MX173383B - Catalizador soportado para la polimerizacion y copolimerizacion de los compuestos insaturados olefinicamente y a un procedimiento de copolimerizacion el cual lo usa - Google Patents
Catalizador soportado para la polimerizacion y copolimerizacion de los compuestos insaturados olefinicamente y a un procedimiento de copolimerizacion el cual lo usaInfo
- Publication number
- MX173383B MX173383B MX025057A MX2505791A MX173383B MX 173383 B MX173383 B MX 173383B MX 025057 A MX025057 A MX 025057A MX 2505791 A MX2505791 A MX 2505791A MX 173383 B MX173383 B MX 173383B
- Authority
- MX
- Mexico
- Prior art keywords
- copolymerization
- polymerization
- supported catalyst
- unsaturated compounds
- olefinically unsaturated
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 238000007334 copolymerization reaction Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 229910052779 Neodymium Inorganic materials 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000004005 microsphere Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Abstract
La presente invención se refiere a un catalizador soportado activo, en la polimerización y la copolimerización de compuestos olefinicamente insaturados, que comprende un compuesto organometálico de aluminio y un componente que se obtiene mediante un compuesto de magnesio, y/o titanio, vanadio o cromo y posiblemente al menos un compuesto de un segundo metal que se selecciona de V, Al, Zr, Hf, Mo y Nd, en contacto con un soporte poroso, caracterizado, porque el soporte poroso comprende microesferas de aerogel de uno o más óxidos inorgánicos y que tienen una área de superficie que excede 300 m2/g, un volumen de poro total que excede lml./mg y al menos el 90 por ciento de sus poros, tienen un diámetro que varía dentro de un rango muy pequeño de valores, siendo la diferencia entre los valores máximo y mínimo de mas de 50 A y el diámetro siendo entre 50 y 1000 A.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19816A IT1240613B (it) | 1990-03-26 | 1990-03-26 | Catalizzatore supportato per la polimerizzazione e la copolimerizzazione di composti olefinicamente insaturi, e procedimento di (co) polimerizzazione impiegante lo stesso |
| CA002050814A CA2050814A1 (en) | 1990-03-26 | 1991-09-06 | Supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds, and a (co)polymerization process which uses it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX173383B true MX173383B (es) | 1994-02-24 |
Family
ID=25674781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX025057A MX173383B (es) | 1990-03-26 | 1991-03-25 | Catalizador soportado para la polimerizacion y copolimerizacion de los compuestos insaturados olefinicamente y a un procedimiento de copolimerizacion el cual lo usa |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US5189000A (es) |
| EP (1) | EP0449355B1 (es) |
| JP (1) | JP3303239B2 (es) |
| KR (1) | KR930011529B1 (es) |
| CN (1) | CN1055184A (es) |
| AT (1) | ATE138667T1 (es) |
| AU (1) | AU631489B2 (es) |
| BR (1) | BR9101191A (es) |
| CA (2) | CA2039015C (es) |
| DE (1) | DE69119813T2 (es) |
| DK (1) | DK0449355T3 (es) |
| ES (1) | ES2088456T3 (es) |
| FI (1) | FI105557B (es) |
| GR (1) | GR3020634T3 (es) |
| IT (1) | IT1240613B (es) |
| MX (1) | MX173383B (es) |
| NO (1) | NO177388C (es) |
| PT (1) | PT97131B (es) |
| ZA (1) | ZA912200B (es) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1240673B (it) * | 1990-04-24 | 1993-12-17 | Tenav | Microsfere di aerogels di ossidi inorganici a stretta distribuzione dei diametri dei pori e metodo per la loro preparazione |
| IT1251939B (it) * | 1991-10-17 | 1995-05-27 | Donegani Guido Ist | Procedimento per la preparazione di materiali a base di ossidi inorganici con granulometria monodispersa e materiali cosi ottenuti. |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| CA2116259A1 (en) * | 1993-02-23 | 1994-08-24 | Akira Sano | Solid catalyst components for olefin polymerization and use thereof |
| DE4334045A1 (de) * | 1993-10-06 | 1995-04-13 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen |
| JP3355572B2 (ja) * | 1994-08-23 | 2002-12-09 | 新日本石油株式会社 | オレフィン類重合触媒およびそれを用いたポリオレフィンの製造方法 |
| EP0779837B1 (en) | 1994-09-08 | 2001-08-01 | Mobil Oil Corporation | Catalytic control of the mwd of a broad/bimodal resin in a single reactor |
| US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
| US5895770A (en) * | 1995-02-28 | 1999-04-20 | Pq Corporation | Olefin polymerization catalysts with specific silica supports |
| US5914377A (en) * | 1995-04-04 | 1999-06-22 | Bayer Ag | Method for the production of diene rubbers in the gas phase |
| US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
| US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
| AU3505497A (en) * | 1996-07-15 | 1998-02-09 | Mobil Oil Corporation | Comonomer pretreated bimetallic catalyst for blow molding and film applications |
| US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
| US6051525A (en) * | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
| EP1066110B1 (en) * | 1998-03-26 | 2003-05-21 | Dow Global Technologies Inc. | Ion exchanged aluminium-magnesium silicate or fluorinated magnesium silicate aerogels and catalyst supports therefrom |
| IT1311978B1 (it) | 1999-03-25 | 2002-03-22 | Polimeri Europa Srl | Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine. |
| US6828268B1 (en) * | 1999-11-05 | 2004-12-07 | Phillips Petroleum Company | Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst |
| DE60104809T2 (de) * | 2001-02-07 | 2005-01-05 | Saudi Basic Industries Corp. | Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung |
| WO2003048213A1 (en) * | 2001-11-30 | 2003-06-12 | Exxonmobil Chemical Patents, Inc. | Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use |
| US8227046B2 (en) * | 2002-11-29 | 2012-07-24 | Council Of Scientific And Industrial Research | Process for preparing self-assembling nanobinary and ternary oxy/hydroxides |
| CA2546275C (en) * | 2003-11-20 | 2012-08-07 | Union Carbide Chemicals & Plastics Technology Corporation | Spray-dried, mixed metal ziegler catalyst compositions |
| US7151073B2 (en) * | 2004-01-16 | 2006-12-19 | Exxonmobil Chemical Patents Inc. | Mesoporous catalyst support, a catalyst system, and method of making and using same for olefin polymerization |
| BRPI0911944B1 (pt) | 2008-08-06 | 2019-08-13 | Union Carbide Chem Plastic | método para preparar um catalisador componente |
| ITMI20090950A1 (it) * | 2009-05-29 | 2010-11-30 | Gegussa Novara Technology Spa | Processo per la preparazione di un aerogelo in pellets |
| KR101930976B1 (ko) * | 2011-06-01 | 2018-12-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중금속 지글러-나타 전촉매 및 그로부터 제조된 올레핀 중합용 촉매 |
| CN104448066B (zh) | 2014-12-16 | 2017-07-07 | 华东理工大学 | 一种负载型多金属烯烃聚合催化剂及其制备方法与应用 |
| CN108203478B (zh) * | 2016-12-20 | 2021-04-30 | 中国石油天然气股份有限公司 | 一种负载型含钼聚乙烯催化剂的制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7702323A (nl) * | 1977-03-04 | 1978-09-06 | Stamicarbon | Katalysator voor de bereiding van polyalkenen. |
| US4405495A (en) * | 1980-06-30 | 1983-09-20 | Union Carbide Corporation | Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization |
| IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| JPH0725817B2 (ja) * | 1986-04-23 | 1995-03-22 | 日本石油株式会社 | オレフイン重合用触媒 |
| DE3635028A1 (de) * | 1986-10-15 | 1988-04-21 | Basf Ag | Verfahren zum herstellen von homopolymerisaten des ethens sowie copolymerisaten des ethens mit hoeheren (alpha)-monoolefinen mittels eines ziegler-katalysatorsystems |
| IT1230133B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Composizioni polipropileniche plasto-elastiche |
| FR2656314B1 (fr) * | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
-
1990
- 1990-03-26 IT IT19816A patent/IT1240613B/it active IP Right Grant
-
1991
- 1991-03-19 DK DK91200594.9T patent/DK0449355T3/da active
- 1991-03-19 DE DE69119813T patent/DE69119813T2/de not_active Expired - Lifetime
- 1991-03-19 EP EP91200594A patent/EP0449355B1/en not_active Expired - Lifetime
- 1991-03-19 ES ES91200594T patent/ES2088456T3/es not_active Expired - Lifetime
- 1991-03-19 AT AT91200594T patent/ATE138667T1/de not_active IP Right Cessation
- 1991-03-21 US US07/673,272 patent/US5189000A/en not_active Expired - Lifetime
- 1991-03-22 NO NO911155A patent/NO177388C/no not_active IP Right Cessation
- 1991-03-22 ZA ZA912200A patent/ZA912200B/xx unknown
- 1991-03-25 KR KR1019910004671A patent/KR930011529B1/ko not_active IP Right Cessation
- 1991-03-25 AU AU73820/91A patent/AU631489B2/en not_active Ceased
- 1991-03-25 MX MX025057A patent/MX173383B/es unknown
- 1991-03-25 FI FI911412A patent/FI105557B/fi active
- 1991-03-25 PT PT97131A patent/PT97131B/pt active IP Right Grant
- 1991-03-25 CA CA002039015A patent/CA2039015C/en not_active Expired - Lifetime
- 1991-03-26 BR BR919101191A patent/BR9101191A/pt not_active IP Right Cessation
- 1991-03-26 CN CN91101854A patent/CN1055184A/zh active Pending
- 1991-03-26 JP JP08631091A patent/JP3303239B2/ja not_active Expired - Lifetime
- 1991-09-06 CA CA002050814A patent/CA2050814A1/en not_active Abandoned
-
1996
- 1996-07-25 GR GR960401990T patent/GR3020634T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO177388C (no) | 1995-09-06 |
| BR9101191A (pt) | 1991-11-05 |
| CA2050814A1 (en) | 1993-03-07 |
| IT9019816A0 (it) | 1990-03-26 |
| NO911155L (no) | 1991-09-27 |
| DE69119813D1 (de) | 1996-07-04 |
| AU7382091A (en) | 1991-11-14 |
| EP0449355A2 (en) | 1991-10-02 |
| NO911155D0 (no) | 1991-03-22 |
| JPH04224807A (ja) | 1992-08-14 |
| FI911412A (fi) | 1991-09-27 |
| DK0449355T3 (da) | 1996-09-09 |
| GR3020634T3 (en) | 1996-10-31 |
| FI911412A0 (fi) | 1991-03-25 |
| ATE138667T1 (de) | 1996-06-15 |
| ZA912200B (en) | 1992-01-29 |
| ES2088456T3 (es) | 1996-08-16 |
| CA2039015A1 (en) | 1991-09-27 |
| US5189000A (en) | 1993-02-23 |
| AU631489B2 (en) | 1992-11-26 |
| KR910016779A (ko) | 1991-11-05 |
| NO177388B (no) | 1995-05-29 |
| FI105557B (fi) | 2000-09-15 |
| DE69119813T2 (de) | 1996-12-19 |
| KR930011529B1 (ko) | 1993-12-10 |
| JP3303239B2 (ja) | 2002-07-15 |
| CN1055184A (zh) | 1991-10-09 |
| EP0449355B1 (en) | 1996-05-29 |
| IT9019816A1 (it) | 1991-09-26 |
| EP0449355A3 (en) | 1991-12-27 |
| CA2039015C (en) | 2002-04-16 |
| PT97131B (pt) | 1998-07-31 |
| IT1240613B (it) | 1993-12-17 |
| PT97131A (pt) | 1991-11-29 |
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