KR960007740A - 금속 황화물 촉매가 지지된 신규한 "인으로 처리된 탄소"를 이용한 탄화수소 오일의 수소화 탈방향족 방법 - Google Patents

금속 황화물 촉매가 지지된 신규한 "인으로 처리된 탄소"를 이용한 탄화수소 오일의 수소화 탈방향족 방법 Download PDF

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KR960007740A
KR960007740A KR1019950024379A KR19950024379A KR960007740A KR 960007740 A KR960007740 A KR 960007740A KR 1019950024379 A KR1019950024379 A KR 1019950024379A KR 19950024379 A KR19950024379 A KR 19950024379A KR 960007740 A KR960007740 A KR 960007740A
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phosphorus
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metal
hydrogenation
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수다카르 차카
쥬니어 프랭크 돌핑거
라파엘 씨저 맥스
조마바이 파텔 마헨드라
오토 프리츠 폴
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알. 에프. 윌슨
텍사코 디벨롭프먼트 코퍼레이션
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Publication of KR960007740A publication Critical patent/KR960007740A/ko

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/48—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/50—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metal, or compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

본 발명은, 고체상 매직 각 방사 31p 핵 자기 공명 스펙트럼에서 -5 내지 -30ppm 사이의 피크에 의해 특징지워지는 폴리포스페이트 종으로서 주로 탄소 표면에 결합하는 인으로 이루어진 신규한 "인 처리된 탄소" 지지체 상에 1이상의 8족 금속, 텅스텐과 몰리브덴에서 선택된 1이상의 금속으로 이루어진 황화된 금속 촉매층을 유지하고; 수소 존재하에 충전된 탄화수소 공급물을 수소화처리 조건에서 상기 촉매와 접촉시켜 수소화 탈방향족반응과, 수소화 탈황반응 및 수소화 탈질소반응을 동시에 일으키는 것으로 이루어진, 바람직하지 않은 방향족 성분, 황 및 질소 화합물을 함유하는 충전된 탄화수소 오일의 수소화 탈방향족, 수소화 탈황 및 수소화 탈질소 방법에 관한 것이다.

Description

금속 황화물 촉매가 지지된 신규한 "인으로 처리된 탄소"를 이용한 탄화수소 오일의 수소화 탈방향족 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. "인 처리된 탄소"지지체 상에, 최종 촉매 중량에 대하여 철, 코발트 및 니켈에서 선택된 1이상의 8족 금속 0.1 내지 15중량%, 텅스텐 1 내지 50중량, 몰리브덴 및 크롬 1 내지 20중량%로부터 선택된 1이상의 6B족 금속으로 이루어진 황화된 금속 촉매의 층을 유지하되, 상기에서 "인 처리된 탄소"지지체는, (1)450℃ 이상의 온도에서 활성 탄소와 인 화합물의 혼합물을 열 처리하여 제조되고, (2)"인 처리된 탄소"내에 존재하는 인은 고체상 매직 각 방사 31p핵 자기공명 스펙트럼에서 -5 내지 -30ppm 사이의 피크로 특징지워지는 폴리포스페이트 조으로서 주로 탄소 표면에 결합하고, (3)100 내지 2,000㎡/g의 B.E.T 표면적과 0.3㎖/g 이상의 질소에 대한 전체 기공 부피 및 12 내지 100Å의 평균 기공 직경을 가지는 것을 특징으로 하며, 온도 200 내지 450℃, 입력 14 내지 207MPa, 시간당 액체 공간속도 0.1 내지 10LHSV 및 수소 공급 속도 36 내지 1,800㎡/㎡의 수소화 처리 조건하에서 순수한 수소와 60부피% 이상의 순수 수소를 함유하는 기체 혼합물에서 선택된 기체의 존재하에 충전된 탄화수소 공급물을 상기 촉매와 접촉하도록 통과시켜 바람직하지 않은 방향족 성분, 황 및 질소 화합물을 함유하는 상기한 충전된 탄화수소 공급물의 수소화 탈방향족반응, 수소화 탈황반응 및 수소화 탈질소반응을 일으켜서 바람직하지 않은 방향족 성분, 황 및 질소 화합물 극소량을 함유하는 탄화수소 기류를 제조하고; 바람직하지 않은 방향족 성분, 황 및 질소 화합물 극소량을 함유하는 생선된 탄화수소 기류를 회수하는 것으로 이루어진, 바람직하지 않은 방향족 성분, 황 및 질소 화합물을 함유하는 충전된 탄화수소 오일의 처리방법.
  2. 제1항에 있어서, 8족 금속이 최종 촉매 중량에 대하여 2 내지 12주량% 존재하는 것인 탄화수소 오일의 처리방법.
  3. 제1항에 있어서, 6B족 금속이 텅스텐이고, 최종 촉매 중량에 대하여 10 내지 45중량% 존재하는 것인 탄화수소 오일의 처리방법.
  4. 제1항에 있어서, 6B족 금속이 최종 촉매 중량에 대하여 5 내지 18중량% 존재하는 몰리브덴 및 크롬으로부터 선택된 1이상의 금속인 것인 탄화수소 오일의 처리방법.
  5. 제1항에 있어서, 촉매가 8족 및 6B족 금속과 함께 0.01 내지 4중량%의 붕소 또는 불소를 함유하는 것인 탄화수소 오일의 처리방법.
  6. 제1항 내지 제5항중 어느 하나의 항에 있어서, 수소화처리 조건의 온도가 300 내지 410℃인 것인 탄화수소 오일의 처리방법.
  7. 제1항 내지 제6항중 어느 하나의 항에 있어서, 압력이 28 내지 173MPa인 것인 탄화수소 오일의 처리방법.
  8. 제1항 내지 제7항중 어느 하나의 항에 있어서, "인 처리된 탄소"지지체의 전체 기공 부피 중 20 내지 80%가 직경이 20 내지 500Å인 기공 내에 있는 것인 탄화수소 오일의 처리방법.
  9. 제1항 내지 제8항중 어느 하나의 항에 있어서, "인 처리된 탄소"지지체가 인 원소로 계산하여 0.1 내지 10중량%의 인을 함유하는 것인 탄화수소 오일의 처리방법.
  10. 제1항 내지 제9항중 어느 하나의 항에 있어서, 탄화수소 오일 공급물이 고정층 반응기 시스템, 비등층 반응기 시스템, 유동층 반응기 시스템, 슬러리 반응기 시스템이나, 또는 분말이나 그래뉼인 촉매가 탄화수소 공급물과 함께 슬러리되어 반응기로 보내지는 병류 시스템에서 처리되는 것인 탄화수소 오일의 처리방법.
  11. "인 처리된 탄소"지지체 상에, 최종 촉매 중량에 대하여 철, 코발트 및 니켈에서 선택된 1 이상의 8족 금속 0.1 내지 15중량%, 텅스텐 1 내지 50중량%, 몰리브덴 및 크롬 1 내지 20중량%로부터 선택된 1 이상의 6B족 금속으로 이루어지되, 상기에서 "인 처리된 탄소"지지체가 (1)450℃ 이상의 온도에서 활성 탄소와 인 화합물의 혼합물을 열 처리하고 제조되고, (2)"인 처리된 탄소"내에 존재하는 인은 고체상 매직 각 방사 31p핵 자기 공명 스펙트럼에서 -5 내지 -30ppm 사이의 피므로 특징지워지는 폴리포스페이트 종으로서 주로 탄소 표면에 결합하고, (3)100 내지 2,000㎡/g의 B.E.T 표면적과 0.3㎖/g 이상의 질소에 대한 전체 기공 부피 및 12 내지 100Å의 평균 기공 직경을 가지는 것을 특징으로 하는, 수소화 탈황반응, 수소화 탈질소반응, 수소화 탈방향족반응, 수소화탈산소반응, 수소화 크래킹반응, 수소화반응, 수소화 청징반응, 수소화 탈금속반응, 및 탄화수소 오일의 수소 대 탄소 비율, API 중력, 색상 등을 개선하는 기타 수소화 처리반응에 유용한 수소화 처리 촉매 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950024379A 1994-08-09 1995-08-08 금속 황화물 촉매가 지지된 신규한 "인으로 처리된 탄소"를 이용한 탄화수소 오일의 수소화 탈방향족 방법 KR960007740A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/287,979 US5462651A (en) 1994-08-09 1994-08-09 Hydrodearomatization of hydrocarbon oils using novel "phosphorus treated carbon" supported metal sulfide catalysts
US08/287,979 1994-08-09

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KR960007740A true KR960007740A (ko) 1996-03-22

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US (2) US5462651A (ko)
EP (1) EP0696632A1 (ko)
JP (1) JPH08176559A (ko)
KR (1) KR960007740A (ko)
CA (1) CA2155086A1 (ko)

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