MX2011007475A - Catalizadores utiles para la alquilacion de hidrocarburos aromaticos. - Google Patents
Catalizadores utiles para la alquilacion de hidrocarburos aromaticos.Info
- Publication number
- MX2011007475A MX2011007475A MX2011007475A MX2011007475A MX2011007475A MX 2011007475 A MX2011007475 A MX 2011007475A MX 2011007475 A MX2011007475 A MX 2011007475A MX 2011007475 A MX2011007475 A MX 2011007475A MX 2011007475 A MX2011007475 A MX 2011007475A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- alkylation
- framework aluminum
- aromatic hydrocarbons
- acid
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/085—Isopropylbenzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/34—Reaction with organic or organometallic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7042—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7046—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Se describe un catalizador útil para la alquilación o transalquilación de compuestos aromáticos. El catalizador es un catalizador zeolítico tratado con ácido producido por un proceso que incluye poner en contacto un catalizador zeolítico acídico que comprende aluminio no estructural y aluminio estructural de superficie, con un ácido dibásico orgánico en una proporción en peso de catalizador a ácido en el intervalo desde aproximadamente 2:1 a aproximadamente 20:1 y a una temperatura en el intervalo desde aproximadamente 50°C hasta aproximadamente 100°C para retirar selectivamente al menos una porción del aluminio no estructural de superficie. El catalizador resultante puede tener una constante de velocidad de primer orden medida, kcum, para la alquilación de benceno con propileno para formar cumeno, de al menos 2.0 cm3/s g.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/353,693 US8450232B2 (en) | 2009-01-14 | 2009-01-14 | Catalysts useful for the alkylation of aromatic hydrocarbons |
PCT/US2009/059353 WO2010082963A1 (en) | 2009-01-14 | 2009-10-02 | Catalysts useful for the alkylation of aromatic hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2011007475A true MX2011007475A (es) | 2011-09-15 |
Family
ID=42319531
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2011007475A MX2011007475A (es) | 2009-01-14 | 2009-10-02 | Catalizadores utiles para la alquilacion de hidrocarburos aromaticos. |
Country Status (15)
Country | Link |
---|---|
US (2) | US8450232B2 (es) |
EP (1) | EP2387464A4 (es) |
JP (1) | JP5404814B2 (es) |
KR (1) | KR101510086B1 (es) |
CN (1) | CN102387861B (es) |
AR (2) | AR075016A1 (es) |
BR (1) | BRPI0924186A2 (es) |
CA (1) | CA2749122A1 (es) |
CL (1) | CL2009002000A1 (es) |
MX (1) | MX2011007475A (es) |
MY (1) | MY152666A (es) |
NO (1) | NO20110968A1 (es) |
SG (1) | SG172989A1 (es) |
TW (1) | TWI435764B (es) |
WO (1) | WO2010082963A1 (es) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MA33459B1 (fr) | 2009-07-13 | 2012-07-03 | Univ Liege | Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees |
US20120215046A1 (en) * | 2011-02-18 | 2012-08-23 | Fina Technology, Inc. | Alkylation Process and Catalysts for Use Therein |
DE102011101877A1 (de) * | 2011-05-18 | 2012-11-22 | Süd-Chemie AG | Niedertemperatur-Oxidationskatalysator mit besonders ausgeprägten hydrophoben Eigenschaften für die Oxidation organischer Schadstoffe |
US20160038929A1 (en) * | 2013-05-09 | 2016-02-11 | Exxonmobil Chemical Patents Inc. | Regeneration of Aromatic Alkylation Catalyst Using Ozone |
WO2014182434A1 (en) * | 2013-05-09 | 2014-11-13 | Exxonmobil Chemical Patents Inc. | Treatment of aromatic alkylation catalysts |
WO2014192860A1 (ja) | 2013-05-31 | 2014-12-04 | 東レバッテリーセパレータフィルム株式会社 | ポリオレフィン多層微多孔膜およびその製造方法 |
EP3102651A1 (en) * | 2014-02-07 | 2016-12-14 | Saudi Basic Industries Corporation | Removal of aromatic impurities from an alkene stream using an acid catalyst |
RU2686693C2 (ru) | 2014-02-07 | 2019-04-30 | Сауди Бейсик Индастриз Корпорейшн | Удаление ароматических примесей из потока алкенов при помощи кислотного катализатора, такого как кислотная ионная жидкость |
CN108473386B (zh) * | 2015-12-22 | 2021-10-08 | 生态石油环保燃料i瑞典有限公司 | 使用双催化剂体系的醇到烃的转化 |
CN106694033A (zh) * | 2016-11-28 | 2017-05-24 | 宣城市聚源精细化工有限公司 | 一种苯和丙烯的烷基化反应催化剂 |
US11208365B2 (en) | 2016-12-20 | 2021-12-28 | Uop Llc | Processes and apparatuses for methylation of aromatics in an aromatics complex |
WO2018160327A1 (en) * | 2017-02-28 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their use in aromatic alkylation processes |
SG11201906864VA (en) | 2017-02-28 | 2019-09-27 | Exxonmobil Chemical Patents Inc | Catalyst compositions and their use in aromatic alkylation processes |
US11130719B2 (en) | 2017-12-05 | 2021-09-28 | Uop Llc | Processes and apparatuses for methylation of aromatics in an aromatics complex |
US11130720B2 (en) * | 2018-03-23 | 2021-09-28 | Uop Llc | Processes for methylation of aromatics in an aromatics complex |
CN111548247B (zh) * | 2020-05-15 | 2022-06-21 | 浙江工业大学 | 通过苯与甲醇烷基化反应制备甲苯和对二甲苯的方法 |
RU2734985C1 (ru) * | 2020-05-21 | 2020-10-27 | Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН, Институт катализа СО РАН) | Способ приготовления катализатора и способ получения изопропилбензола (варианты) |
CN113045375A (zh) * | 2021-03-22 | 2021-06-29 | 浙江大学衢州研究院 | 一种由二戊基蒽烷基转移制备2-戊基蒽的方法 |
CN114315500A (zh) * | 2021-12-15 | 2022-04-12 | 浙江恒逸石化研究院有限公司 | 一种烷基转移反应制备烷基蒽及烷基苯的方法 |
CN114931971B (zh) * | 2022-04-26 | 2023-11-14 | 榆林学院 | 一种镍纳米团簇负载晶间中孔沸石催化剂及其制备方法和应用 |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
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US3442795A (en) | 1963-02-27 | 1969-05-06 | Mobil Oil Corp | Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom |
US4083886A (en) | 1976-03-29 | 1978-04-11 | Uop Inc. | Transalkylation of alkylaromatic hydrocarbons |
US4469908A (en) | 1978-12-14 | 1984-09-04 | Mobil Oil Corporation | Alkylation of aromatic hydrocarbons |
US4371714A (en) | 1980-12-30 | 1983-02-01 | Mobil Oil Corporation | Preparation of 4-alkylanisoles and phenols |
US4419220A (en) | 1982-05-18 | 1983-12-06 | Mobil Oil Corporation | Catalytic dewaxing process |
US4954243A (en) | 1983-11-03 | 1990-09-04 | Mobil Oil Corporation | Catalytic cracking with framework aluminum extracted zeolite |
EP0259526B1 (en) | 1986-09-09 | 1991-09-18 | Exxon Research And Engineering Company | A high silica zeolite (ecr-17), a catalyst containing that zeolite, and a hydrocarbon conversion process using that catalyst |
US4891448A (en) * | 1987-11-23 | 1990-01-02 | The Dow Chemical Company | Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers |
US4891458A (en) | 1987-12-17 | 1990-01-02 | Innes Robert A | Liquid phase alkylation or transalkylation process using zeolite beta |
ES2007545A6 (es) * | 1988-08-03 | 1989-06-16 | Petroquimica Espanola S A Petr | Proceso de alquilacion catalitica en lecho fijo de hidrocarburos aromaticos. |
FR2638157B1 (fr) * | 1988-10-26 | 1991-04-19 | Inst Francais Du Petrole | Procede de production d'alkylbenzenes utilisant un catalyseur a base de mordenite modifiee |
GB8829923D0 (en) * | 1988-12-22 | 1989-02-15 | Ici Plc | Zeolites |
FR2648129B1 (fr) * | 1989-06-07 | 1991-10-31 | Inst Francais Du Petrole | Procede de production d'alkylbenzenes utilisant des catalyseurs a base de zeolithe y desaluminee |
US5019543A (en) * | 1989-07-05 | 1991-05-28 | Exxon Research & Engineering Company | High silica crystalline zeolites and process for their preparation |
US5118897A (en) | 1990-09-17 | 1992-06-02 | Abb Lummus Crest Inc. | Reactivation of alkylation catalysts |
FR2669618B1 (fr) | 1990-11-26 | 1993-05-07 | Elf Aquitaine | Procede de desalumination des zeolithes synthetiques a larges pores, catalyseurs et adsorbants organophiles selectifs renfermant les zeolithes desaluminees obtenues selon le procede et zeolithe beta essentiellement silicique. |
KR100186839B1 (ko) | 1991-06-21 | 1999-05-15 | 리챠드 지. 워터맨 | 방향족 화합물의 알킬화방법 |
US5196574A (en) | 1991-12-23 | 1993-03-23 | Uop | Detergent alkylation process using a fluorided silica-alumina |
US5200168A (en) * | 1992-01-31 | 1993-04-06 | Mobil Oil Corp. | Process for the dealumination of zeolite Beta |
US5321194A (en) | 1992-05-11 | 1994-06-14 | Mobil Oil Corporation | N-olefin skeletal isomerization process using dicarboxylic acid treated zeolites |
US5242676A (en) | 1992-05-11 | 1993-09-07 | Mobil Oil Corp. | Selective surface dealumination of zeolites using dicarboxylic acid |
US5292880A (en) * | 1992-05-11 | 1994-03-08 | Mobil Oil Corporation | Synthesis of caprolactam using catalysts |
US5234872A (en) * | 1992-05-11 | 1993-08-10 | Mobil Oil Corp. | Method for producing zeolites with reduced surface acidity |
US5238677A (en) * | 1992-06-15 | 1993-08-24 | Mobil Oil Corp. | Process for the dealumination of mordenite |
US5284989A (en) * | 1992-11-04 | 1994-02-08 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
US5304695A (en) | 1993-02-22 | 1994-04-19 | Mobil Oil Corporation | Double bond isomerization of olefin-containing feeds with minimal oligomerization using permanently surface acidity deactivated zeolite catalysts |
US5980859A (en) * | 1994-08-18 | 1999-11-09 | Uop Llc | Modified zeolite beta processes for preparation |
US5567666A (en) * | 1995-05-15 | 1996-10-22 | Mobil Oil Corporation | Selectivated zeolite catalyst treated with a dealuminizing agent |
US5770782A (en) | 1996-02-08 | 1998-06-23 | Huntsman Petrochemical Corporation | Process and system for alkylation of aromatic compounds |
US5723710A (en) | 1996-07-12 | 1998-03-03 | Uop | Zeolite beta and its use in aromatic alkylation |
US5874647A (en) | 1996-08-20 | 1999-02-23 | Solutia Inc. | Benzene hydroxylation catalyst stability by acid treatment |
US5929295A (en) | 1997-08-06 | 1999-07-27 | Phillips Petroleum Company | Hydrodealkylation and transalkylation of C9 + aromatic compounds |
US6617481B1 (en) | 1998-12-29 | 2003-09-09 | Uop Llc | Process for producing phenyl-alkanes using an adsorptive separation section |
US6620402B2 (en) | 1999-12-06 | 2003-09-16 | Haldor Topsoe A.S | Method of preparing zeolite single crystals with straight mesopores |
US6747182B2 (en) * | 2000-03-24 | 2004-06-08 | Exxonmobil Chemical Patents Inc. | Production of alkylated aromatic compounds using dealuminated catalysts |
CA2562905C (en) * | 2004-04-20 | 2011-10-11 | Uop Llc | Uzm-8 and uzm-8hs crystalline aluminosilicate zeolitic compositions and processes using the compositions |
US7253331B2 (en) | 2004-05-12 | 2007-08-07 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
-
2009
- 2009-01-14 US US12/353,693 patent/US8450232B2/en not_active Expired - Fee Related
- 2009-10-02 WO PCT/US2009/059353 patent/WO2010082963A1/en active Application Filing
- 2009-10-02 MX MX2011007475A patent/MX2011007475A/es active IP Right Grant
- 2009-10-02 MY MYPI20113223 patent/MY152666A/en unknown
- 2009-10-02 KR KR1020117018954A patent/KR101510086B1/ko not_active IP Right Cessation
- 2009-10-02 CN CN200980158015.8A patent/CN102387861B/zh not_active Expired - Fee Related
- 2009-10-02 BR BRPI0924186A patent/BRPI0924186A2/pt not_active IP Right Cessation
- 2009-10-02 JP JP2011546241A patent/JP5404814B2/ja not_active Expired - Fee Related
- 2009-10-02 CA CA2749122A patent/CA2749122A1/en not_active Abandoned
- 2009-10-02 EP EP09838536A patent/EP2387464A4/en not_active Withdrawn
- 2009-10-02 SG SG2011051075A patent/SG172989A1/en unknown
- 2009-10-27 CL CL2009002000A patent/CL2009002000A1/es unknown
- 2009-11-30 TW TW098140769A patent/TWI435764B/zh not_active IP Right Cessation
-
2010
- 2010-01-12 AR ARP100100073A patent/AR075016A1/es active IP Right Grant
-
2011
- 2011-07-04 NO NO20110968A patent/NO20110968A1/no not_active Application Discontinuation
-
2013
- 2013-04-18 US US13/865,278 patent/US20130230450A1/en not_active Abandoned
-
2015
- 2015-04-06 AR ARP150101031A patent/AR099964A2/es unknown
Also Published As
Publication number | Publication date |
---|---|
AR075016A1 (es) | 2011-03-02 |
SG172989A1 (en) | 2011-08-29 |
CN102387861A (zh) | 2012-03-21 |
CA2749122A1 (en) | 2010-07-22 |
NO20110968A1 (no) | 2011-08-11 |
US20100179359A1 (en) | 2010-07-15 |
KR101510086B1 (ko) | 2015-04-10 |
KR20110111484A (ko) | 2011-10-11 |
TW201029740A (en) | 2010-08-16 |
US20130230450A1 (en) | 2013-09-05 |
TWI435764B (zh) | 2014-05-01 |
CN102387861B (zh) | 2015-09-09 |
CL2009002000A1 (es) | 2010-01-04 |
JP2012515081A (ja) | 2012-07-05 |
BRPI0924186A2 (pt) | 2019-09-24 |
MY152666A (en) | 2014-10-31 |
WO2010082963A1 (en) | 2010-07-22 |
US8450232B2 (en) | 2013-05-28 |
EP2387464A1 (en) | 2011-11-23 |
JP5404814B2 (ja) | 2014-02-05 |
EP2387464A4 (en) | 2012-01-18 |
AR099964A2 (es) | 2016-08-31 |
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