KR980700386A - 분말도료용 수지 조성물(resin composition for powder coating) - Google Patents

분말도료용 수지 조성물(resin composition for powder coating) Download PDF

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KR980700386A
KR980700386A KR1019970703489A KR19970703489A KR980700386A KR 980700386 A KR980700386 A KR 980700386A KR 1019970703489 A KR1019970703489 A KR 1019970703489A KR 19970703489 A KR19970703489 A KR 19970703489A KR 980700386 A KR980700386 A KR 980700386A
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formula
group
powder coating
resin composition
component
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KR1019970703489A
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KR100385599B1 (ko
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사또루 미야께
히사오 이께다
모또히꼬 히다까
다께오 모로
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가시와끼 시로
닛산 가가꾸 고오교 가부시끼 가이샤
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03—Powdery paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/06—Triglycidylisocyanurates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/06—Triglycidylisocyanurates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C09D201/06—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing oxygen atoms
    • C09D201/08—Carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic

Abstract

하기의 성분 (A), (B) 및 (C) 를 함유하는, 분말 도료용 수지 조성물 : (A) 수평균 분자량이 1,000 내지 20,000, 산가가 5 내지 200 및 유리전이온도가 30 내지 120℃ 인 카르복실기 함유 수지;(B) 화학식 (1) 의 트리스(-메틸글리시딜)이소시아누레이트; 및 (C) 개환중합반응 억제제로서, 분자내에 화학식 (2) 의 결합을 갖는 아민 및 오늄염으로 구성된 군에서 선택한 1 종이상의 화합물.

Description

분말도료용 수지 조성물(RESIN COMPOSITION FOR POWDER COATING)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기의 성분 (A), (B) 및 (C) 를 함유하는, 분발 도료용 수지 조성물 : (A) 수평균 분자량이 1,000 내지 20,000, 산가가 5 내지 200 및 유리전이온도가 30 내지 120℃ 인 카르복실기 함유 수지;
    (B) 하기 화학식 (1) 의 트리스( β-메틸글리시딜)이소시아누레이트 :
    [화학식1]
    ; 및
    (C) 개환중합반응 억제제로서, 분자내에 하기 화학식 (2) 의 결합을 갖는 아민 및 오늄염으로 구성된 군에서 선택한 1 종이상의 화합물 :
    [화학식2]
  2. 제 1 항에 있어서, 성분(C)에 있어 분자내에 화학식 (2) 의 결합을 갖는 아민은 하기 화학식 (3) 의 구조를 갖는 고리형 아민인, 분말 도료용 수지 조성물:
    [화학식3]
    [식중, m 은 정수 2 내지 11 이고, n 은 정수 2 또는 3 이다].
  3. 제 1 또는 2 항에 있어서, 성분(C)에 있어 오늄염은, 하기 화학식 (4) 의 구조를 갖는 사차암모늄염:
    [화학식4]
    [식중, m 은 정수 2 내지 11 이고, n 은 정수 2 또는 3 이며, R1은 알킬기 또는 아릴기이고, Y 는 음이온이다]; 하기 화학식 (5) 의 구조를 갖는 사차암모늄염:
    [화학식5]
    R2R3R4R5N_Y_
    [식중, 각각의 R2,R3,R4및 R5는 알칼기 또는 아릴기이고, N 은 질소원자이며, Y 는 음이온이고, 단, R2,R3,R4및 R5는 각각 C-N 결합으로 질소원자에 결합된다]; 하기 화학식 (6) 의 구조를 갖는 사차암모늄염:
    [화학식6]
    [식중, 각각의 R6및 R7는 알킬기 또는 아릴기이고, Y 는 음이온이다]; 하기 화학식 (7) 의 구조를 갖는 사차암모늄염:
    [화학식7]
    [식중, R8은 알킬기 또는 아릴기이고, Y_는 음이온이다]; 하기 화학식 (8) 의 구조를 갖는 사차암모늄염;
    [화학식8]
    [식중, 각각의 R9및 R10은 알킬기 또는 아릴기이고, Y는 음이온이다];
    하기 화학식 (9) 의 구조를 갖는 삼차암모늄염:
    [화학식9]
    [식중, m 은 정수 2 내지 11 이고, n 은 정수 2 또는 3 이며, H 는 수소원자이고, Y 는 음이온이다];
    하기 화학식 (10) 의 구조를 갖는 사차포스포늄염 :
    [화학식10]
    R11R12R13R14P-Y-
    [식중, 각각의 R11,R12,R13및 R14는 알킬기 또는 아릴기이고, P 는 인 원자이며, Y-는 음이온이고, 단, R11,R12,R13및 R14는 각각 C-P 결합으로 인원자에 결합된다];
    하기 화학식 (11) 의 구조를 갖는 삼차술포늄염 :
    [화학식11]
    R15R16R17S-Y-
    [식중, 각각의 R15,R16및 R17은 알킬기 또는 아릴기이고, Y-는 음이온이며, 단, R15, R16및 R17은 각각 C-S 결합으로 황원자에 결합된다] 인, 분말 도료용 수지 조성물.
  4. 제 1 항에 있어서, 성분 (C) 는 청구항 3 에서 정의된 바와 같은 화학식 (4), (6), (7), (8), (9), (10) 및 (11) 의 화합물로 구성된 군에서 선택한 1 종이상의 오늄염인, 분말 도료용 수지 조성물.
  5. 제 1 내지 4 항중 어느 한 항에 있어서, (성분 B 내의-메틸글리시딜기)/(성분 A 내의 카르복실기) 의 당량비가 1.1 내지 2.5 의 범위내가 되는 비율 정도로 성분 (A) 및 (B) 가 함유된, 분말 도료용 수지 조성물.
  6. 제 1 내지 5 항중 어느 한 항에 있어서, 성분(C) 가 성분 (A) 의 100 중량부당 0.01 내지 10 중량부의 양으로 함유된, 분말 도료용 수지 조성물.
  7. 제 1 내지 6 항중 어느 한 항에 있어서, 성분(A)에 있어 카르복실기 함유 수지는 폴리에스테르 수지, 폴리아크릴산 수지 또는 이의 혼합물인, 분말 도료용 수지 조성물.
  8. 제 1 내지 6 항중 어느 한 항에 있어서, 성분(A)에 있어 카르복실기 함유 수지는 지방족 카르복실산에서 유래된 카르복실기를 갖는 폴리에스테르 수지인, 분말 도료용 수지 조성물.
  9. 제 1 내지 6 항중 어느 한 항에 있어서, 성분(A)에 있어 카르복실기 함유 수지는 4.0 이하의 pKa 값을 갖는 방향족 카르복실산에서 유래된 카르복실기를 갖는 폴리에스테르 수지인, 분말 도료용 수지 조성물.
KR1019970703489A 1994-11-28 1995-11-14 분말도료용수지조성물 KR100385599B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP94-292790 1994-11-28
JP29279094 1994-11-28
JP7628195 1995-03-31
JP95-76281 1995-03-31

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KR980700386A true KR980700386A (ko) 1998-03-30
KR100385599B1 KR100385599B1 (ko) 2005-02-24

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US (2) US6114473A (ko)
EP (1) EP0794984B1 (ko)
KR (1) KR100385599B1 (ko)
CN (1) CN1073603C (ko)
AU (1) AU701183B2 (ko)
DE (1) DE69529576T2 (ko)
DK (1) DK0794984T3 (ko)
TW (1) TW330944B (ko)
WO (1) WO1996017026A1 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11228867A (ja) * 1998-02-17 1999-08-24 Nissan Chem Ind Ltd 粉体塗料用樹脂組成物
KR100571313B1 (ko) * 1998-03-17 2006-04-17 후지 샤신 필름 가부시기가이샤 포지티브 감광성 조성물
US7858285B2 (en) * 2006-11-06 2010-12-28 Xerox Corporation Emulsion aggregation polyester toners
US20080197283A1 (en) * 2007-02-16 2008-08-21 Xerox Corporation Emulsion aggregation toner compositions and developers
JP5673963B2 (ja) * 2010-01-26 2015-02-18 日産化学工業株式会社 ポジ型レジスト組成物及びマイクロレンズの製造方法
US8580886B2 (en) 2011-09-20 2013-11-12 Dow Corning Corporation Method for the preparation and use of bis (alkoxysilylorgano)-dicarboxylates
WO2013081820A2 (en) 2011-12-02 2013-06-06 Dow Corning Corporation Ester-functional silanes and the preparation and use thereof;and use of iminium compounds as phase transfer catalysts

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH524654A (de) * 1968-08-07 1972-06-30 Ciba Geigy Ag Neue, heisshärtbare Mischungen aus Polyepoxidverbindungen, Ringe enthaltenden Polyestern und Polycarbonsäureanhydriden
CH515925A (de) * 1968-11-21 1971-11-30 Ciba Geigy Ag Verfahren zur Herstellung neuer B-Methylglycidyl-isocyanurate und ihre Verwendung zur Herstellung härtbarer Massen
US4147737A (en) * 1970-12-23 1979-04-03 Internationale Octrooi Maatschappij Octropa B.V. Powder coating composition employing mixture of polyepoxide resin with modified polyester resin
US3894016A (en) * 1971-01-15 1975-07-08 Ciba Geigy Corp Polyacrylates of isocyanurates
CH546800A (de) * 1971-07-09 1974-03-15 Ciba Geigy Ag Verfahren zum haerten von polyacrylaten mit ionisierenden strahlen.
GB1509043A (en) * 1975-04-29 1978-04-26 Ucb Sa Powdered epoxy resin and polyester coating compositions
JPS53111335A (en) * 1977-03-11 1978-09-28 Dainippon Ink & Chem Inc Powder coating resin composition
JPS56136856A (en) * 1980-03-31 1981-10-26 Dainippon Ink & Chem Inc Powder coating resin composition
DE3204333A1 (de) * 1982-02-09 1983-08-11 Bayer Ag, 5090 Leverkusen Reaktive carboxylgruppenhaltige polymere, verfahren zu ihrer herstellung und ihre verwendung als bindemittelkomponente fuer pulverlacke
NL8204205A (nl) * 1982-10-29 1984-05-16 Dsm Resins Bv Polyester en de toepassing daarvan in poederlak.
US4507441A (en) * 1983-05-16 1985-03-26 Scott Bader Company Limited Accelerators for the cure of epoxy resins
US5470893A (en) * 1990-06-01 1995-11-28 Courtaulds Coatings (Holdings) Limited Powder coating compositions
US4910287A (en) * 1989-01-06 1990-03-20 Ruco Polymer Corporation 1-methyl imidazole catalyzed carboxyl terminated polyester
KR950012768B1 (ko) * 1989-12-28 1995-10-21 고려화학주식회사 저온 경화형 폴리에스테르 수지의 제조방법 및 이를 함유하는 분체도료 조성물
JP2810500B2 (ja) * 1990-07-03 1998-10-15 日本ペイント株式会社 粉体塗料
US5097006A (en) * 1990-11-21 1992-03-17 U C B S.A. Weatherable powder coating compositions
US5244944A (en) * 1991-06-05 1993-09-14 Eastman Kodak Company Thermosetting powder coating compositions
US5369178A (en) * 1991-07-05 1994-11-29 Mitsui Toatsu Chemicals, Inc. Resin composition for thermosetting coating
AU2568492A (en) * 1991-08-27 1993-03-16 Dow Chemical Company, The Polyester compositions containing phosphonium compounds
GB9200330D0 (en) * 1992-01-08 1992-02-26 Ucb Sa Thermosetting compositions in powder form for the preparation of matt coatings
ATE159268T1 (de) * 1992-03-16 1997-11-15 Ucb Sa Cycloaliphatische polyester mit carboxylendgruppen zur darstellung von pulverlacken
US5728779A (en) * 1992-12-01 1998-03-17 Dsm N.V. Powder paint of epoxy-reactive polymer and aliphatic chain-containing polyepoxide
JP3211469B2 (ja) * 1993-04-09 2001-09-25 日本油脂ビーエーエスエフコーティングス株式会社 艶消粉体塗料組成物、塗装方法および塗膜

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CN1166853A (zh) 1997-12-03
EP0794984B1 (en) 2003-02-05
KR100385599B1 (ko) 2005-02-24
EP0794984A1 (en) 1997-09-17
CN1073603C (zh) 2001-10-24
DE69529576D1 (de) 2003-03-13
WO1996017026A1 (en) 1996-06-06
DK0794984T3 (da) 2003-02-24
AU701183B2 (en) 1999-01-21
US6303706B1 (en) 2001-10-16
AU3856695A (en) 1996-06-19
US6114473A (en) 2000-09-05
DE69529576T2 (de) 2003-08-14
TW330944B (en) 1998-05-01

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