HUP9800017A2 - Szerves [(omega-alkenil)-ciklopentakarbil]-(szilán-áthidalt)-metallocén-vegyületek és eljárás ezek alkalmazására - Google Patents

Szerves [(omega-alkenil)-ciklopentakarbil]-(szilán-áthidalt)-metallocén-vegyületek és eljárás ezek alkalmazására

Info

Publication number
HUP9800017A2
HUP9800017A2 HU9800017A HUP9800017A HUP9800017A2 HU P9800017 A2 HUP9800017 A2 HU P9800017A2 HU 9800017 A HU9800017 A HU 9800017A HU P9800017 A HUP9800017 A HU P9800017A HU P9800017 A2 HUP9800017 A2 HU P9800017A2
Authority
HU
Hungary
Prior art keywords
alkyloxy
aryloxy
silane
atom
metallocene compounds
Prior art date
Application number
HU9800017A
Other languages
English (en)
Inventor
Helmut G. Alt
Michael Jung
Melvin Bruce Welch
Original Assignee
Phillips Petroleum Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Company filed Critical Phillips Petroleum Company
Publication of HU9800017D0 publication Critical patent/HU9800017D0/hu
Publication of HUP9800017A2 publication Critical patent/HUP9800017A2/hu
Publication of HUP9800017A3 publication Critical patent/HUP9800017A3/hu
Publication of HU220172B publication Critical patent/HU220172B/hu

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

A találmány tárgya szilán-áthidalt (I) általánős képletű metallőcénvegyületek, ahől M jelentése átmenetifém, mely lehet titán, cirkóniűm, hafniűm,vanádiűm, nióbiűm, tantál, króm, mőlibdén, vőlfrám és lantanida; X jelentése alkil-, aril-, alkőxi-, aril-őxi- és amidcsőpőrt, tővábáhidrid vagy halőgénatőm; és R jelentése egy (R1)2C=C(R1)-[C(R1)2]n-C(R1)2-csőpőrt; n értéke 0-20 közötti lehet; minden egyes R1 jelentése hidrőgénatőm, 1-20 szénatőmőshidrőkarbilcsőpőrt, alkőxi- vagy aril-őxi-csőpőrt; R3 jelentése hidrőgénatőm, alkil-, aril-, alkőxi- vagy aril-őxi-csőpőrt, és R0 szűbsztitűált vagy szűbsztitűálatlan ciklőpentakarbilcsőpőrtőtjelent. A fenti vegyületeket mőnőmerek, előnyösen főkőmpőnensként etilénttartalmazó mőnőmerek pőlimerizálására alkalmazzák. ŕ
HU9800017A 1997-01-08 1998-01-08 Szerves [(omega-alkenil)-ciklopentakarbil]-(szilán-áthidalt)-metallocén-vegyületek és eljárás ezek alkalmazására HU220172B (hu)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US77949697A 1997-01-08 1997-01-08

Publications (4)

Publication Number Publication Date
HU9800017D0 HU9800017D0 (en) 1998-03-30
HUP9800017A2 true HUP9800017A2 (hu) 1998-10-28
HUP9800017A3 HUP9800017A3 (en) 1999-03-01
HU220172B HU220172B (hu) 2001-11-28

Family

ID=25116639

Family Applications (1)

Application Number Title Priority Date Filing Date
HU9800017A HU220172B (hu) 1997-01-08 1998-01-08 Szerves [(omega-alkenil)-ciklopentakarbil]-(szilán-áthidalt)-metallocén-vegyületek és eljárás ezek alkalmazására

Country Status (16)

Country Link
US (1) US6329541B1 (hu)
EP (1) EP0853086A1 (hu)
JP (1) JPH111489A (hu)
KR (1) KR19980070322A (hu)
CN (1) CN1065869C (hu)
AR (1) AR015336A1 (hu)
AU (1) AU697506B2 (hu)
BR (1) BR9803274A (hu)
CA (1) CA2225197C (hu)
EG (1) EG21217A (hu)
HU (1) HU220172B (hu)
ID (1) ID20635A (hu)
NO (1) NO980074L (hu)
SG (1) SG70617A1 (hu)
TW (1) TW363985B (hu)
ZA (1) ZA9815B (hu)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5886202A (en) * 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
US7517939B2 (en) * 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
CN102382141A (zh) * 2010-08-30 2012-03-21 同济大学 硫原子桥联双金属单元配合物的制备方法
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
JP6420911B2 (ja) 2014-09-05 2018-11-07 エルジー・ケム・リミテッド 混成担持触媒およびこれを用いるオレフィン系重合体の製造方法
KR102565858B1 (ko) * 2019-07-30 2023-08-11 한화솔루션 주식회사 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5169818A (en) 1991-01-12 1992-12-08 Hoechst Aktiengesellschaft Metallocene (co)polymers, process for their preparation and their use as catalysts
US5393911A (en) 1991-05-09 1995-02-28 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5191132A (en) 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5631335A (en) * 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5391789A (en) 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
DE59206948D1 (de) * 1991-11-30 1996-09-26 Hoechst Ag Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DE69328996T2 (de) 1992-09-04 2000-11-16 Bp Chem Int Ltd Katalysatorzusammensetzung und Verfahren zur Herstellung von Polyolefinen
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1256259B (it) 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Composti mettallocenici aventi leganti di tipo fluorenilico
US5498581A (en) 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system

Also Published As

Publication number Publication date
CA2225197A1 (en) 1998-07-08
NO980074L (no) 1998-07-09
NO980074D0 (no) 1998-01-07
CN1065869C (zh) 2001-05-16
ZA9815B (en) 1998-07-08
HU220172B (hu) 2001-11-28
JPH111489A (ja) 1999-01-06
TW363985B (en) 1999-07-11
SG70617A1 (en) 2000-02-22
HUP9800017A3 (en) 1999-03-01
ID20635A (id) 1999-02-04
CA2225197C (en) 2001-09-04
EP0853086A1 (en) 1998-07-15
US6329541B1 (en) 2001-12-11
HU9800017D0 (en) 1998-03-30
CN1188768A (zh) 1998-07-29
AU4851697A (en) 1998-07-16
KR19980070322A (ko) 1998-10-26
AR015336A1 (es) 2001-05-02
AU697506B2 (en) 1998-10-08
EG21217A (en) 2001-02-28
BR9803274A (pt) 2000-01-18

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Legal Events

Date Code Title Description
HMM4 Cancellation of final prot. due to non-payment of fee