |
GB8728882D0 (en) * | 1987-12-10 | 1988-01-27 | Ici Plc | Hydrogen |
CN2098965U (en) | 1991-08-28 | 1992-03-18 | 庞玉学 | Float head-drivepipe type tube reactor |
US5264008A (en) * | 1991-10-07 | 1993-11-23 | United Technologies Corporation | Reformer seal plate |
US5275632A (en) * | 1991-10-07 | 1994-01-04 | International Fuel Cells Corporation | Reformer support arrangement |
DK173052B1 (en) * | 1997-05-05 | 1999-12-06 | Topsoe Haldor As | Process for producing ammonia synthesis gas |
JPH11169702A (en) * | 1997-12-10 | 1999-06-29 | Babcock Hitachi Kk | Heat exchanger type modification apparatus |
US6139810A (en) * | 1998-06-03 | 2000-10-31 | Praxair Technology, Inc. | Tube and shell reactor with oxygen selective ion transport ceramic reaction tubes |
DK173742B1 (en) * | 1998-09-01 | 2001-08-27 | Topsoe Haldor As | Process and reactor system for producing synthesis gas |
US6258330B1 (en) * | 1998-11-10 | 2001-07-10 | International Fuel Cells, Llc | Inhibition of carbon deposition on fuel gas steam reformer walls |
AU5386999A (en) * | 1999-08-13 | 2001-03-13 | Technip Kti S.P.A. | Catalyst tubes for endothermic reaction especially for the production of hydrogen and syngas |
ES2248207T3 (en) * | 2000-09-20 | 2006-03-16 | Air Products And Chemicals, Inc. | DEVICE AND PROCEDURE FOR REFORMING HYDROCARBONS. |
CN1774393A (en) * | 2003-04-15 | 2006-05-17 | 国际壳牌研究有限公司 | Reactor for performing a steam reforming reaction and a process to prepare synthesis gas |
US20070264186A1 (en) * | 2004-09-09 | 2007-11-15 | Dybkjaer Ib | Process for Production of Hydrogen and/or Carbon Monoxide |
US7761994B2 (en) | 2006-05-17 | 2010-07-27 | Air Products And Chemicals, Inc. | Reactor with expandable structure providing improved heat transfer |
US7501078B2 (en) | 2007-01-10 | 2009-03-10 | Air Products And Chemicals, Inc. | Process for generating synthesis gas using catalyzed structured packing |
CN101109611A (en) * | 2007-07-05 | 2008-01-23 | 浙江大学 | Anti-deposition and anti-crystallization process and device for heat exchanger |
KR101266673B1 (en) * | 2007-11-01 | 2013-05-28 | 에스케이이노베이션 주식회사 | Hydrogen generating apparatus using steam reforming reaction |
GB0918246D0 (en) * | 2009-10-19 | 2009-12-02 | Davy Process Techn Ltd | Apparatus |
WO2012103432A2 (en) | 2011-01-28 | 2012-08-02 | Catacel Corp. | Improved stackable structural reactors |
US20140103259A1 (en) * | 2011-04-07 | 2014-04-17 | BioMethanol CHemie Nederland B.V | Multi-tubular steam reformer and process for catalytic steam reforming of a hydrocarbonaceous feedstock |
DE102011118217A1 (en) | 2011-11-11 | 2013-05-16 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Reformer tube with internal heat exchange |
US9440903B2 (en) | 2012-09-24 | 2016-09-13 | Arkema Inc. | Shell and tube oxidation reactor with improved resistance to fouling |
GB201403787D0 (en) * | 2014-03-04 | 2014-04-16 | Johnson Matthey Plc | Steam reforming |
CN204122092U (en) * | 2014-08-06 | 2015-01-28 | 庞玉学 | Thimble tube heat-exchanged reformer |
EP3296255A1 (en) | 2016-09-14 | 2018-03-21 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Reformer tube with structured catalyst and improved temperature control |
CN207102559U (en) * | 2017-04-14 | 2018-03-16 | 中国石油化工股份有限公司 | Burn formula hydrogen manufacturing conversion furnace in a kind of bottom based on double tube reactor |
-
2016
- 2016-09-14 EP EP16400041.6A patent/EP3296255A1/en active Pending
- 2016-10-24 DE DE102016120167.7A patent/DE102016120167A1/en not_active Withdrawn
-
2017
- 2017-09-05 SG SG11201901946RA patent/SG11201901946RA/en unknown
- 2017-09-05 WO PCT/EP2017/025252 patent/WO2018050291A1/en active Application Filing
- 2017-09-05 MX MX2019002852A patent/MX2019002852A/en unknown
- 2017-09-05 KR KR1020197009462A patent/KR102415731B1/en active IP Right Grant
- 2017-09-05 CA CA3036416A patent/CA3036416A1/en active Pending
- 2017-09-05 EA EA201990648A patent/EA039256B1/en unknown
- 2017-09-05 US US16/333,004 patent/US11351517B2/en active Active
- 2017-09-05 AU AU2017326121A patent/AU2017326121B2/en active Active
- 2017-09-11 CN CN201710811812.8A patent/CN107812499B/en active Active
- 2017-09-11 CN CN201721162068.5U patent/CN207709023U/en not_active Withdrawn - After Issue
Also Published As
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CA3036416A1 (en) | 2018-03-22 |
WO2018050291A1 (en) | 2018-03-22 |
CN107812499B (en) | 2021-12-28 |
EP3296255A1 (en) | 2018-03-21 |
DE102016120167A1 (en) | 2018-03-15 |
CN207709023U (en) | 2018-08-10 |
US20190275494A1 (en) | 2019-09-12 |
CN107812499A (en) | 2018-03-20 |
AU2017326121B2 (en) | 2021-11-18 |
KR102415731B1 (en) | 2022-07-04 |
US11351517B2 (en) | 2022-06-07 |
KR20190046939A (en) | 2019-05-07 |
AU2017326121A1 (en) | 2019-04-18 |
EA201990648A1 (en) | 2019-07-31 |
EA039256B1 (en) | 2021-12-23 |
MX2019002852A (en) | 2019-06-12 |
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