KR950704374A - 프로필렌 단일 중합체(propylene homopolymers) - Google Patents

프로필렌 단일 중합체(propylene homopolymers)

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Publication number
KR950704374A
KR950704374A KR1019950702447A KR19950702447A KR950704374A KR 950704374 A KR950704374 A KR 950704374A KR 1019950702447 A KR1019950702447 A KR 1019950702447A KR 19950702447 A KR19950702447 A KR 19950702447A KR 950704374 A KR950704374 A KR 950704374A
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alkyl
propylene homopolymer
aryl
group
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KR1019950702447A
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KR100289453B1 (ko
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랑하우저 프란쯔
게르트 주에르겐
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랑핑어, 슈타인호프
바스프 악티엔게젤샤프트
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 155℃미만의 융점, 5중량% 미만의 크실렌 용해 단편 및 3미만의 분자량 분포를 가지는 프로필렌 단일 중합체에 관한 것이다.

Description

프로필렌 단일 중합체(PROPYLENE HOMOPOLYMERS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

155℃미만의 융점, 5중량% 미만의 크실렌 용해 단편 및 3미만의 분자량 분포를 가지는 프로필렌 단일 중합체.
제1항에 있어서, 융점이 150℃ 이하인 것을 특징으로 하는 프로필렌 단일 중합체.
제1항 또는 2항에 있어서, 2중량%의 크실렌 용해 단편을 가지는 것을 특징으로 하는 프로필렌 단일 중합체.
제1항 내지 3항 중 어느 한항에 있어서, 활성 성분으로서 주기율표의 IV족 및 V족 금속의 금속 복합체 및 산화 알루미늄 올리고머 화합물을 포함하는 촉매 시스템의 존재하에서, 1 내지 300 bar의 압력 및 1 내지 300℃의 온도에서 프로필렌을 중합하여 얻어지는 것을 특징으로 하는 프로필렌 단일 중합체.
제1항 내지 4항 중 어느 한 항에 있어서, 7 내지 70 bar의 압력 및 30 내지 170℃의 온도에서 프로필렌을 중합하여 얻어지는 것을 특징으로 하는 프로필렌 단일 중합체.
제1항 내지 5항중 어느 한 항에 있어서, 일반식(I)의 금속 복합체가 주기율표의 IV족 및 V족 금속의 금속 복합체로서 사용되며, 산화알루미늄 올리고머 화합물로서 일반식(II)의 개방 사슬 또는 고리 알루모옥산 화합물이 사용되는 것을 특징으로 하는 프로필렌 단일 중합체.
[상기식에서, M이 티타늄, 지르코늄, 하프늄, 바나듐, 니오븀 또는 탄탈이고, X가 불소, 염소, 브톰, 요오드, 수소, C1-C10-알킬, C6-C15-아릴, -OR5이고, R5가 C1-C10-알킬, C6-C15-아릴, 각각 알킬기에 1 내지 10개의 탄소 원자를 가지고 아릴기에 6 내지 20개의 탄소 원자를 가지는 알킬아릴, 아릴알킬, 플루오로알킬 또는 플루오로아릴이고, R5내지 R4및 R6내지 R9가 각각 수소, C1-C10의 알킬, 계속하여 치환체로서 C1-C10-알킬 라디칼을 수반하는 5원 내지 7원 시클로알킬, 두개의 인접한 라디칼이 함께 포화고리 또는 4 내지 15개의 탄소 원자를 가지는 부분적으로 포화 또는 불포화고리를 형성하는 C6-C15-아릴 또는 아릴아킬, 또는 Si(R10)3이고, R10이 C1-C10-알킬, C6-C15-아릴 또는 C3-C10-시클로알킬이고,
Z가 실리콘, 게르마늄, 주석 또는 탄소이며, R11, R12, R13, R14는 각각 수소, C1-C10의 알킬, 두개의 인접한 라디칼이 함께 포화고리 또는 4내지 15개의 탄소 원자를 가지는 부분적으로 포화 또는 불포화고리를 형성하는 C6-C15-아릴이다.)
[상기 식에서, R15가 C1-C4-알킬이고, m이 5 내지 30의 정수이다.]
제4항에 따른 공정 조건 하에서, 프로필렌 단일 중합체를 제조하는 방법.
섬유, 필름 및 몰딩을 제조하기 위하여, 제1항 내지 6항 중 어느 한 항에 따른 프로필렌 단일 중합체를 사용하는 방법.
필수 성분으로서 제1 내지 6항에 따른 프로필렌 단일 중합체로부터 얻을 수 있는 섬유, 필름 및 몰딩.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950702447A 1992-12-16 1993-12-03 프로필렌 단독중합체 KR100289453B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4242486A DE4242486A1 (de) 1992-12-16 1992-12-16 Propylen-Homopolymere
DEP4242486.0 1992-12-16
PCT/EP1993/003397 WO1994013713A1 (de) 1992-12-16 1993-12-03 Propylen-homopolymere

Publications (2)

Publication Number Publication Date
KR950704374A true KR950704374A (ko) 1995-11-20
KR100289453B1 KR100289453B1 (ko) 2001-05-02

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ID=6475444

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EP (1) EP0674668B1 (ko)
JP (1) JPH08504457A (ko)
KR (1) KR100289453B1 (ko)
DE (2) DE4242486A1 (ko)
ES (1) ES2105606T3 (ko)
WO (1) WO1994013713A1 (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100367964B1 (ko) * 1994-10-13 2003-04-26 엑손모빌 케미칼 패턴츠 인코포레이티드 중합촉매시스템,이의제조및용도
JPH08198913A (ja) * 1995-01-26 1996-08-06 Sumitomo Chem Co Ltd ポリプロピレンフイルム
EP0745638A1 (de) * 1995-05-31 1996-12-04 Hoechst Aktiengesellschaft Biaxial orientierte Polypropylenfolie mit verbessertem Weiterreisswiderstand
ES2150616T3 (es) * 1995-05-31 2000-12-01 Hoechst Ag Lamina de polipropileno biaxialmente orientada con una estabilidad dimensional mejorada.
EP0745637A1 (de) * 1995-05-31 1996-12-04 Hoechst Aktiengesellschaft Biaxial orientierte Polypropylenfolie mit hohem Flächenmodul
EP0747212A1 (de) * 1995-05-31 1996-12-11 Hoechst Aktiengesellschaft Biaxial orientierte Polypropylenfolie mit verbesserten Eigenschaften hinsichtlich Wasserdampf- und Sauerstoffbarriere
ES2150615T3 (es) * 1995-05-31 2000-12-01 Hoechst Ag Lamina de polipropileno biaxialmente orientada con propiedades mejoradas referente a la mecanica y la barrera.
EP0745639A1 (de) * 1995-05-31 1996-12-04 Hoechst Aktiengesellschaft Biaxial orientierte Polypropylenfolie mit guten optischen Eigenschaften
EP0745477A1 (de) * 1995-05-31 1996-12-04 Hoechst Aktiengesellschaft Biaxial orientierte Polypropylenfolie mit verbessertem Migrationswiderstand
DE19544709A1 (de) * 1995-11-30 1997-06-05 Basf Ag Biaxial orientierte Polypropylenfolie aus Metallocen-Polypropylen
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
JPH10182899A (ja) * 1996-12-27 1998-07-07 Mitsui Chem Inc ポリプロピレン製二軸延伸フィルム
DE19710761A1 (de) * 1997-03-14 1998-09-17 Basf Ag Hochkristalline Propylenhomopolymerisate
US5908594A (en) * 1997-09-24 1999-06-01 Fina Technology, Inc. Process of making polypropylene fiber
US7022795B1 (en) 1998-03-13 2006-04-04 Novolen Technology Holdings, C.V. Highly crystalline propylene homopolymers
DE50012267D1 (de) 1999-12-21 2006-04-27 Basell Polyolefine Gmbh Teilkristalline propylenpolymerisat-zusammensetzung zur herstellung von biaxial gereckten polypropylenfolien
US7402638B2 (en) 2003-08-22 2008-07-22 Mitsui Chemicals, Inc. Propylene polymer particle method of producing the same and use thereof
CN105980421B (zh) 2014-12-04 2018-04-27 株式会社Lg化学 未经拉伸的基于聚丙烯的膜

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JP3016880B2 (ja) * 1991-02-01 2000-03-06 三菱化学株式会社 フィルム成形用高結晶性ポリプロピレン
DE4119343A1 (de) * 1991-06-12 1992-12-17 Basf Ag Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
JPH05178927A (ja) * 1991-12-27 1993-07-20 Tosoh Corp オレフィン重合用触媒およびオレフィン重合体の製造方法

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Publication number Publication date
DE4242486A1 (de) 1994-06-23
KR100289453B1 (ko) 2001-05-02
ES2105606T3 (es) 1997-10-16
EP0674668A1 (de) 1995-10-04
JPH08504457A (ja) 1996-05-14
EP0674668B1 (de) 1997-08-20
WO1994013713A1 (de) 1994-06-23
DE59307181D1 (de) 1997-09-25

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