LV11684B - Pesticides - Google Patents

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Publication number
LV11684B
LV11684B LVP-96-314A LV960314A LV11684B LV 11684 B LV11684 B LV 11684B LV 960314 A LV960314 A LV 960314A LV 11684 B LV11684 B LV 11684B
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LV
Latvia
Prior art keywords
alkyl
formula
methyl
compound
phenyl
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LVP-96-314A
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English (en)
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LV11684A (lv
Inventor
Hugo Ziegler
Stephan Trah
Saleem Farooq
Rene Zurfleh
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Ciba Geigy Ag
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Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Publication of LV11684A publication Critical patent/LV11684A/lv
Publication of LV11684B publication Critical patent/LV11684B/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/76—Nitrogen atoms to which a second hetero atom is attached
    • C07D213/77—Hydrazine radicals
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
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    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/46—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom rings with more than six members
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
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    • C07C251/74—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms
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    • C07C251/74—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/78—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton
    • C07C251/80—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton the carbon skeleton containing rings
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/54—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and etherified hydroxy groups bound to the carbon skeleton
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
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    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
    • C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
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    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
    • C07D295/28—Nitrogen atoms
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    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
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    • C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
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Claims (53)

  1. .11LV 11684 Izgudrojuma formula 1. Savienojums ar formulu (I) o
    A / \ I tā iespējamie izomēri un izomēru maisījumi, kur vai nu: a) X ir slāpekļa atoms un V ir ORn vai NR12R13, vai arī b) X ir CH un Y ir OR11, un, bez tam vēl: R11 ir Ci^alkilgrupa; R12 un R13, neatkarīgi viens no otra, ir ūdeņraža atoms vai Ci^alkilgrupa; A ir skābekļa atoms vai grupa NR4; R1 ir ūdeņraža atoms, CMalkilgrupa, Cļ^halogēnalkilgrupa, ciklopropilgrupa, ciāngrupa vai metiltiogrupa; 2 F?2 ir ūdeņraža atoms, C^alkilgrupa, C3-6cikloalkilgrupa, Z-B grupa
    (D)
    II (D) vai tienilgrupa; n D ir vienādi vai dažādi aizvietotāji no rindas: halogēna atoms, Ci^alkilgrupa, Ci^alkoksigrupa, C^halogēnalkilgrupa, Ci.2halogēnalkoksigrupa, C3-6alkenil-oksigrupa, C3-6alkiniloksigrupa, Ci.4alkilēndioksigrupa, ciāngrupa un nitro-grupa; n ir 0, 1, 2, 3 vai 4; Z ir -O-, -0-Ci-4alkilgrupa-, -Ci^alkilgrupa-O-, -S(0)m-, -Ci^alkilgrupa-S(0)m-, -S(0)m-Ci-4alkilgrupa-; m ir 0, 1 vai 2; B ir Cļ-ealkilgrupa, Ci-6halogēnalkilgrupa, C3-6Cikloalkilgrupa; C2-6alkenilgrupa vai C2^alkinilgrupa, neobligāti aizvietotas ar 1-3 halogēna atomiem; arilgrupa vai heterocikliska grupa, kas katra var būt neobligāti aizvietota ar 1-5 aizvietotājiem no rindas: Ci-6alkilgrupa, C^halogēnalkilgrupa, Ci-6alkoksi-grupa, halogēnaizvietota Ci-6alkoksigrupa; grupa
    vai trimetilsililgrupa; Rs, R6. R7, Re un Rg, neatkarīgi viens no otra, ir ūdeņraža atoms, Ci^alkil-grupa vai halogēna atoms; p irO, 1, 2 vai 3; R3 ir ūdeņraža atoms, Ci_6alkilgrupa; C^halogēnalkilgrupa, kas satur 1-5 halogēna atomus; CMalkoksi-Ci^alkilgrupa; C2-4alkenil-Ci.2alkilgrupa, neobligāti aizvietota ar 1-3 halogēna atomiem; C2-4alkinil-Ci_2aīkilgrupa; C3.6Cikloalkilgrupa, neobligāti aizvietota ar 1-4 halogēna atomiem; C3-6ciklo-alkil-Cļ^alkilgrupa, neobligāti aizvietota ar 1-4 halogēna atomiem; ciānaizvietota CMalkilgrupa, CMalkoksikarbonil-Cļ^alkilgrupa, C^alkoksi-karbamoil-Ci-2alkilgrupa; fenil-Ci.3alkilgrupa, neobligāti aizvietota ar halogēna atomu, Ci_3alkilgrupu, Ci^alkoksigrupu, Ci^halogēnalkilgrupu, ciāngrupu, nitrogrupu vai Ci^alkilēndioksigrupu, pie kam fenilgrupa var saturēt 1-3 vienādus vai dažādus aizvietotājus; fenilgrupa, neobligāti aizvietota ar 1-2 3 .11 LV 11684 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: Ci^alkilgrupa, CMalkoksigrupa, halogēna atoms, C-|.2halogēnalkilgrupa, kas satur 1-3 halogēna atomus, nitrogrupu vai ciāngrupu; piridinilgrupa, kas neobligāti aizvietota ar 1-2 ar 1-2 aizvietotājiem, kas neatkarīgi viens no otra ņemti no rindas: Ci^alkilgrupa, Ci^alkoksigrupa, halogēna atoms, Ci-2halogēn-alkilgrupa, kas satur 1-3 halogēna atomus, nitrogrupa vai ciāngrupa; R4 ir Ci^alkilgrupa, fenilgrupa vai arī R3 un R4 abi kopā ar slāpekļa atomu, kuram tie pievienoti, veido piesātinātu vai nepiesātinātu 5-7 locekļu ciklu, kas var papildus saturēt 1-3 heteroatomus no rindas: N, 0 un S un ir neobligāti aizvietots ar CMalkilgrupu, kur izņemot savienojumus ar formulu 1, kuros :ja X ir CH, Y ir OCH3, A ir skābekļa atoms R1 ir ūdeņraža atoms, R3 ir metilgrupa, tad R3 nav fenilgrupa, kas aizvietota tikai ar vienu vai vairākiem hlora atomiem.
  2. 2. Savienojums ar formulu (I) pēc 1. punkta, kurā vai nu: a) X ir slāpekļa atoms un Y ir OCH3 vai NHCH3 vai arī b) XirCHun Y ir OCH3, un, bez tam vēl: A ir O vai grupa NR4; R1 ir ūdeņraža atoms, Ci^alkilgrupa, Ci_4halogēnalkilgrupa, ciklopropilgrupa, ciāngrupa vai metiltiogrupa; R2 ir ūdeņraža atoms, Ci^alkilgrups, C3-dkloalkilgrupa, grupa
    n Z-B
    vai tienilgrupa; n D ir vienādi vai dažādi aizvietotāji no rindas: halogēna atoms, Ci^alkilgrupa, CMalkoksigrupa, Ci-2halogēnalkilgrupa, Ci^halogēnalkoksigrupa, C3-6alkenil-oksigrupa, C3^alkiniloksigrupa, Ci^alkilēndioksigrupa, ciāngrupa un nitrogrupa; n ir 0, 1, 2, 3 vai 4; Z ir -O-, -O-Ci^alkilgrupa-, -Ci.4alkilgrupa-0-, -S(0)m-, -Ci.4alkilgrupa-S(0)m-, -S(0)m-Ci^alkilgrupa-; 4 m ir 0, 1 vai 2; B ir Ci^alkilgrupa, C^halogēnalkilgrupa, C3.6cikloalkilgrupa; C2-6alkenilgrupa vai C2-4alkinilgrupa, neobligāti aizvietotas ar 1-3 halogēna atomiem; arilgrupa vai heterocikliska grupa, kas katra var būt neobligāti aizvietota ar 1-5 aizvietotājiem no rindas; Cvealkilgrupa, Ci-6halogēnalkilgrupa, C-|.6alkoksi-grupa, halogēnaizvietota Ci-ealkoksigrupa;
    grupa Rs, R6. R7, Re un Rg , neatkarīgi viens no otra, ir ūdeņraža atoms, Ci. 4alkilgrupa vai halogēna atoms; p irO, 1, 2 vai 3; R3 ir ūdeņraža atoms, Ci-6alkilgrupa; Ci-6halogēnalkilgrupa, kas satur 1-5 halogēna atomus; Ci^alkoksi-Ci^alkilgrupa; C2-4alkenil-Ci.2alkilgrupa, neobligāti aizvietota ar 1-3 halogēna atomiem; C2^alkinil-C1.2alkilgrupa; C3.6cikloalkilgrupa, neobligāti aizvietota ar 1-4 halogēna atomiem; C3^cikio-alkil-C^alkilgrupa, neobligāti aizvietota ar 1-4 halogēna atomiem; ciānaizvietota Ci^alkilgrupa, Ci-4alkoksikarbonil-Ci-2alkilgrupa, Ci_4alkoksi-karbamoil-Ci.2alkilgrupa; fenil-Ci.3alkilgrupa, neobligāti aizvietota ar halogēna atomu, Ci.3alkilgrupu, Ci^alkoksigrupu, Ci^halogēnalkilgrupu, ciāngrupu, nitrogrupu vai Ci^alkilēndioksigrupu, pie kam fenilgrupa var saturēt 1-3 vienādus vai dažādus aizvietotājus; fenilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: C^alkilgrupa, Ci^alkoksigrupa, halogēna atoms, Ci-2halogēnalkilgrupa, kas satur 1-3 halogēna atomus, nitrogrupa vai ciāngrupa; piridinilgrupa, kas neobligāti aizvietota ar 1-2 ar 1-2 aizvietotājiem, kas neatkarīgi viens no otra ņemti no rindas: Ci_4alkilgrupa, Cļ^alkoksigrupa, halogēna atoms, Ci_2halogēn-alkilgrupa, kas satur 1-3 halogēna atomus, nitrogrupa vai ciāngrupa; R4 ir CMalkilgrupa, fenilgrupa vai arī R3 un R4 abi kopā ar slāpekļa atomu, kuram tie pievienoti, veido piesātinātu vai nepiesātinātu 5-7 locekļu ciklu, kas var papildus saturēt 1-3 heteroatomus no rindas: N, 0 un S un ir neobligāti aizvietots ar Ci^alkilgrupu. 5 LV 11684
  3. 3. Savienojums ar formulu (I) pēc 2. punkta, kurā X ir slāpekļa atoms un Y ir OC3.
  4. 4. Savienojums ar formulu (I) pēc 2. punkta, kurā X ir CH.
  5. 5. Savienojums ar formulu (I) pēc 2. punkta, kurā X ir slāpekļa atoms, Y ir NHCH3 un Ri ir ūdeņraža atoms, metilgrupa, ciklopropilgrupa vai ciāngrupa.
  6. 6. Savienojums ar formulu (I) pēc 2. punkta, kurā A ir skābekļa atoms, NCH3 vai p-fenilēngrupa.
  7. 7. Savienojums ar formulu (I) pēc 2. punkta, kurā Ri ir ūdeņraža atoms, metilgrupa, ciklopropilgrupa vai ciāngrupa.
  8. 8. Savienojums ar formulu (I) pēc 2. punkta, kurā R2 ir CMalkilgrupa vai ciklopropilgrupa. R2 ir grupa
  9. 9. Savienojums ar formulu (I) pēc 2. punkta, kurāf~\
    (D) un D ir halogēna atoms, CMalkilgrupa, CMalkoksigrupa; C^halogēnalkilgrupa, kas satur 1-5 halogēna atomus; C-^halogēnalkoksigrupa, C3.6alkenil-oksigrupa, C3^alkiniloksigrupa, C-Malkilēndioksigrupa, ciāngrupa, nitrogrupa vai tienilgrupa; n ir 0, 1, 2, 3 vai 4. 6 III
  10. 10. Savienojums ar formulu (I) pēc jebkura no 2. līdz 7. punktam, kurā 6 III R2 ir grupa
    un Z ir -0-, -O-CMalkilgrupa-, -Ci^alkilgrupa-O-, -S(0)m-, -CMalkilgrupa-S(0)m-, -S(0)m-Ci.4alkilgrupa-.
  11. 11. Savienojums ar formulu (I) pēc jebkura no 2. līdz 7. punktam, kurā R2 ir grupa // Z-B un B ir Ci^alkilgrupa, Ci^halogēnalkilgrupa; C^alkenilgrupa vai C^alkinil-Ci.2alkilgrupa, neobligāti aizvietotas ar 1-3 halogēna atomiem; arilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem no rindas: Ci.2alkilgrupa, Ci.2halogēnalkilgrupa, halogēna atoms, Ci.2alkoksigrupa, Ci.2halogēn-alkoksigrupa; grupa R — (CH)
    R7 Rs. R6. R7, Re un R9 , neatkarīgi viens no otra, ir ūdeņraža atoms, Ci.2alkilgrupa vai halogēna atoms; p ir 0, 1,2 vai 3.
  12. 12. Savienojums ar formulu (I) pēc 2. punkta, kurā R2 ir fenilgrupa, kas stāvoklī 4 aizvietota ar aizvietotāju -Z-B.
  13. 13. Savienojums ar formulu (I) pēc 2. punkta, kurā R3 ir ūdeņraža atoms, Ci.6alkilgrupa, Ci^halogēnalkilgrupa, kas satur 1-3 halogēna atomus; Ci^alkoksi-C^alkilgrupa, Ci^alkoksikarbonil-Ci.2alkil-grupa; propenilgrupa, neobligāti aizvietota ar 1-3 halogēna atomiem; propargilgrupa, C3^cikloalkilgrupa; ciklopropilmetilgrupa, neobligāti aizvietota ar 1-2 halogēna atomiem; metilgrupa, metoksigrupa; halogēnaizvietota metilgrupa, kas satur 1-3 halogēna atomus, ciāngrupa un nitrogrupa; 7 7 LV 11684 piridinilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: halogēna atoms, metilgrupa, metoksigrupa, halogēnaizvietota metilgrupa, kas satur 1-3 halogēna atomus, ciāngrupa un nitrogrupa; vai arī R3 un R4 kopā ar slāpekļa atomu, kuram tie pievienoti, veido 5-7 locekļu ciklu, kas var papildus saturēt 1-3 heteroatomus no rindas: N, O un S un ir neobligāti aizvietots ar C^alkilgrupu.
  14. 14. Savienojums ar formulu (I) pēc jebkura no 2. līdz 13. punktam, kurā R4 ir metilgrupa vai fenilgrupa.
  15. 15. Savienojums ar formulu (I) pēc jebkura no 1. līdz 4. punktam, kurā X ir CH; Y ir OCH3; Ri ir CH3; AirO; R2 ir 4-metilfenilgrupa, 4-alliloksifenilgrupa, 4-(3-trifluormetilbenziloksi)-fenilgrupa vai 4-(2,2-dihlorciklopropilmetoksi)fenilgrupa; R3 ir CH3.
  16. 16. Savienojums ar formulu (I) pēc 1. punkta, kurā vai nu a) X ir slāpekļa atoms un Y ir OCH3 vai NHCH3, vai arī b) XirCHun Y ir OCH3, un, vēl bez tam, A ir 0 vai NR4; R1 ir ūdeņraža atoms, Ci^alkilgrupa, ciklopropilgrupa, ciāngrupa vai metiltiogrupa; R2 ir ūdeņraža atoms, Ci^alkilgrupa, C3.6Cikloalkilgrupa; fenilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: halogēna atoms, Ci^alkilgrupa, Cļ^alkoksigrupa, Ci.2halogēnalkilgrupa, Ci.2halogēnalkoksigrupa, C3.6alkeniloksigrupa, C3.6alkiniloksigrupa, Ci^alkilēndioksigrupa, ciāngrupa, nitrogrupa: tienilgrupa; 8 Īli R3 ir ūdeņraža atonļs, Ci^alkilgrupa; Ci-ehalogēnalkilgrupa, kas satur 1-5 halogēna atomus; Ci-4alkoksi-Ci-2alkilgrupa; C2-4alkenil-C1.2alkilgrupa, neobligāti aizvietota ar 1-3 halogēna atomiem; C2-4alkinil-Ci-2alkilgrupa; C3^cikloalkilgrupa, neobligāti aizvietota ar 1-4 halogēna atomiem; C3^ciklo-alkil-Ci-4alkilgrupa, neobligāti aizvietota ar 1-4 halogēna atomiem; Cļ^ciān-alkilgrupa; CMalkoksikarbonil-Ci^alkilgrupa; fenil-Cļ-salkilgrupa, neobligāti aizvietota ar 1-3 vienādiem vai dažādiem aizvietotājiem no rindas: halogēna atoms, Ci-3alkilgrupa, Ci-4alkoksigrupa, Ci^halogēnalkilgrupa, ciāngrupa, nitrogrupa, Ci^alkilēndioksigrupa; fenilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: CMalkilgrupa, Ci^alkoksigrupa, halogēna atoms; Ci.2halogēnalkilgrupa, kas satur 1-3 halogēna atomus, nitrogrupa un ciāngrupa; piridinilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: Ci^alkilgrupa, Ci^alkoksigrupa, halogēna atoms; Ci-2halogēnalkilgrupa, kas satur 1-3 halogēna atomus, nitrogrupa un ciāngrupa; R4 ir C-Malkilgrupa vai fenilgrupa, vai arī R3 un R4 kopā ar slāpekļa atomu, kuram tie pievienoti, veido 5-7 locekļu ciklu, kas var papildus saturēt 1-3 heteroatomus no rindas: N, O un S un ir neobligāti aizvietots ar Ci-4alkilgrupu.
  17. 17. Savienojums ar formulu (I) pēc 16. punkta, kurā X ir CH vai slāpekļa atoms; Y ir OCH3; R1 ir CH3; A ir O vai NR4; R1 ir metilgrupa, ciklopropilgrupa vai metiltiogrupa; R2 ir metilgrupa, ciklopropilgrupa; fenilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: halogēna atoms, C^alkilgrupa, CMalkoksigrupa; Ci-2halogēnalkilgrupa, kas satur 1-5 halogēna atomus; Ci.2halogēnalkoksigrupa, C3-6alkeniloksigrupa, C3-6alkinil-oksigrupa, Ci^alkilēndioksigrupa, ciāngrupa, nitrogrupa; vai tienilgrupa; R3 nozīmes atbilst formulā (I) dotajām; R4 ir metilgrupa vai fenilgrupa, vai arī 9 LV 11684 R3 un R4 kopā ar slāpekļa atomu, kuram tie pievienoti, veido pirolidinilgrupu, piperidinilgrupu, morfolinilgrupu, tiomorfolinilgrupu, heksametilēnimTna grupu, imidazolilgrupu, pirazolilgrupu, pirolilgrupu, 1,2,4-triazolilgrupu vai 1,2,3-triazolilgrupu.
  18. 18. Savienojums ar formulu (I) pēc 16. punkta, kurā X ir slāpekļa atoms; Y ir NHCH3; Ri ir CH3; A ir 0 vai NR4; Ri ir metilgrupa, ciklopropilgrupa vai metiltiogrupa; R2 ir metilgrupa, ciklopropilgrupa; fenilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: halogēna atoms, CMalkilgrupa, C^alkoksigrupa; Ci.2halogēnalkilgrupa, kas satur 1-5 halogēna atomus; Ci-2halogēnalkoksigrupa, C3_6alkeniloksigrupa, C3.6alkinil-oksigrupa, C^alkilēndioksigrupa, ciāngrupa, nitrogrupa; vai tienilgrupa; R3 nozīmes atbilst formulā (I) dotajām; R4 ir metilgrupa vai fenilgrupa, vai arī R3 un R4 kopā ar slāpekļa atomu, kuram tie pievienoti, veido pirolidinilgrupu, piperidinilgrupu, morfolinilgrupu, tiomorfolinilgrupu, heksametilēnimīna grupu, imidazolilgrupu, pirazolilgrupu, pirolilgrupu, 1,2,4-triazolilgrupu vai 1,2,3-triazolilgrupu.
  19. 19. Savienojums ar formulu (I) pēc 16. punkta, kurā AirO; R1 ir metilgrupa; R2 ir metilgrupa; fenilgrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: halogēna atoms, Cļ^alkilgrupa, C-Malkoksigrupa; Cļ^halogēnalkilgrupa, kas satur 1-5 halogēna atomus; Ci-2halogēnalkoksigrupa, C3.6alkeniloksigrupa, C3.6alkiniloksigrupa, CMalkilēndioksigrupa, ciāngrupa, nitrogrupa; vai tienilgrupa; R3 ir Ci-6alkilgrupa. 10
  20. 20. Savienojums ar formulu (I) pēc 16. punkta, kurā: Ri ir metilgrupa; R2 ir metilgrupa; R3 nozīmes atbilst 1. punktā minētajām; R4 ir metilgrupa vai fenilgrupa, vai arī R3 un R4 abi kopā ar slāpekļa atomu, kuram tie pievienoti, veido piesātinātu vai nepiesātinātu 5-7 locekļu ciklu, kas var papildus saturēt 1-3 heteroatomus no rindas: N, O un S un ir neobligāti aizvietots ar CMalkilgrupu.
  21. 21. Savienojums ar formulu (I) pēc 16. punkta, kurā: R3 ir ūdeņraža atoms, C-Malkilgrupa; Ci^halogēnalkilgrupa, kas satur 1-3 halogēna atomus; Ci-2alkoksi-Ci.2alkilgrupa; propenilgrupa, neobligāti aizvietota ar 1-3 halogēna atomiem; C3-6Cikloalkilgrupa; C3-6ciklo-alkilmetilgrupa, neobligāti aizvietota ar 1-2 halogēna atomiem; Ci-2ciān-alkilgrupa; Ci^alkoksikarbonil-C^alkilgrupa; fenil-Ci.2alkilgrupa, neobligāti aizvietota ar halogēna atomu, metilgrupu, metoksigrupu; halogēnmetilgrupu, kas satur 1-3 halogēna atomus; ciāngrupa un nitrogrupa; piridinilgrupa, neobligāti aizvietota ar 1-2 vienādiem vai dažādiem aizvietotājiem, kas ņemti no rindas: halogēna atoms, metilgrupa, metoksigrupa; halogēnmetilgrupa, kas satur 1-3 halogēna atomus; ciāngrupa, nitrogrupa; R4 ir metilgrupa vai fenilgrupa, vai arī R3 un R4 abi kopā ar slāpekļa atomu, kuram tie pievienoti, veido piesātinātu vai nepiesātinātu 5-7 locekļu ciklu, kas var papildus saturēt 1-3 heteroatomus no rindas: N, O un S un ir neobligāti aizvietots ar Ci^alkilgrupu.
  22. 22. Savienojums ar formulu (I) pēc 21. punkta, kurā: R3 un R4 abi kopā ar slāpekļa atomu, kuram tie pievienoti, veido triazolilgrupu, morfolinilgrupu, 2,6-dimetilmorfoIinilgrupu, azepinilgrupu, piperidinilgrupu vai pirolidinilgrupu.
  23. 23. Savienojums ar formulu (I) pēc 16. punkta, kurā: AirO; R1 ir metilgrupa; 11 ,11 11 ,11 LV 11684 R2 ir metilgrupa; feniigrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: halogēna atoms, Ci^alkilgrupa, Ci^alkoksigrupa; Ci_2halogēnalkilgrupa, kas satur 1-5 halogēna atomus; Ci-2halogēnalkoksigrupa, C3-6alkeniloksigrupa, C3^alkiniloksigrupa, Ci^alkilēndioksigrupa, ciāngrupa, nitrogrupa; vai tienilgrupa; R3 ir ūdeņraža atoms, CMalkilgrupa; Ci^halogēnalkilgrupa, kas satur 1-3 halogēna atomus; C^alkoksi-Ci^alkilgrupa; propenilgrupa, neobligāti aizvietota ar 1-3 halogēna atomiem; C3^cikloalkilgrupa; C3-6Ciklo-alkilmetilgrupa, neobligāti aizvietota ar 1-2 halogēna atomiem; Ci-2ciān-alkilgrupa; Ci.2alkoksikarbonil-Ci-2alkilgrupa; fenil-Ci.2alkilgrupa, neobligāti aizvietota ar halogēna atomu, metilgrupu, metoksigrupu; halogēnmetilgrupu, kas satur 1-3 halogēna atomus; ciāngrupu vai nitrogrupu; piridinilgrupa, neobligāti aizvietota ar 1-2 vienādiem vai dažādiem aizvietotājiem, kas ņemti no rindas: halogēna atoms, metilgrupa, metoksigrupa, halogēnmetilgrupa, kas satur 1-3 halogēna atomus, ciāngrupa, nitrogrupa.
  24. 24. Savienojums ar formulu (I) pēc 23. punkta, kurā: A ir 0; R1 ir metilgrupa; R2 ir metilgrupa; feniigrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: halogēna atoms, metilgrupa, metoksigrupa, trifluormetilgrupa un trifluormetoksigrupa; R3 ir metilgrupa.
  25. 25. Savienojums ar formulu (I) pēc 16. punkta, kurā" A ir NCH3; R1 ir metilgrupa; R2 ir metilgrupa; feniigrupa, neobligāti aizvietota ar 1-2 aizvietotājiem, kas, neatkarīgi viens no otra, ņemti no rindas: halogēna atoms, metilgrupa, metoksigrupa, trifluormetilgrupa un trifluormetoksigrupa; R3 ir metilgrupa; feniigrupa, neobligāti aizvietota ar halogēna atomu, metilgrupu, metoksigrupu; halogēnmetilgrupu, kas satur 1-3 halogēna atomus; ciāngrupu vai nitrogrupu; piridinilgrupa, neobligāti aizvietota ar 1-2 12 vienādiem vai dažādiem aizvietotājiem, kas ņemti no rindas: halogēna atoms, metilgrupa, metoksigrupa, halogēnmetilgrupa, kas satur 1-3 halogēna atomus, ciāngrupa, nitrogrupa.
  26. 26. Savienojums ar formulu (I) pēc 1. punkta, kurā: X ir slāpekļa atoms; Y ir ORi 1; Rn irCi^alkilgrupa; A, Ri, R2 un R3 nozīmes atbilst 1. punktā minētajām.
  27. 27. Savienojums ar formulu (I) pēc 26. punkta, kurā: AirO; Rļ un R2 ir metilgrupa; R3 ir ūdeņraža atoms, Ci.4alkilgrupa; Ci^halogēnalkilgrupa, kas satur 1-3 halogēna atomus; C-i-2alkoksi-Ci.2alkilgrupa; propenilgrupa, neobligāti aizvietota ar 1-3 halogēna atomiem; propargilgrupa; C3^cikloalkilgrupa; C3.6cikloalkilmetilgrupa, neobligāti aizvietota ar 1-2 halogēna atomiem; Ci.2ciānalkilgrupa; Ci.2alkoksikarbonil-Ci.2alkilgrupa; fenil-Ci.2alkilgrupa, neobligāti aizvietota ar halogēna atomu, metilgrupu, metoksigrupu; halogēnmetilgrupu, kas satur 1-3 halogēna atomus; ciāngrupu vai nitrogrupu; piridinilgrupa, neobligāti aizvietota ar 1-2 vienādiem vai dažādiem aizvietotājiem, kas ņemti no rindas: halogēna atoms, metilgrupa, metoksigrupa, halogēnmetilgrupa, kas satur 1-3 halogēna atomus, ciāngrupa, nitrogrupa.
  28. 28. Savienojums ar formulu (I) pēc 1. punkta, kurā: X ir slāpekļa atoms; Y ir NR12R13; R12 un R13, neatkarīgi viens no otra, ir ūdeņraža atoms vai Ci.4alkilgrupa; A, R1, R2 un R3 nozīmes atbilst 1. punktā minētajām.
  29. 30. Savienojums ar formulu (I) pēc 29. punkta, kurā: Y ir NH2, N(CH3)2 vai NHC2H5; .11 .11 13 LV 11684 A ir O; Ri un R2 ir metilgrupa; R3 ir ūdeņraža atoms, Ci^alkilgrupa; CMhalogēnalkilgrupa, kas satur 1-3 halogēna atomus; Ci.2alkoksi-Ci.2alkilgrupa; propenilgrupa, neobligāti aizvietota ar 1-3 halogēna atomiem; propargilgrupa; C3_6Cikloalkilgrupa; C3-6Cikloalkilmetilgrupa, neobligāti aizvietota ar 1-2 halogēna atomiem; Ci.2ciānalkilgrupa; Ci.2alkoksikarbonil-Ci-2alkilgrupa; fenil-Ci^alkilgrupa, neobligāti aizvietota ar halogēna atomu, metilgrupu, metoksigrupu; halogēnmetilgrupu, kas satur 1-3 halogēna atomus; ciāngrupu vai nitrogrupu; fenilgrupa, neobligāti aizvietota ar halogēna atomu, metilgrupu, metoksigrupu; halogēnmetilgrupu, kas satur 1-3 halogēna atomus; ciāngrupu vai nitrogrupu; piridinilgrupa, neobligāti aizvietota ar 1-2 vienādiem vai dažādiem aizvietotājiem, kas ņemti no rindas: halogēna atoms, metilgrupa, metoksigrupa, halogēnmetilgrupa, kas satur 1-3 halogēna atomus, ciāngrupa, nitrogrupa.
  30. 31. Savienojums ar formulu (I) pēc 30. punkta, kurā: R3 ir ūdeņraža atoms, C-Malkilgrupa vai CMhalogēnalkilgrupa, kas satur 1-3 halogēna atomus.
  31. 32. Savienojums ar formulu (I) pēc 1. punkta, kurā X=C saite ir E formā.
  32. 33. Paņēmiens savienojuma ar formulu (I) pēc 1. punkta iegūšanai, kas paredz: A) lai iegūtu savienojumu ar formulu (I), kurā Y ir NR12R13, apstrādā savienojumu ar formulu (I), kurā Y ir ORn ar HNR12R13 šķīdumā pie temperatūras no 0 °C līdz 40 °C; B) lai iegūtu savienojumu ar formulu (I), kurā X, Y, A un R1 - R3 nozīmes atbilst formulā (I) dotajām, pie kam R3 nav ūdeņraža atoms: oksīmu ar formulu (II) II 14 II 14 HON
    R kur A un Ri - R3 nozīmes ir jau minētās, apstrādā ar savienojumu (III) O
    III kur X un Y nozīmes ir jau minētās, bet U ir atšķeļamā grupa, inertā organiskā šķīdinātājā bāzes klātienē, neobligātā starpfāzu katalizatora klātienē pie temperatūras no 0 °C līdz 50 °C;
    C) lai iegūtu savienojumu ar formulu (I), kurā A ir skābekļa atoms un X, Y un R1 - R3 nozīmes ir formulā (I) minētās- 0 oksīmu ar formulu (IV) kurā X, Y, R1 un R2 nozīmes ir jau minētās, apstrādā ar savienojumu (V) (V) U-R3 kur R3 nozīmes atbilst formulai (I) minētajām, bet U nozīmes atbilst formulai (III) minētajām, pie tam R3 nav ne ūdeņraža atoms, nedz arī fenilgrupa vai piridinilgrupa; D) lai iegūtu savienojumu ar formulu (IV), kurā X, Y, R1 un R2 nozīmes atbilst formulai (I) minētajām: ketonu ar formulu (VI) 15 .11 LV 11684 Ο h3c
    VI kurā X, Y, Rļ un R2 nozīmes ir jau minētās, apstrādā ar hidroksilamīnu vai tā sāli šķīdumā pie temperatūras no 0 °C līdz 50 °C; E) lai iegūtu savienojumu ar formulu (I), kurā A, X, Y un Rļ - R3 nozīmes ir formulai (I) minētās, pie kam R3 nav ūdeņraža atoms: enolu vai oksīmu ar formulu (VII) o
    VII kurā A, X, Y un Rļ - R3 nozīmes ir jau minētās, apstrādā ar metilējošu aģentu, piemēram, metiljodīdu, dimetilsulfātu vai diazometānu piemērotā šķīdinātājā bāzes klātienē.
  33. 34. Paņēmiens savienojuma ar formulu (VII) o
    VII 16 kurā A, X, Y un Ri - R3 nozīmes ir formulai (I) minētās, iegūšanai, kas paredz: a) lai iegūtu savienojumu ar formulu (VII), kurā X ir CH: feniletiķskābes atvasinājumu ar formulu (VIII) O
    vm kurā A, Y un R1 - R3 nozīmes ir jau minētās, apstrādā ar skudrskābes esteri bāzes klātienē; B) lai iegūtu savienojumu ar formulu (VII), kurā X ir slāpekļa atoms: feniletiķskābes atvasinājumu ar formulu (VIII), kur A, Y un R, - R3 nozīmes ir jau minētās, apstrādā ar slāpekļpaskābi vai tās esteri bāzes klātienē; C) lai iegūtu savienojumu ar formulu (VII), kurā X ir CH: ketoesteri ar formulu (IX) o o il
    IX kurā A, Y un Rļ - R3 nozīmes ir jau minētās, apstrādā ar metoksimetilēntrifenilfosforānu; D) lai iegūtu savienojumu ar formulu (VII), kurā X ir N: 17 II LV 11684 ketoesteri ar formulu (IX), kurā A, Y un Ri - R3 nozīmes ir jau minētās, apstrādā ar O-metilhidroksilamīnu vai tā sāli.
  34. 35. Kompozīcija, kas paredzēta kaitēkļu iznīcināšanai, atšķiras ar to, ka tā kā aktīvo vielu satur savienojumu pēc 1. punkta kopā ar piemērotu nesēju.
  35. 36. Kompozīcija pēc 35. punkta, kas atšķiras ar to, ka aktīvā viela ir savienojums, kas minēts jebkurā no 2. līdz 15. punktam.
  36. 37. Kompozīcija pēc 35. punkta, kas atšķiras ar to, ka aktīvā viela ir savienojums, kas minēts jebkurā no 16. līdz 25. punktam.
  37. 38. Kompozīcija pēc 35. punkta, kas atšķiras ar to, ka aktīvā viela ir savienojums, kas minēts jebkurā no 26. līdz 32. punktam.
  38. 39. Kompozīcija pēc jebkura no 35. līdz 38. punktam, kas atšķiras ar to, ka kaitēkļi ir fitopatogēnie mikroorganismi.
  39. 40. Kompozīcija pēc 39. punkta, kas atšķiras ar to, ka mikroorganismi ir sēnītes.
  40. 41. Kompozīcija pēc jebkura no 35. līdz 38. punktam, kas atšķiras ar to, ka kaitēkļi ir kukaiņi vai ērces.
  41. 42. Savienojuma ar formulu (I) pēc 1. punkta pielietojums kaitēkļu apkarošanai.
  42. 43. Paņēmiens kaitēkļu apkarošanai vai to vairošanās profilaksei, kas paredz kaitēkļus vai to attīstības vidi apstrādāt ar savienojumu pēc 1. punkta.
  43. 44. Paņēmiens pēc 43. punkta, kas atšķiras ar to, ka tajā izmanto savienojumu pēc jebkura no 2. līdz 15. punktam. 18
  44. 45. Paņēmiens pēc 43. punkta, kas atšķiras ar to, ka tajā izmanto savienojumu pēc jebkura no 16. līdz 25. punktam.
  45. 46. Paņēmiens pēc 43. punkta, kas atšķiras ar to, ka tajā izmanto savienojumu pēc jebkura no 26. līdz 32. punktam.
  46. 47. Paņēmiens pēc jebkura no 43. fidz 46. punktam, kas atšķiras ar to, ka kaitēkļi ir fitopatogēnie mikroorganismi.
  47. 48. Paņēmiens pēc 47. punkta, kas atšķiras ar to, ka mikroorganismi ir sēnītes.
  48. 49. Paņēmiens pēc jebkura no 43. līdz 46. punktam, kas atšķiras ar to, ka kaitēkļi ir kukaiņi vai ērces.
  49. 50. . Paņēmiens pēc jebkura no 43. fīdz 46. punktam, kas atšķiras ar to, ka apstrādei pakļauj sēklu. 51. Sēkla, kas apstrādāta ar paņēmienu pēc 50. punkta.
  50. 52. Savienojums ar formulu (VII) O
    kurā A, X, Y un Rļ - R3 nozīmes atbilst formulai (I) 1. punkta minētajām. VII 19 ;U LV 11684
  51. 53. Savienojums ar formulu (VIII) o
    vin kurā A, Y un Ri - R3 nozīmes atbilst formulai (I) 1. punktā minētajām.
  52. 54. Savienojums ar formulu (IX) O
    kurā A, Y un Rļ - R3 nozīmes atbilst formulai (I) 1. punktā minētajām.
  53. 55. Savienojums pēc formulām 11.1 un II.2
    II. 2
LVP-96-314A 1994-01-05 1996-07-24 Pesticides LV11684B (en)

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EP0738260A1 (en) 1996-10-23
MD1315B1 (en) 1999-09-30
US5756426A (en) 1998-05-26
NO962823D0 (no) 1996-07-04
FI962712A7 (fi) 1996-08-16
CZ291625B6 (cs) 2003-04-16
EP0738260B1 (en) 2001-08-29
MD1315C2 (ro) 2000-06-30
HUT74980A (en) 1997-03-28
NO307045B1 (no) 2000-01-31
CN1152007C (zh) 2004-06-02
CA2179418C (en) 2004-06-22
CZ199096A3 (en) 1996-10-16
AP9600820A0 (en) 1996-07-31
NO962823L (no) 1996-07-04
FI962712A0 (fi) 1996-07-01
IL112227A (en) 1999-11-30
US6313166B1 (en) 2001-11-06
HU9601839D0 (en) 1996-10-28
EP0738260B2 (en) 2006-12-13
US5981585A (en) 1999-11-09
IL112227A0 (en) 1995-03-30
AU690190B2 (en) 1998-04-23
CN1141032A (zh) 1997-01-22
LV11684A (lv) 1997-02-20
MD960291A (en) 1997-10-31
CA2179418A1 (en) 1995-07-13
SK88096A3 (en) 1996-12-04
HU219157B (hu) 2001-02-28
AP654A (en) 1998-07-31
WO1995018789A1 (en) 1995-07-13
AU1385195A (en) 1995-08-01

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