SG11201903179WA - Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols - Google Patents

Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols

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Publication number
SG11201903179WA
SG11201903179WA SG11201903179WA SG11201903179WA SG11201903179WA SG 11201903179W A SG11201903179W A SG 11201903179WA SG 11201903179W A SG11201903179W A SG 11201903179WA SG 11201903179W A SG11201903179W A SG 11201903179WA SG 11201903179W A SG11201903179W A SG 11201903179WA
Authority
SG
Singapore
Prior art keywords
suite
gevo
colorado
building
south
Prior art date
Application number
SG11201903179WA
Inventor
Jonathan O Smith
Madeline Sjodin
Austin Vaillancourt
Paul Starkey
Steve Donen
Michelle Shebowich
Original Assignee
Gevo Inc
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Filing date
Publication date
Application filed by Gevo Inc filed Critical Gevo Inc
Publication of SG11201903179WA publication Critical patent/SG11201903179WA/en

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    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
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    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
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    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C1/00—Working-up tar
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 111111111111111111111010111111111111111111111111111111111111H1111111111111111110111111 Organization International Bureau (10) International Publication Number (43) International Publication Date .....0\"\" WO 2018/071905 Al 19 April 2018 (19.04.2018) WIP0 1 PCT (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every CO7C 2/24 (2006.01) B01J 8/04 (2006.01) kind of national protection available): AE, AG, AL, AM, C07C 2/12 (2006.01) C08G 61/02 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, C07C 5/03 (2006.01) C10C 1/20 (2006.01) CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, CO7C 6/02 (2006.01) ClOG 3/00 (2006.01) DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, (21) International Application Number: HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, PCT/US2017/056793 KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, (22) International Filing Date: OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, 16 October 2017 (16.10.2017) SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (25) Filing Language: English (26) Publication Language: English (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, — (30) Priority Data: GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, 62/408,476 14 October 2016 (14.10.2016) US UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, 62/412,046 24 October 2016 (24.10.2016) US TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, 62/426,787 28 November 2016 (28.11.2016) US EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, 62/484,580 12 April 2017 (12.04.2017) US MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, 62/489,756 25 April 2017 (25.04.2017) US TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, 62/500,892 03 May 2017 (03.05.2017) US KM, ML, MR, NE, SN, TD, TG). 62/521,664 19 June 2017 (19.06.2017) US 62/539,287 31 July 2017 (31.07.2017) US Published: = — Applicant: GEVO, INC. [US/US]; 345 Inverness Drive with international search report (Art. 21(3)) = (71) South, Building C., Suite 310, Englewood, Colorado 80112 (US). Inventors; and (72) = (71) Applicants: SMITH, Jonathan 0. [US/US]; c/o GEVO, INC., 345 Inverness Drive South, Building C., Suite 310, Englewood, Colorado 80112 (US). SJODIN, Madeline [US/US]; c/o GEVO, INC., 345 Inverness Drive South, Building C., Suite 310, Englewood, Colorado 80112 (US). _ = VAILLANCOURT, Austin [US/US]; c/o GEVO, INC., 345 Inverness Drive South, Building C., Suite 310, Engle- = _ = wood, Colorado 80112 (US). STARKEY, Paul [US/US]; c/o GEVO, INC., 345 Inverness Drive South, Building C., Suite 310, Englewood, Colorado 80112 (US). DONEN, Steve [US/US]; c/o GEVO, INC., 345 Inverness Drive = = South, Building C., Suite 310, Englewood, Colorado 80112 = (US). SHEBOWICH, Michelle [US/US]; c/o GEVO, Inc., = — 345 Inverness Drive South, Building C., Suite 310, Engle- wood, Colorado 80112 (US). Agent: BROW, William E. et al.; Cooley LLP, 1299 Penn- sylvania Avenue, NM., Suite 700, Washington, District of (74) Columbia 20004 (US). — 1-1 11 in C::::) (54) Title: CONVERSION OF MIXTURES OF C2-C8 OLEFINS TO JET FUEL AND/OR DIESEL FUEL IN HIGH YIELD FROM ON BIO-BASED ALCOHOLS 1-1 I N (57) : The present disclosure provides methods and materials for oligomerization of lower olefins (e.g., C2-C8) to transporta- 0 - --- GO tions fuels including diesel and/or jet fuel. The oligomerization employs, in certain embodiments, tungstated zirconium catalysts. Sur- prisingly, the oligomerizations proceed smoothly in high yields and exhibit little to no sensitivity to the presence of significant amounts 0 of oxygenates (e.g., water, lower alcohols such as C2-C8 alcohols) in the feed stream. Accordingly, the present disclosure is uniquely ei suited to the production of fuels derived from biobased alcohols, wherein olefms produced from such bio-based alcohols typically 0 contain high levels of oxygenates.
SG11201903179WA 2016-10-14 2017-10-16 Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols SG11201903179WA (en)

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US201662408476P 2016-10-14 2016-10-14
US201662412046P 2016-10-24 2016-10-24
US201662426787P 2016-11-28 2016-11-28
US201762484580P 2017-04-12 2017-04-12
US201762489756P 2017-04-25 2017-04-25
US201762500892P 2017-05-03 2017-05-03
US201762521664P 2017-06-19 2017-06-19
US201762539287P 2017-07-31 2017-07-31
PCT/US2017/056793 WO2018071905A1 (en) 2016-10-14 2017-10-16 Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols

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