JPH10511094A - オレフィンのカルボニル化 - Google Patents
オレフィンのカルボニル化Info
- Publication number
- JPH10511094A JPH10511094A JP8519918A JP51991896A JPH10511094A JP H10511094 A JPH10511094 A JP H10511094A JP 8519918 A JP8519918 A JP 8519918A JP 51991896 A JP51991896 A JP 51991896A JP H10511094 A JPH10511094 A JP H10511094A
- Authority
- JP
- Japan
- Prior art keywords
- group
- iodide
- acid
- compound
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.脂肪族カルボン酸、脂肪族カルボン酸アルキルエステル及び脂肪族カルボ ン酸無水物から選ばれた脂肪族カルボニル化合物を製造するにあたり、一酸化炭 素と、オレフィン並びに (1)少なくとも一種の第6族金属から選ばれた第一成分並びに (2)(i)塩素、臭素又は沃素の化合物から選ばれたハロゲン化物 (ii)アルカリ金属化合物、 (iii)第15族元素の第四級有機化合物の塩、 (iv)第15族元素のトリ置換有機化合物及び (v)トリ置換ホスフィン化合物の酸化物 の少なくとも一種の化合物から選ばれた第二成分 を含んでなる触媒系の混合物とを、(1)第8族、第9族及び第10族金属並びに (2)ギ酸及びギ酸エステルの実質的に不存在下に、カルボニル化温度及び圧力 条件下に、接触させることを含んでなる脂肪族カルボニル化合物の製造方法。 2.オレフィンが2〜20個の炭素を含み、カルボニル化温度及び圧力条件が温 度75〜350℃及び圧力8〜346バール(絶対)である請求の範囲第1項に記載の方 法。 3.触媒系が(A)少なくとも一つの第6族金属、(B)少なくとも一つの沃 素化合物及び(C)アルカリ金属塩、第四級ホスホニウム化合物塩、トリ置換ホ スフィン又はトリ置換ホスフィン酸化物から選ばれた少なくとも一つの成分を含 んでなり、そしてオレフィンが2〜8個の炭素を含む請求の範囲第2項に記載の 方法。 4.混合物が更に有機溶媒を含み、触媒系が(A)少なくとも一つの第6族金 属、(B)少なくとも一つの沃素化合物並びに(C) アルカリ金属塩、第四級ホスホニウム化合物の塩、トリ置換ホスフィン又はトリ 置換ホスフィン酸化物及び炭素数2〜8のオレフィンから選ばれた少なくとも一 つの成分を含んでなり、そしてプロセスを圧力18〜104バール(絶対)及び温度1 50〜250℃で実施する請求の範囲第1項に記載の方法。 5.溶媒が脂肪族カルボン酸であり、触媒系が(A)モリブテン、(B)沃化 水素、沃化アルキルもしくはその混合物及び(C)アルカリ金属の沃化物塩、第 四級ホスホニウム化合物の沃化物塩、トリ置換ホスフィン又はトリ置換ホスフィ ン酸化物を含んでなり、そしてオレフィンが2〜4個の炭素を含む請求の範囲第 4項に記載の方法。 6.カルボニルがプロピオン酸であり、混合物がエチレン及び水を含み、そし て触媒系が(A)モリブテン、(B)沃化水素、アルキル沃素もしくはその混合 物であり及び(C)アルカリ金属の沃化物塩、第四級ホスホニウム化合物の沃化 物塩、トリ置換ホスフィン又はトリ置換ホスフィン酸化物を含んでなり、プロセ スを圧力18〜104バール(絶対)及び温度150〜250℃で実施する請求の範囲第1 項に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US35917894A | 1994-12-19 | 1994-12-19 | |
US08/359,178 | 1994-12-19 | ||
US08/509,039 US5936117A (en) | 1994-12-08 | 1995-07-28 | Carbonylation of olefins |
US08/509,039 | 1995-07-28 | ||
PCT/US1995/016438 WO1996019427A1 (en) | 1994-12-19 | 1995-12-15 | Carbonylation of olefins |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH10511094A true JPH10511094A (ja) | 1998-10-27 |
JP3792715B2 JP3792715B2 (ja) | 2006-07-05 |
Family
ID=27000372
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP51991896A Expired - Fee Related JP3792715B2 (ja) | 1994-12-19 | 1995-12-15 | オレフィンのカルボニル化 |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0799173B1 (ja) |
JP (1) | JP3792715B2 (ja) |
CN (1) | CN1073064C (ja) |
CA (1) | CA2208002A1 (ja) |
DE (1) | DE69508794T2 (ja) |
MX (1) | MX9704535A (ja) |
TW (1) | TW349088B (ja) |
WO (1) | WO1996019427A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2021143130A (ja) * | 2020-03-10 | 2021-09-24 | 株式会社トクヤマ | プロピオン酸金属塩水溶液 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0973610A1 (en) * | 1997-04-10 | 2000-01-26 | Eastman Chemical Company | Process and catalyst for carbonylating olefins |
JP5422229B2 (ja) * | 2008-08-25 | 2014-02-19 | 花王株式会社 | オレフィンの製造法 |
EP3502081B1 (de) * | 2017-12-21 | 2020-07-01 | Evonik Operations GmbH | Verfahren zur pd-katalysierten hydroxycarbonylierung von diisobuten: verhältnis 3,5,5-trimethylhexansäure/h2o |
EP3502082B1 (de) * | 2017-12-21 | 2020-02-12 | Evonik Operations GmbH | Verfahren zur pd-katalysierten hydroxycarbonylierung von diisobuten: einfluss des lösungsmittels |
ES2787299T3 (es) * | 2017-12-21 | 2020-10-15 | Evonik Degussa Gmbh | Proceso para la conversión directa de alquenos en ácidos carboxílicos |
CN111111774A (zh) * | 2018-11-01 | 2020-05-08 | 中国科学院大连化学物理研究所 | 有机含膦聚合物载体负载铑和杂多酸催化剂及制备和应用 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US435036A (en) * | 1890-08-26 | Method of and means for bending electrotype-plates | ||
US4354036A (en) * | 1980-12-24 | 1982-10-12 | The Halcon Sd Group, Inc. | Preparation of carboxylic acid esters |
GB8328905D0 (en) * | 1983-10-28 | 1983-11-30 | Bp Chem Int Ltd | Carboxylic acid and esters |
-
1995
- 1995-11-20 TW TW084112312A patent/TW349088B/zh active
- 1995-12-15 DE DE69508794T patent/DE69508794T2/de not_active Expired - Lifetime
- 1995-12-15 JP JP51991896A patent/JP3792715B2/ja not_active Expired - Fee Related
- 1995-12-15 CA CA 2208002 patent/CA2208002A1/en not_active Abandoned
- 1995-12-15 MX MX9704535A patent/MX9704535A/es not_active IP Right Cessation
- 1995-12-15 WO PCT/US1995/016438 patent/WO1996019427A1/en not_active Application Discontinuation
- 1995-12-15 CN CN95197581A patent/CN1073064C/zh not_active Expired - Fee Related
- 1995-12-15 EP EP95943851A patent/EP0799173B1/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2021143130A (ja) * | 2020-03-10 | 2021-09-24 | 株式会社トクヤマ | プロピオン酸金属塩水溶液 |
Also Published As
Publication number | Publication date |
---|---|
EP0799173B1 (en) | 1999-03-31 |
MX9704535A (es) | 1997-12-31 |
TW349088B (en) | 1999-01-01 |
EP0799173A1 (en) | 1997-10-08 |
WO1996019427A1 (en) | 1996-06-27 |
DE69508794D1 (de) | 1999-05-06 |
CA2208002A1 (en) | 1996-06-27 |
CN1175241A (zh) | 1998-03-04 |
DE69508794T2 (de) | 1999-08-19 |
JP3792715B2 (ja) | 2006-07-05 |
CN1073064C (zh) | 2001-10-17 |
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