MX2009012234A - Activacion de catalizadores de alta selectividad en plantas de oxido de olefina. - Google Patents
Activacion de catalizadores de alta selectividad en plantas de oxido de olefina.Info
- Publication number
- MX2009012234A MX2009012234A MX2009012234A MX2009012234A MX2009012234A MX 2009012234 A MX2009012234 A MX 2009012234A MX 2009012234 A MX2009012234 A MX 2009012234A MX 2009012234 A MX2009012234 A MX 2009012234A MX 2009012234 A MX2009012234 A MX 2009012234A
- Authority
- MX
- Mexico
- Prior art keywords
- reactor
- temperature
- high selectivity
- heat source
- external heat
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un método para obtener una temperatura de inicio controlada de un proceso de epoxidación que excede la temperatura máxima que se puede alcanzar en un reactor de epoxidación con relación al uso de una fuerte de calor externa. El método de la presente invención utiliza una reacción de oxidación dentro del reactor para llevar la temperatura del reactor a una temperatura que es apropiada para acondicionar un catalizador de alta selectividad. El método de la presente invención incluye primeramente llevar el reactor que incluye un catalizador de alta selectividad a una primera temperatura utilizando la fuente de calor externa al reactor, el cual mientras está dentro del reactor designa limitaciones y mantiene en flujo de gas al reactor que está dentro de 25 a 100% del rango de diseño. Una vez que el reactor haya alcanzado la primera temperatura, al menos una olefina, por ejemplo, etileno y después oxígeno son introducidos al gas de alimentación del reactor. Las concentraciones y de olefina y oxígeno son ajustadas para tener un calor de reacción que permitirá el crecimiento del flujo de gas en el reactor a 100% del diseño y después suficiente calor de reacción para elevar la temperatura de reacción a una segunda temperatura la cual es mayor que la primera temperatura y mayor que la temperatura del reactor que se puede alcanzar por la fuente de calor externa.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US91762107P | 2007-05-11 | 2007-05-11 | |
PCT/US2008/005838 WO2008140714A1 (en) | 2007-05-11 | 2008-05-07 | Start-up of high selectivity catalysts in olefin oxide plants |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2009012234A true MX2009012234A (es) | 2010-03-26 |
Family
ID=40002537
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2009012234A MX2009012234A (es) | 2007-05-11 | 2008-05-07 | Activacion de catalizadores de alta selectividad en plantas de oxido de olefina. |
Country Status (11)
Country | Link |
---|---|
US (1) | US7696368B2 (es) |
EP (1) | EP2162446B8 (es) |
JP (1) | JP2010527352A (es) |
KR (1) | KR101485955B1 (es) |
CN (1) | CN101711239B (es) |
BR (1) | BRPI0811260B8 (es) |
CA (1) | CA2687234C (es) |
MX (1) | MX2009012234A (es) |
RU (1) | RU2452564C2 (es) |
TW (1) | TWI526248B (es) |
WO (1) | WO2008140714A1 (es) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7553980B2 (en) † | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
US9115104B2 (en) * | 2009-01-27 | 2015-08-25 | Scientific Design Company, Inc. | Ethylene oxide catalyst with optimized cesium content |
US8530682B2 (en) | 2009-12-17 | 2013-09-10 | Scientific Design Company, Inc. | Process for epoxidation start-up |
CA2784603C (en) | 2009-12-23 | 2018-06-12 | Nabil Rizkalla | A process for initiating a highly selective ethylene oxide catalyst |
EP2651908B1 (en) | 2010-12-15 | 2016-02-24 | Dow Technology Investments LLC | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
SG193989A1 (en) * | 2011-04-11 | 2013-11-29 | Dow Technology Investments Llc | Process for conditioning a high efficiency ethylene oxide catalyst |
BR112014009339A2 (pt) * | 2011-10-18 | 2017-04-18 | S Padia Ashok | processo de epoxidação com adição de moderador |
CN105008339B (zh) * | 2013-01-11 | 2017-09-12 | 科学设计公司 | 具有后调节步骤的环氧化工艺 |
EP3548471B1 (en) | 2016-12-02 | 2021-05-19 | Shell Internationale Research Maatschappij B.V. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
CN113121474A (zh) * | 2019-12-30 | 2021-07-16 | 中国石油化工股份有限公司 | 乙烯环氧化银催化剂的开车方法 |
CN114436998A (zh) * | 2020-11-05 | 2022-05-06 | 中国石油化工股份有限公司 | 一种乙烯环氧化开车方法 |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2040782A (en) | 1936-05-12 | Manufacture of olefine oxides | ||
US1998878A (en) | 1931-03-27 | 1935-04-23 | Fr De Catalyse Generalisee Sa | Process for the production of ethylene oxide |
US3702619A (en) | 1971-01-28 | 1972-11-14 | Shell Oil Co | In-line mixing apparatus for gases |
US4012425A (en) | 1972-01-07 | 1977-03-15 | Shell Oil Company | Ethylene oxide process |
JPS5136245B2 (es) | 1973-09-07 | 1976-10-07 | ||
US3873440A (en) | 1973-11-14 | 1975-03-25 | Universal Oil Prod Co | Startup method for exothermic catalytic reaction zones |
JPS5341233B2 (es) | 1973-11-28 | 1978-11-01 | ||
US4066575A (en) | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
DE2636680C3 (de) | 1976-08-14 | 1979-04-05 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren |
US4350616A (en) | 1980-07-03 | 1982-09-21 | The Dow Chemical Company | Method of making catalysts for the production of ethylene oxide |
US4808738A (en) | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
IN169589B (es) * | 1986-10-31 | 1991-11-16 | Shell Int Research | |
US4820675A (en) | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US4833261A (en) | 1986-10-31 | 1989-05-23 | Shell Oil Company | Ethylene oxide process |
US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US4921681A (en) | 1987-07-17 | 1990-05-01 | Scientific Design Company, Inc. | Ethylene oxide reactor |
US4874879A (en) | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
CA1339317C (en) | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
US5145824A (en) | 1991-01-22 | 1992-09-08 | Shell Oil Company | Ethylene oxide catalyst |
US5155242A (en) | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
US5364826A (en) | 1993-09-13 | 1994-11-15 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
CA2137310C (en) * | 1993-12-20 | 2004-02-17 | John C. Jubin Jr. | Catalytic converter and method for highly exothermic reactions |
US5418202A (en) | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
EP0789693B1 (en) | 1994-11-01 | 1999-01-07 | Shell Internationale Researchmaatschappij B.V. | Process for preparing ethylene oxide catalysts |
US5739075A (en) | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
US5760253A (en) | 1997-01-29 | 1998-06-02 | Arco Chemical Technology, L.P. | Catalytic converter and method for highly exothermic reactions |
DE10034320A1 (de) | 2000-07-14 | 2002-02-07 | Inst Pflanzenbiochemie Ipb | Verfahren zur Beeinflussung des Sinapingehalts in transgenen Pflanzenzellen und Pflanzen |
US7132555B2 (en) | 2000-09-26 | 2006-11-07 | Shell Oil Company | Rod-shaped inserts in reactor tubes |
EP1247806A1 (en) * | 2001-03-05 | 2002-10-09 | Degussa AG | Process for the epoxidation of olefins |
EP1247805A1 (en) * | 2001-03-05 | 2002-10-09 | Degussa AG | Process for the epoxidation of olefins |
AU2003243758A1 (en) | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin |
DE60333292D1 (de) | 2002-06-28 | 2010-08-19 | Shell Int Research | Verfahren für den start eines epoxierungsprozesses und epoxidierungsverfahren für olefine |
EP1517751B2 (en) | 2002-06-28 | 2016-06-01 | Shell Internationale Research Maatschappij B.V. | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
US6960671B2 (en) * | 2002-09-20 | 2005-11-01 | Arco Chemical Technology, L.P. | Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein |
KR20060002920A (ko) | 2003-04-01 | 2006-01-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 올레핀 에폭시화 방법 및 그 방법에 사용하기 위한 촉매 |
US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
-
2008
- 2008-05-07 RU RU2009145963/04A patent/RU2452564C2/ru active
- 2008-05-07 WO PCT/US2008/005838 patent/WO2008140714A1/en active Application Filing
- 2008-05-07 MX MX2009012234A patent/MX2009012234A/es active IP Right Grant
- 2008-05-07 EP EP08754227.0A patent/EP2162446B8/en not_active Revoked
- 2008-05-07 BR BRPI0811260A patent/BRPI0811260B8/pt active IP Right Grant
- 2008-05-07 CA CA2687234A patent/CA2687234C/en active Active
- 2008-05-07 CN CN2008800157212A patent/CN101711239B/zh active Active
- 2008-05-07 US US12/116,653 patent/US7696368B2/en active Active
- 2008-05-07 JP JP2010508369A patent/JP2010527352A/ja active Pending
- 2008-05-07 KR KR20097025846A patent/KR101485955B1/ko active IP Right Grant
- 2008-05-09 TW TW097117314A patent/TWI526248B/zh active
Also Published As
Publication number | Publication date |
---|---|
EP2162446B8 (en) | 2016-06-01 |
BRPI0811260A2 (pt) | 2014-11-04 |
CA2687234C (en) | 2016-04-19 |
RU2009145963A (ru) | 2011-06-20 |
KR101485955B1 (ko) | 2015-01-22 |
US7696368B2 (en) | 2010-04-13 |
CN101711239A (zh) | 2010-05-19 |
JP2010527352A (ja) | 2010-08-12 |
CN101711239B (zh) | 2012-09-26 |
BRPI0811260B8 (pt) | 2017-03-21 |
EP2162446A1 (en) | 2010-03-17 |
TW200906482A (en) | 2009-02-16 |
TWI526248B (zh) | 2016-03-21 |
WO2008140714A1 (en) | 2008-11-20 |
EP2162446B1 (en) | 2016-03-16 |
EP2162446A4 (en) | 2011-09-07 |
US20080306291A1 (en) | 2008-12-11 |
RU2452564C2 (ru) | 2012-06-10 |
CA2687234A1 (en) | 2008-11-20 |
KR20100022977A (ko) | 2010-03-03 |
BRPI0811260B1 (pt) | 2017-01-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX2009012234A (es) | Activacion de catalizadores de alta selectividad en plantas de oxido de olefina. | |
MY157612A (en) | Process for epoxidation start-up | |
DE60109821D1 (de) | Katalysator und prozess zur epoxidierung | |
WO2003014014A3 (en) | Catalyst and its use in the synthesis of hydrogen peroxide | |
EP2679284A3 (en) | Chemical oxygen generator with bimetal reaction control | |
MY150586A (en) | Olefin production process | |
MX2010002725A (es) | Produccion de oxido de etileno utilizando concentracion moderadora fija. | |
EP3090997A1 (en) | A process for methane to methanol conversion at low temperature | |
Noujima et al. | Unique catalysis of gold nanoparticles in the chemoselective hydrogenolysis with H 2: cooperative effect between small gold nanoparticles and a basic support | |
MX351029B (es) | Procesos de epoxidación. | |
MX2012007440A (es) | Un proceso para iniciar un catalizador de oxido de etileno altamente selectivo. | |
US8679999B2 (en) | Process for regeneration of titano silicate catalyst | |
WO2013023257A8 (pt) | Processo catalítico oxidativo para síntese de ácido lático | |
NO20021698D0 (no) | Integrert prosess for fremstilling av epoksyder | |
US20190023672A1 (en) | Methods for direct epoxidation of propylene with oxygen | |
CN105170176A (zh) | 一种烯烃环氧化催化剂及其制备方法和应用 | |
CN101687831A (zh) | 混合气体的制造方法和制造装置、以及环氧化合物的制造装置和制造方法 | |
IN2012DN05166A (es) | ||
TWI466875B (zh) | Method for making epoxides | |
WO2009053026A3 (en) | Process for producing carnosol from carnosic acid using hydrogen peroxide or peracids | |
JP2010037229A (ja) | 二酸化炭素からのメタノール合成方法 | |
CN112341322A (zh) | 一种氧气氧化合成2,3,5-三甲基-1,4-苯醌的方法 | |
ATE497954T1 (de) | Direktes epoxidierungsverfahren unter verwendung eines gemischten katalysatorsystems | |
WO2011084606A3 (en) | Process for olefin oxide production | |
JP2004269379A (ja) | プロピレンオキサイドの製造方法。 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration |