KR960700234A - 촉매산화방법(Catalytic Oxidation Process) - Google Patents

촉매산화방법(Catalytic Oxidation Process)

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Publication number
KR960700234A
KR960700234A KR1019950702658A KR19950702658A KR960700234A KR 960700234 A KR960700234 A KR 960700234A KR 1019950702658 A KR1019950702658 A KR 1019950702658A KR 19950702658 A KR19950702658 A KR 19950702658A KR 960700234 A KR960700234 A KR 960700234A
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South Korea
Prior art keywords
catalytic oxidation
oxidized
acid
oxidation method
thiols
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KR1019950702658A
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English (en)
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KR0160588B1 (ko
Inventor
데니스 오스카 코메인
에릭 진 미어버겐
데니스 패트릭 라일리
데이빗 존 사이코라
길버트 프랑소와 조제프 스트렉스
메리 제니퍼 토리스 영
Original Assignee
제임스 클리프튼 보올딩
몬산토 캄파니
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Publication of KR960700234A publication Critical patent/KR960700234A/ko
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Publication of KR0160588B1 publication Critical patent/KR0160588B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/38—One sulfur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/22—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
    • C07C319/24—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/14—Dithiocarbamic acids; Derivatives thereof
    • C07C333/30—Dithiocarbamic acids; Derivatives thereof having sulfur atoms of dithiocarbamic groups bound to other sulfur atoms
    • C07C333/32—Thiuramsulfides; Thiurampolysulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62—Benzothiazoles
    • C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C07D277/70—Sulfur atoms
    • C07D277/76—Sulfur atoms attached to a second hetero atom
    • C07D277/78—Sulfur atoms attached to a second hetero atom to a second sulphur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62—Benzothiazoles
    • C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C07D277/70—Sulfur atoms
    • C07D277/76—Sulfur atoms attached to a second hetero atom
    • C07D277/80—Sulfur atoms attached to a second hetero atom to a nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/14—All rings being cycloaliphatic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

선택적으로 1차 혹은 2차아민의 존재하에서, 포르피라진 혹은 포르피라진 유도체의 금속착물을 포함하지 않는 탄소촉매와 함께 산소를 이용하여, 티올 혹은 티올의 염 혹은 디티오카르빔산 혹은 그의 염에 대한 촉매산하를 실행하였다.

Description

촉매산화방법(Catalytic Oxidation Process)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 촉매가 탄소이고 포르피라진 혹은 포르피라진 유도체의 금속착물을 함유하지 않으며, 선택적으로 1차 혹은 2차아민의 존재하에서, 산소와 티올 혹은 티올의 염 혹은 디티오카르빔산 혹은 그의 염의 촉매산화방법.
  2. 제1항에 있어서, 산화되는 물질은, (A)질소-포함 헤테로고리의 티올, (B)지방족 및 방향족 탄화수소티올, 및 (C)디알킬-디티오카르빔산 및 그들의 염으로 부터 선택되는 것을 특징으로 하는 촉매 산화방법.
  3. 제2항에 있어서, 산화되는 물질은 2-머캅토벤조티아졸, 2-피리딘티올, 2-피리딘티올, 4-피리미딘티올, 2-피라진티올, 3-피라진티올, 2-머캅토벤즈이미다졸, 2-퀴놀린티올 및 2-레피딘티올로부터 선택되는 것을 특징으로 하는 촉매산화방법.
  4. 제3항에 있어서, 아민이 존재하고 이 아민은 t-부틸아민, 시클로헥실아민, 이소프로필아민, 모로플린 및 디이소프로필아민으로부터 선택된 것을 특징으로 하는 촉매산화방법.
  5. 제4항에 있어서, 황이 존재하는 것을 특징으로 하는 촉매산화방법.
  6. 제2항에 있어서, 산화되는 물질은 에틸머캅탄, 1-프로필머캅탄, 이소프로필머캅탄, t-부틸머캅탄, n-부틸-1-머캅탄, 시클로헥실머캅탄 및 페닐머캅탄으로부터 선택되는 것을 특징으로 하는 촉매산화방법.
  7. 제2항에 있어서, 산화되는 물질은 디메틸디티오카르빔산 및 그의 금속 혹은 암모늄염, 디에틸디티오카르빔산 및 그의 금속 혹은 암모늄염, 및 디부틸디티오카르빔산 및 그의 금속 혹은 암모늄염으로부터 선택되는 것을 특징으로 하는 촉매산화방법.
  8. 제1항에 디티오카르빈산이 아민존재하에서 산화되는 것을 특징으로 하는 촉매산화방법.
  9. 제1항에 있어서, 디티오카르빔산이 황 존재하에서 산화되는 것을 특징으로 하는 촉매산화방법.
  10. 제1항에 있어서, 탄소촉매는 활성탄인 것을 특징으로 하는 촉매산화방법.
  11. 제10항에 있어서, 활성탄은 그것의 표면으로부터 산화물을 제거하기 위해 처리된 것을 특징으로 하는 촉매산화방법.
  12. 제1항에 있어서, 산화는 양자성 혹은 비양자성 용매를 함유하는 액체반응매개체내에서 실행되는 것을 특징으로 하는 촉매산화방법.
  13. 제4항에 있어서, 산화는 과도한 아민을 함유하는 반응매개체내에서 실행되는 것을 특징으로 하는 촉매산화방법.
  14. 제1항에 있어서, 산소는 불활성기체와 혼합된 것을 특징으로 하는 촉매산화방법.
  15. 제1항에 있어서, 산소는 0.1 내지 1.0MPa 사이의 게이지압력에서 공급되는 것을 특징으로 하는 촉매산화방법.
  16. 제1항에 있어서, 0℃ 내지 150℃사이의 온도범위에서 반응시키는 것을 특징으로 하는 촉매산화방법.
  17. 제16항에 있어서, 30℃ 내지 90℃사이의 온도범위에서 반응시키는 것을 특징으로 하는 촉매산화방법.
  18. 제1항에 있어서, 탄소는 티올 혹은 그의 염, 혹은 디티오카르빔산 혹은 그의 염의 중량을 기준으로, 1~75중량%로 존재하는 것을 특징으로 하는 촉매산화방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950702658A 1992-12-30 1993-12-03 촉매산화방법 KR0160588B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US99871392A 1992-12-30 1992-12-30
US998,713 1992-12-30
US7/998713 1992-12-30
PCT/US1993/011740 WO1994015927A1 (en) 1992-12-30 1993-12-03 Catalytic oxidation process

Publications (2)

Publication Number Publication Date
KR960700234A true KR960700234A (ko) 1996-01-19
KR0160588B1 KR0160588B1 (ko) 1998-12-01

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EP (1) EP0677045B1 (ko)
JP (1) JPH08505618A (ko)
KR (1) KR0160588B1 (ko)
CN (1) CN1041924C (ko)
AT (1) ATE176667T1 (ko)
AU (1) AU674558B2 (ko)
BR (1) BR9307799A (ko)
CA (1) CA2150388A1 (ko)
CZ (1) CZ154995A3 (ko)
DE (1) DE69323500T2 (ko)
ES (1) ES2128548T3 (ko)
GE (1) GEP19991598B (ko)
HU (1) HUT72002A (ko)
MX (1) MX9400063A (ko)
RU (1) RU2104275C1 (ko)
SK (1) SK84595A3 (ko)
WO (1) WO1994015927A1 (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69307140T2 (de) * 1992-06-05 1997-06-05 Monsanto Co 4-pyrimidin sulfenamide und ihre verwendung in kautschuk
CN101139338B (zh) * 2007-07-09 2013-10-23 青岛科技大学 基于2-硫醇苯并噻唑铵盐的氧气法制备2,2＇-二硫代二苯并噻唑
CN103554055B (zh) * 2013-10-29 2015-06-17 西南化工研究设计院有限公司 一种n-氧二乙撑-2-苯并噻唑次磺酰胺的绿色制备工艺
CN107638877B (zh) * 2017-09-28 2020-07-14 晋城天成化工有限公司 二硫化四甲基秋兰姆的合成方法
CN108101864B (zh) * 2017-12-20 2021-08-10 蔚林新材料科技股份有限公司 N-叔丁基-2-苯并噻唑次磺酰胺的制备方法
CN116102520B (zh) * 2022-12-19 2024-06-07 山东尚舜化工有限公司 一种氧气氧化法合成促进剂mbts（dm）的方法
CN115999495B (zh) * 2023-03-24 2023-06-27 东营巨宝工贸有限公司 一种应用于氧气氧化法生产硫化促进剂的反应釜

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3654297A (en) * 1969-02-10 1972-04-04 American Cyanamid Co Process for oxidizing 2-mercaptobenzothiazole
US4182873A (en) * 1972-10-04 1980-01-08 Rhone-Poulenc S.A. Process for the preparation of thiazolesulphenamides
DE2944225A1 (de) * 1979-11-02 1981-05-07 Akzo Gmbh, 5600 Wuppertal Verfahren zur herstellung von dithiazoldisulfiden
ES496923A0 (es) * 1979-11-23 1981-11-16 Monsanto Europe Sa Un proceso para la produccion de sulfenamidas
DE3205555A1 (de) * 1982-02-17 1983-08-25 Akzo Gmbh, 5600 Wuppertal Verfahren zur herstellung von dithiazoldisulfiden
DE3325724A1 (de) * 1983-07-16 1985-01-24 Akzo Gmbh, 5600 Wuppertal Verfahren zur herstellung von thiazolyl-2-sulfenamiden

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Publication number Publication date
WO1994015927A1 (en) 1994-07-21
CZ154995A3 (en) 1995-12-13
EP0677045B1 (en) 1999-02-10
JPH08505618A (ja) 1996-06-18
DE69323500D1 (de) 1999-03-25
MX9400063A (es) 1994-07-29
CN1041924C (zh) 1999-02-03
DE69323500T2 (de) 1999-09-16
BR9307799A (pt) 1995-11-14
HU9501952D0 (en) 1995-09-28
AU674558B2 (en) 1997-01-02
AU5737994A (en) 1994-08-15
EP0677045A1 (en) 1995-10-18
KR0160588B1 (ko) 1998-12-01
ES2128548T3 (es) 1999-05-16
HUT72002A (en) 1996-03-28
ATE176667T1 (de) 1999-02-15
CA2150388A1 (en) 1994-07-21
CN1096024A (zh) 1994-12-07
SK84595A3 (en) 1995-12-06
GEP19991598B (en) 1999-04-29
RU2104275C1 (ru) 1998-02-10
RU95113603A (ru) 1997-06-10

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