MX168892B - Procedimiento para la produccion de aldehidos - Google Patents
Procedimiento para la produccion de aldehidosInfo
- Publication number
- MX168892B MX168892B MX007175A MX717587A MX168892B MX 168892 B MX168892 B MX 168892B MX 007175 A MX007175 A MX 007175A MX 717587 A MX717587 A MX 717587A MX 168892 B MX168892 B MX 168892B
- Authority
- MX
- Mexico
- Prior art keywords
- pct
- aldehyde
- high boiling
- sec
- condensation products
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
La presente invención se refiere a un procedimiento continuo para la producción de aldehidos opcionalmente substituídos, que contienen por lo menos 7 átomos de carbono, mediante hidroformilación de una olefina, caracterizado dicho procedimiento porque comprende los pasos de: proveer una zona de hidroformilación, una zona de recuperación de producto y medios para hacer circular líquido entre la zona de hidroformilación y la zona de recuperación de producto; proveer en la zona de hidroformilación un volumen predeterminado, substancialmente constante, de un medio de hidroformilación líquido que contiene, distribuídos uniformemente en él, a) un catalizador de hidroformilación de complejo de rodio que comprende rodio en combinación compleja con monóxido de carbono y con un ligando; b) ligando libre; c) no más que una cantidad menor predeterminada de por lo menos uno de dichos aldehidos opcionalmente substituídos; y d) un solvente inerte.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB868616038A GB8616038D0 (en) | 1986-07-01 | 1986-07-01 | Process |
GB878705108A GB8705108D0 (en) | 1987-03-05 | 1987-03-05 | Process |
GB878706265A GB8706265D0 (en) | 1987-03-17 | 1987-03-17 | Process |
Publications (1)
Publication Number | Publication Date |
---|---|
MX168892B true MX168892B (es) | 1993-06-14 |
Family
ID=27263082
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX007175A MX168892B (es) | 1986-07-01 | 1987-07-01 | Procedimiento para la produccion de aldehidos |
Country Status (13)
Country | Link |
---|---|
US (1) | US5053551A (es) |
EP (1) | EP0313559B1 (es) |
JP (1) | JPH0832646B2 (es) |
KR (1) | KR950012999B1 (es) |
AT (1) | ATE66668T1 (es) |
AU (1) | AU612580B2 (es) |
BR (1) | BR8707736A (es) |
CA (1) | CA1308118C (es) |
DE (1) | DE3772574D1 (es) |
DK (1) | DK85888A (es) |
ES (1) | ES2007088A6 (es) |
MX (1) | MX168892B (es) |
WO (1) | WO1988000179A2 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0589463B1 (en) * | 1992-09-25 | 1997-08-20 | Mitsubishi Chemical Corporation | A method of controlling a hydroformylation reaction |
DE4300921C1 (de) * | 1993-01-15 | 1994-04-14 | Hoechst Ag | Verfahren zur Lösungsmittel-Rückgewinnung sowie dafür geeignete Vorrichtung |
JP3551509B2 (ja) * | 1994-12-12 | 2004-08-11 | 三菱化学株式会社 | アルデヒド類の製造方法 |
US6035743A (en) * | 1998-03-18 | 2000-03-14 | Schwinn Cycling & Fitness Inc. | Multi-functional clipless pedal |
TWI427094B (zh) * | 2010-10-25 | 2014-02-21 | Nanya Plastics Corp | 一種提高丙二酚型氫化環氧樹脂產率的氫化方法 |
SG11201405863QA (en) | 2012-04-12 | 2014-11-27 | Basf Se | Method for replenishing the catalyst in continuous hydroformylation |
MX2015002936A (es) * | 2012-09-07 | 2016-01-25 | Hse Hitit Solar Enerji Anonim Sirketi | Sistema de destilacion al vacio producido por una columna barometrica. |
KR20140042402A (ko) * | 2012-09-28 | 2014-04-07 | 주식회사 엘지화학 | 올레핀으로부터 알코올의 제조장치 및 제조방법 |
BR112018009017B1 (pt) * | 2015-11-10 | 2021-01-26 | Dow Technology Investments Llc | processo para produção de aldeídos |
CN109499081A (zh) * | 2018-12-04 | 2019-03-22 | 江苏拓驰工程技术开发有限公司 | 一种带刮板加热功能的刮膜蒸发器 |
US20220176385A1 (en) * | 2019-03-05 | 2022-06-09 | Basf Se | Mixture of octene hydroformylation by-product and diesel, kerosene or c8-c20 olefins as collectors |
CN114521194B (zh) | 2020-09-17 | 2024-03-29 | 株式会社Lg化学 | 醛的制备方法和醛的制备装置 |
CN114773172B (zh) * | 2022-06-20 | 2022-10-18 | 中海油天津化工研究设计院有限公司 | 一种烯烃氢甲酰化制醛工艺优化方法 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
GB1458375A (en) * | 1973-04-09 | 1976-12-15 | Ici Ltd | Hydroformylation |
JPS582932B2 (ja) * | 1973-09-21 | 1983-01-19 | 三菱化学株式会社 | ブチルアルデヒドの製造法 |
US4159999A (en) * | 1974-11-22 | 1979-07-03 | Celanese Corporation | Hydroformylation of olefins |
US4148830A (en) * | 1975-03-07 | 1979-04-10 | Union Carbide Corporation | Hydroformylation of olefins |
US4247486A (en) * | 1977-03-11 | 1981-01-27 | Union Carbide Corporation | Cyclic hydroformylation process |
FR2351077A1 (fr) * | 1976-05-13 | 1977-12-09 | Celanese Corp | Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium |
US4282100A (en) * | 1978-09-18 | 1981-08-04 | The Sanko Steamship Co., Ltd. | Apparatus for reforming fuel oil wherein ultrasonic waves are utilized |
DE16286T1 (de) * | 1979-03-21 | 1983-05-11 | Davy Mckee (London) Ltd., London | Hydroformylierungsverfahren. |
EP0016285B2 (en) * | 1979-03-21 | 1986-03-05 | DAVY McKEE (LONDON) LIMITED | Process for the production of valeraldehydes by hydroformylation of butene-1 |
CA1123859A (en) * | 1979-06-18 | 1982-05-18 | Edward B. Hackman | Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters |
US4329511A (en) * | 1979-06-18 | 1982-05-11 | Celanese Corporation | Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters |
JPS5645436A (en) * | 1979-09-21 | 1981-04-25 | Mitsubishi Chem Ind Ltd | Hydroformylation of olefin |
US4283562A (en) * | 1979-10-26 | 1981-08-11 | Union Carbide Corporation | Hydroformylation process using stable rhodium catalyst |
US4260828A (en) * | 1980-04-16 | 1981-04-07 | Union Carbide Corporation | Hydroformylation process |
DE3114147A1 (de) * | 1981-04-08 | 1982-10-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur gewinnung von aldehyden |
DE3371067D1 (en) * | 1982-06-11 | 1987-05-27 | Davy Mckee London | Hydroformylation process |
DE3361212D1 (en) * | 1982-06-11 | 1985-12-19 | Davy Mckee London | Hydroformylation process |
ATE28183T1 (de) * | 1982-06-11 | 1987-07-15 | Davy Mckee London | Hydroformylierungsverfahren. |
WO1984003697A1 (en) * | 1983-03-16 | 1984-09-27 | Exxon Research Engineering Co | High temperature hydroformylation |
DE3341035A1 (de) * | 1983-11-12 | 1985-05-23 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
GB8334359D0 (en) * | 1983-12-23 | 1984-02-01 | Davy Mckee Ltd | Process |
US4678857A (en) * | 1986-03-31 | 1987-07-07 | Texaco Inc. | Process for separation of product resulting from hydroformylation |
GB2192182B (en) * | 1986-07-01 | 1990-05-23 | Davy Mckee | Process for the production of aldehydes |
-
1987
- 1987-06-12 JP JP62503454A patent/JPH0832646B2/ja not_active Expired - Lifetime
- 1987-06-12 BR BR8707736A patent/BR8707736A/pt not_active IP Right Cessation
- 1987-06-12 DE DE8787903733T patent/DE3772574D1/de not_active Expired - Lifetime
- 1987-06-12 AU AU74820/87A patent/AU612580B2/en not_active Ceased
- 1987-06-12 EP EP87903733A patent/EP0313559B1/en not_active Expired - Lifetime
- 1987-06-12 US US07/278,437 patent/US5053551A/en not_active Expired - Lifetime
- 1987-06-12 KR KR1019880700224A patent/KR950012999B1/ko not_active IP Right Cessation
- 1987-06-12 AT AT87903733T patent/ATE66668T1/de not_active IP Right Cessation
- 1987-06-12 WO PCT/GB1987/000408 patent/WO1988000179A2/en active IP Right Grant
- 1987-06-30 CA CA000540943A patent/CA1308118C/en not_active Expired - Lifetime
- 1987-07-01 MX MX007175A patent/MX168892B/es unknown
- 1987-07-01 ES ES8702168A patent/ES2007088A6/es not_active Expired
-
1988
- 1988-02-19 DK DK085888A patent/DK85888A/da not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
JPH0832646B2 (ja) | 1996-03-29 |
KR880701699A (ko) | 1988-11-04 |
AU7482087A (en) | 1988-01-29 |
KR950012999B1 (ko) | 1995-10-24 |
WO1988000179A3 (en) | 1988-01-28 |
JPH01503532A (ja) | 1989-11-30 |
DE3772574D1 (de) | 1991-10-02 |
AU612580B2 (en) | 1991-07-18 |
CA1308118C (en) | 1992-09-29 |
ES2007088A6 (es) | 1989-06-01 |
ATE66668T1 (de) | 1991-09-15 |
BR8707736A (pt) | 1989-10-31 |
DK85888D0 (da) | 1988-02-19 |
EP0313559A1 (en) | 1989-05-03 |
US5053551A (en) | 1991-10-01 |
DK85888A (da) | 1988-02-19 |
WO1988000179A2 (en) | 1988-01-14 |
EP0313559B1 (en) | 1991-08-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX168892B (es) | Procedimiento para la produccion de aldehidos | |
US4283562A (en) | Hydroformylation process using stable rhodium catalyst | |
US4247486A (en) | Cyclic hydroformylation process | |
US4260828A (en) | Hydroformylation process | |
US4277627A (en) | Hydroformylation process | |
CA1191866A (en) | Hydroformylation process | |
US4297239A (en) | Hydroformylation catalyst reactivation | |
DE16285T1 (de) | Verfahren zur herstellung von aldehyden durch hydroformylierung von alkenen. | |
MY118644A (en) | Method for the production of aldehydes | |
US4374278A (en) | Hydroformylation catalyst reactivation | |
ATE24710T1 (de) | Verfahren zur herstellung von aldehyden. | |
JPS611633A (ja) | アルデヒドの製造方法 | |
ES434027A1 (es) | Procedimiento para recuperar sistemas catalicos de produc- tos brutos de hidroformilacion. | |
DE3684113D1 (de) | Verfahren zur herstellung von aldehyden. | |
SE7709110L (sv) | Hydroformyleringsforfarande | |
JPH0129778B2 (es) | ||
ATE24475T1 (de) | Verfahren zur reinigung eines gemisches von wasser mit c1-c2-alkoholen das von der industriellen herstellung von ethanol stammt, mit hilfe eines extraktionsmittels. | |
US3151166A (en) | Method for preparing color stable ethanolamines | |
SE444311B (sv) | Forfarande for hydroformylering av en alfa-olefin med 2-20 kolatomer for framstellning av aldehyder | |
US3535399A (en) | Removal of carbonyls from polymerizable monomers | |
US2684385A (en) | Continuous aldolization | |
SE444932B (sv) | Forfarande for rodiumkatalyserad hydroformylering av olefiner for framstellning av motsvarande aldehyder | |
FR2359822A1 (fr) | Procede pour la preparation d'acetate de vitamine a | |
HUT55740A (en) | Process for the production of 2,2-dimethyl-propane diol-(1,3) | |
US4036936A (en) | Process for preparing hydrazine hydrate |