KR960010073A - 수소처리촉매, 그의 용도 및 그의 제조방법 - Google Patents

수소처리촉매, 그의 용도 및 그의 제조방법 Download PDF

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KR960010073A
KR960010073A KR1019950031270A KR19950031270A KR960010073A KR 960010073 A KR960010073 A KR 960010073A KR 1019950031270 A KR1019950031270 A KR 1019950031270A KR 19950031270 A KR19950031270 A KR 19950031270A KR 960010073 A KR960010073 A KR 960010073A
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alumina
metal
catalyst composition
diameter
weight
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KR1019950031270A
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KR100356431B1 (ko
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가츠히사 후지타
데츠로 가모
마사후미 시모와케
요시마사 이노우에
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피이터 코르넬리스 샬크비즈크
니폰 케첸 캄퍼니 리미티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

본 발명은 수소처리 촉매, 그의 용도 및 그의 제조방법에 관한 것으로서, 보다 구체적으로는 황- 및 금속- 함유 공급원료의 수소탈황 및 수소 탈금속을 동시에 실행하기에 적합한 촉매에 관한 것이며, a. 적어도 90중량%가 알루미나로 구성되고, 상기 알루미나는 R값이 2Θ=32°에서 X-선 희절 피이크의 직접 강도 및 2Θ=46°에서 X-선 희절 피이크의 집적 강도 사이의 비로서 정의되는 0.08-30의 R값을 가지는 알루미나로 구성된 지지체로 이루어지고, b. 금속으로 산정될 적에 VIB족 금속 성분 2-8중량%로 구성되며, c. 금속으로 산정될 적에 Ⅷ족 금속 성분 0.5-2.5중량%로 구성되고, d. (ⅰ) 총 기공 부피가 0.5-1.0㎖/g, (ⅱ) 평균 기공 직경이 18-30nm, (ⅲ) 60nm 이하의 직경을 가진 기공의 기공 부피의 적어도 40%가 평균 기공 직경 ±5nm의 범위내에 존재하는 것을 만족시키는 질소 흡착에 의해 측정되는 바와 같은 가공 크기 분포를 가지는 것을 특징으로 한다.

Description

수소처리촉매, 그의 용도 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. a. 적어도 90중량%가 알루미나로 구성되고, 상기 알루미나는 R값이 2Θ=32°에서 X-선 희절 피이크의 직접 강도 및 2Θ=46°에서 X-선 희절 피이크의 집적 강도 사이의 비로서 정의되는 0.08-30의 R값을 가지는 알루미나로 구성된 지지체로 이루어지고, b. 금속으로 산정될 적에 VIB족 금속 성분 2-8중량%로 구성되며, c. 금속으로 산정될 적에 Ⅷ족 금속 성분 0.5-2.5중량%로 구성되고, d. (ⅰ) 총 기공 부피가 0.5-1.0㎖/g, (ⅱ) 평균 기공 직경이 18-30nm, (ⅲ) 60nm 이하의 직경을 가진 기공의 기공 부피의 적어도 40%가 평균 기공 직경 ±5nm의 범위내에 존재하는 것을 만족시키는 질소 흡착에 의해 측정되는 바와 같은 가공 크기 분포를 가지는 것을 특징으로 하는 촉매 조성물
  2. 제1항에 있어서, 기공 크기 분포가 (ⅳ) 50nm 이하의 직경을 가진 기공의 기공 부피 10-20%가 35-50nm의 직경을 가진 기공내 존재하는 부가적인 요구사항을 만족시키는 것을 특징으로 하는 촉매 조성물
  3. 제1항 또는 제2항에 있어서, VIB족 금속 성분이 몰리브듐이고 Ⅷ족 금속 성분이 니켈인 것을 특징으로 하는 촉매 조성물
  4. 공급원료를 상승된 온도 및 압력에서 제1항 내지 제4항 중 어느 한 항에 따른 촉매와 접촉시키는 것을 특징으로 하는 금속 및 황을 함유하는 수소탈황 및 수소탈금속반응을 동시에 실행하는 금속
  5. 제1항 내지 제4항 중 어느 한 항에 따른 촉매 조성물을 제조하는 방법에 있어서, 알루미나 선구체가 제조되고, 상기 알루미나 선구체를 성형하여 지지체 입자를 형성하며, 성형된 지지체 입자를 소성 후 알루미나가 0.08-0.30의 범위내 R값을 갖는 방법으로 실행되는 소성 단계에 주입되며, 소성된 지지체 입자들은 촉매 조성물로 함입되는 금속 성분의 선구체와 접촉되게 하며 금속-함유 지지체 입자들은 건조되고 소성되어 적어도 일부의 금속 성분 선구체를 그의 산화물 형으로 전환시키는 것을 특징으로 하는 촉매 조성물을 제조하는 방법
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950031270A 1994-09-19 1995-09-19 수소처리촉매,그용도및제조방법 KR100356431B1 (ko)

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JP94-248288 1994-09-19
JP24828894A JP3504984B2 (ja) 1994-09-19 1994-09-19 重質炭化水素油の水素化脱硫脱金属触媒
JPDOJ4797 1994-09-19

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EP (1) EP0704239B1 (ko)
JP (1) JP3504984B2 (ko)
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CA (1) CA2158594C (ko)
DE (1) DE69508022D1 (ko)
MY (1) MY112928A (ko)
SG (1) SG34272A1 (ko)
TW (1) TW364861B (ko)
ZA (1) ZA957855B (ko)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11319584A (ja) 1998-05-11 1999-11-24 Nippon Kecchen Kk 粒状触媒用担体の製造方法および該担体を用いた触媒の製造方法
JP4266406B2 (ja) * 1998-05-11 2009-05-20 日本ケッチェン株式会社 粒状触媒用担体及びこの担体を用いた触媒及び該触媒による炭化水素油の水素化処理方法
JP4773634B2 (ja) * 2001-06-08 2011-09-14 日本ケッチェン株式会社 重質炭化水素油の２段階水素化処理方法
JP4773633B2 (ja) * 2001-06-08 2011-09-14 日本ケッチェン株式会社 重質炭化水素油の２段階水素化処理方法
JP4612229B2 (ja) * 2001-06-08 2011-01-12 日本ケッチェン株式会社 重質炭化水素油の水素化処理用触媒並びに水素化処理方法
FR2839902B1 (fr) 2002-05-24 2007-06-29 Inst Francais Du Petrole Catalyseur d'hydroraffinage et/ou d'hydroconversion et son utilisation dans des procedes d'hydrotraitement de charges hydrocarbonees
EP1561572A4 (en) * 2002-11-14 2007-04-18 Hosokawa Yoko Kk MULTILAYER PACKAGING AND PACKAGING MATERIAL FOR FOOD AND MEDICINAL PRODUCTS AND TOOLS FOR FOOD, MEDICINAL PRODUCTS AND TOOLS
AU2003201827A1 (en) * 2003-01-06 2004-08-10 Uop Llc Attrition resistant catalyst for hydrocarbon conversion
US7816299B2 (en) * 2003-11-10 2010-10-19 Exxonmobil Research And Engineering Company Hydrotreating catalyst system suitable for use in hydrotreating hydrocarbonaceous feedstreams
US7597795B2 (en) * 2003-11-10 2009-10-06 Exxonmobil Research And Engineering Company Process for making lube oil basestocks
US20050109679A1 (en) * 2003-11-10 2005-05-26 Schleicher Gary P. Process for making lube oil basestocks
US20100098602A1 (en) 2003-12-19 2010-04-22 Opinder Kishan Bhan Systems, methods, and catalysts for producing a crude product
NL1027772C2 (nl) * 2003-12-19 2006-08-29 Shell Int Research Systemen, methoden en katalysatoren voor het produceren van een ruwe-oliehoudend product.
US7745369B2 (en) 2003-12-19 2010-06-29 Shell Oil Company Method and catalyst for producing a crude product with minimal hydrogen uptake
CN100549136C (zh) * 2003-12-19 2009-10-14 国际壳牌研究有限公司 生产原油产品的系统,方法和催化剂
US8025791B2 (en) 2003-12-19 2011-09-27 Shell Oil Company Systems and methods of producing a crude product
US7591941B2 (en) * 2003-12-19 2009-09-22 Shell Oil Company Systems, methods, and catalysts for producing a crude product
US20060060510A1 (en) * 2004-09-17 2006-03-23 Bhan Opinder K High activity hydrodesulfurization catalyst, a method of making a high activity hydrodesulfurization catalyst, and a process for manufacturing an ultra-low sulfur distillate product
CN101166808B (zh) 2005-04-11 2013-03-27 国际壳牌研究有限公司 生产具有降低mcr含量的原油产品的方法和催化剂
JP2008536000A (ja) 2005-04-11 2008-09-04 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 窒素含有量の少ない原油生成物の製造方法及び触媒
TW200700152A (en) * 2005-04-21 2007-01-01 Shell Int Research Hydrogenation catalyst and hydrogenation method
KR20080112373A (ko) * 2006-04-13 2008-12-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 알데하이드의 수소화 방법
US8110527B2 (en) 2006-08-11 2012-02-07 China Petroleum & Chemical Corporation Alumina having a complex pore structure, and catalyst and process for selective hydrogenation of cracking gasoline
US20080083650A1 (en) 2006-10-06 2008-04-10 Bhan Opinder K Methods for producing a crude product
WO2008122029A1 (en) * 2007-04-02 2008-10-09 Inventure Chemical, Inc. Simultaneous esterification and alcohol ysis/hydrolysis of oil-containing materials with cellulosic and peptidic content
US7943792B2 (en) * 2007-04-02 2011-05-17 Inventure Chemical Inc. Production of biodiesel, cellulosic sugars, and peptides from the simultaneous esterification and alcoholysis/hydrolysis of materials with oil-containing substituents including phospholipids and peptidic content
JP5684107B2 (ja) * 2008-04-10 2015-03-11 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒系および原油供給物をこのような触媒系で変換するための方法
US7777085B2 (en) * 2008-10-01 2010-08-17 Inventure Chemical, Inc. Method for conversion of oil-containing algae to 1,3-propanediol
TWI579043B (zh) 2012-02-17 2017-04-21 先進精鍊科技有限公司 球形觸媒支撐物及其製備方法
TWI611836B (zh) 2012-02-17 2018-01-21 Advanced Refining Technologies Llc. 觸媒支撐物及其製備方法
TWI632235B (zh) 2012-06-20 2018-08-11 美商先進精鍊科技有限公司 用於殘渣油徑原料之加氫脫硫反應的觸媒及其製備方法
TWI666310B (zh) * 2013-03-15 2019-07-21 Advanced Refining Technologies Llc 觸媒組成物、加氫處理重烴類部分之方法及製備沉澱氧化鋁組成物的方法
RU2605939C2 (ru) * 2015-05-22 2016-12-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Носитель катализатора гидрооблагораживания вакуумного газойля и способ его приготовления (варианты)
FR3075072B1 (fr) * 2017-12-14 2021-11-26 Ifp Energies Now Catalyseur d'hydrodesulfuration selective des essences de fcc

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3931052A (en) 1973-08-29 1976-01-06 Mobil Oil Corporation Alumina-supported catalyst for residua demetalation and desulfurization
US4271042A (en) * 1977-12-20 1981-06-02 Mobil Oil Corporation Process for demetalation and desulfurization of petroleum oils
US4588709A (en) 1983-12-19 1986-05-13 Intevep, S.A. Catalyst for removing sulfur and metal contaminants from heavy crudes and residues
US5223472A (en) * 1992-04-14 1993-06-29 Union Oil Company Of California Demetallation catalyst
US5358633A (en) * 1993-05-28 1994-10-25 Texaco Inc. Hydrodesulfurization of cracked naphtha with low levels of olefin saturation

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Publication number Publication date
JPH0889805A (ja) 1996-04-09
EP0704239A2 (en) 1996-04-03
KR100356431B1 (ko) 2003-02-07
SG34272A1 (en) 1996-12-06
CA2158594C (en) 2005-05-24
EP0704239B1 (en) 1999-03-03
CA2158594A1 (en) 1996-03-20
JP3504984B2 (ja) 2004-03-08
US5888380A (en) 1999-03-30
ZA957855B (en) 1996-05-06
EP0704239A3 (ko) 1996-05-01
TW364861B (en) 1999-07-21
DE69508022D1 (de) 1999-04-08
MY112928A (en) 2001-10-31

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