KR970704659A - 올레핀의 카르보닐화 방법(Process for Carbonylating Olefins) - Google Patents

올레핀의 카르보닐화 방법(Process for Carbonylating Olefins) Download PDF

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Publication number
KR970704659A
KR970704659A KR1019970700192A KR19970700192A KR970704659A KR 970704659 A KR970704659 A KR 970704659A KR 1019970700192 A KR1019970700192 A KR 1019970700192A KR 19970700192 A KR19970700192 A KR 19970700192A KR 970704659 A KR970704659 A KR 970704659A
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South Korea
Prior art keywords
nickel
water
process according
propionic acid
carbonylating
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KR1019970700192A
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English (en)
Inventor
페르디난트 립페르트
아르투르 휜
마르틴 셰퍼
레오폴트 후퍼
Original Assignee
스타르크, 스타인호프
바스프 악티엔게젤샤프트
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Application filed by 스타르크, 스타인호프, 바스프 악티엔게젤샤프트 filed Critical 스타르크, 스타인호프
Publication of KR970704659A publication Critical patent/KR970704659A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/122—Propionic acid

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 물, 알코올 또는 카르복실산 및 할로겐이 없는 촉매의 존재하에 올레핀을 일산화탄소로 카르보닐화시키는 방법에 관한 것이다. 니켈 또는 니켈 화합물 및 크롬, 몰리브덴, 텅스텐, 레윰, 루테늄, 오스뮴, 로듐, 이리듐, 팔라듐, 백금, 은 및 금으로 구성된 군으로부터 선택된 하나 이상의 금속, 또는 상기 금속들의 조합을 촉매로서 사용한다.

Description

올레핀의 카르보닐화 방법(Process for Carbonylating Olefins)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 니켈 또는 니켈 화합물 및 크롬, 몰리브덴, 텅스텐, 레윰, 루테늄, 오스뮴, 로듐, 이리듐, 팔라듐, 백금, 은 및 금으로 구성된 군으로부터 선택된 하나 이상의 금속, 또는 상기 금속들의 혼합물로 이루어진 촉매를 사용하는 것으로 이루어지는, 물, 알코올 또는 카르복실산, 및 할로겐이 없는 촉매의 존재하에 올레핀을 일산화탄소로 카르보닐화시키는 방법.
  2. 제1항에 있어서, 사용하는 촉매가 니켈 및 루테늄, 또는 니켈 및 백금, 또는 이 금속들의 화합물인 방법.
  3. 제1항 또는 2항에 있어서, 카르보닐화를 170 내지 250℃의 온도 및 30 내지 150 바아의 압력에서 수행하는 방법.
  4. 제1항 내지 제 3항 중 어느 한 항에 있어서, 에틸렌을 물의 존재하에 카르보닐화시켜 프로피온산을 형성시키는 방법.
  5. 제4항에 있어서, 프로피온산의 합성을 물 함량이 10 내지 90중량%인 프로피온산으로 이루어지는 용매중에서 수행하는 것인 방법.
  6. 제1항 내지 제3항 중 어느 한 항에 있어서, 에틸렌을 물이 없는 프로피온산의 존재하에 반응시켜 프로피온산 무수물을 형성시키는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970700192A 1994-07-13 1995-07-03 올레핀의 카르보닐화 방법(Process for Carbonylating Olefins) KR970704659A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4424710.9 1994-07-13
DE4424710A DE4424710A1 (de) 1994-07-13 1994-07-13 Verfahren zur Carbonylierung von Olefinen
PCT/EP1995/002560 WO1996002487A1 (de) 1994-07-13 1995-07-03 Verfahren zur carbonylierung von olefinen

Publications (1)

Publication Number Publication Date
KR970704659A true KR970704659A (ko) 1997-09-06

Family

ID=6523044

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970700192A KR970704659A (ko) 1994-07-13 1995-07-03 올레핀의 카르보닐화 방법(Process for Carbonylating Olefins)

Country Status (8)

Country Link
US (1) US5705683A (ko)
EP (1) EP0770052B1 (ko)
JP (1) JPH10502650A (ko)
KR (1) KR970704659A (ko)
CN (1) CN1070168C (ko)
DE (2) DE4424710A1 (ko)
TW (1) TW287154B (ko)
WO (1) WO1996002487A1 (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19706876A1 (de) * 1997-02-21 1998-08-27 Basf Ag Verfahren zur Herstellung von Carbonsäuren oder deren Estern durch Carbonylierung von Olefinen
EP1414776A1 (en) * 2001-08-03 2004-05-06 Eastman Chemical Company Vapor phase carbonylation process using gold catalysts
EP1414777A1 (en) * 2001-08-03 2004-05-06 Eastman Chemical Company Vapor phase carbonylation process using iridium-gold co-catalysts
DE102004018284A1 (de) * 2004-04-15 2005-11-03 Wacker-Chemie Gmbh Verfahren zur Ethylen-Rückgewinnung in einem Kreisgasprozess zur Herstellung von Vinylacetat
US7582792B2 (en) * 2006-06-15 2009-09-01 Eastman Chemical Company Carbonylation process
US7629491B2 (en) * 2006-06-26 2009-12-08 Eastman Chemical Company Hydrocarboxylation process
US20090247783A1 (en) * 2008-04-01 2009-10-01 Eastman Chemical Company Carbonylation process
JP5626987B2 (ja) * 2010-12-28 2014-11-19 三菱瓦斯化学株式会社 新規脂環式アルコール
US9273020B2 (en) * 2012-05-02 2016-03-01 Haldor Topsoe A/S Process for the production of chemical compounds from carbon dioxide
DE102016218235A1 (de) * 2016-09-22 2018-03-22 Siemens Aktiengesellschaft Verfahren zur Herstellung von Propanol, Propionaldehyd und/oder Propionsäure aus Kohlendioxid, Wasser und elektrischer Energie
CN115724726A (zh) * 2021-08-26 2023-03-03 中国科学院大连化学物理研究所 一种由烯烃羰基化直接制备酮的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE868150C (de) * 1941-09-21 1953-02-23 Basf Ag Verfahren zur Herstellung von Carbonsaeuregemischen
DE863194C (de) * 1943-04-01 1953-01-15 Basf Ag Verfahren zur Herstellung von Carbonsaeuren und Carbonsaeureanhydriden
GB630279A (en) * 1947-02-19 1949-10-10 Du Pont Improvements in or relating to the synthesis of carboxylic acids
US2658075A (en) * 1951-04-27 1953-11-03 Basf Ag Process for preparing carboxylic acids and their anhydrides
US2768968A (en) * 1953-06-13 1956-10-30 Basf Ag Carbonylation of olefins with cobalt or nickel complex catalysts
GB1063617A (en) * 1964-06-11 1967-03-30 Dow Chemical Co Manufacture of organic acids
US3717670A (en) * 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
NL6917764A (ko) * 1969-11-25 1971-05-27
FR2491460A1 (fr) * 1980-10-03 1982-04-09 Rhone Poulenc Ind Procede de preparation d'esters par carbonylation de composes monoolefiniques
US4625055A (en) * 1982-09-30 1986-11-25 The Halcon Sd Group, Inc. Preparation of carboxylic acids
GB8803535D0 (en) * 1988-02-16 1988-03-16 Shell Int Research Process for preparation of carboxylic acids/esters thereof
EP0495547B1 (en) * 1991-01-15 1996-04-24 Shell Internationale Researchmaatschappij B.V. Carbonylation of olefins

Also Published As

Publication number Publication date
EP0770052A1 (de) 1997-05-02
DE4424710A1 (de) 1996-01-18
CN1155881A (zh) 1997-07-30
EP0770052B1 (de) 1999-03-31
WO1996002487A1 (de) 1996-02-01
CN1070168C (zh) 2001-08-29
JPH10502650A (ja) 1998-03-10
TW287154B (ko) 1996-10-01
DE59505524D1 (de) 1999-05-06
US5705683A (en) 1998-01-06

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