KR950702222A - 오일 첨가제 및 조성물(oil additives and compositions) - Google Patents
오일 첨가제 및 조성물(oil additives and compositions)Info
- Publication number
- KR950702222A KR950702222A KR1019940704855A KR19940704855A KR950702222A KR 950702222 A KR950702222 A KR 950702222A KR 1019940704855 A KR1019940704855 A KR 1019940704855A KR 19940704855 A KR19940704855 A KR 19940704855A KR 950702222 A KR950702222 A KR 950702222A
- Authority
- KR
- South Korea
- Prior art keywords
- composition
- copolymer
- ethylene
- coor
- oil
- Prior art date
Links
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
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- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
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- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
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- C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
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- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/16—Amides; Imides
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
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- C10M145/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of a saturated carboxylic or carbonic acid
- C10M145/08—Vinyl esters of a saturated carboxylic or carbonic acid
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- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/16—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate polycarboxylic
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- C10M157/00—Lubricating compositions characterised by the additive being a mixture of two or more macromolecular compounds covered by more than one of the main groups C10M143/00 - C10M155/00, each of these compounds being essential
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Abstract
둘 이상의 재에스테르화된 에틸렌-불포화 에스테르 공중합체, 예를 들면 에틸렌-비닐 아세테이트 공중합체를 포함하여 이루어지는 조성물은 연료 오일의 저온 성질을 개선시킨다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (31)
- (a)에틸렌으로부터 유도된 단위와 함께, 하기식 I의 단위 및 하기식 Ⅱ의 단위를 가지며, 공중합체 내식 I 및 Ⅱ의 단위의 전체 몰 비율이 10%미만인 오일 가용성 에틸렌 공중합체를 포함하여 이루어지거나(단, 식I의 단위와 식Ⅱ의 단위는 상이하다)또는 (b)(i)에틸렌으로부터 유도된 단위와 함께, 10몰%미만의 하기식 I의 단위를 갖는 오일 가용성 에틸렌 공중합체와 (ii)에틸렌으로부터 유도된 단위와 함께, 10몰%미만의 하기식 Ⅱ의 단위를 갖는 오일 가용성 에틸렌 공중합체를 포함하여 이루어지는(단, 공중합체(i)와 공중합체(ii)는 상이하다)조성물:-CH2-CRR1(I)-CH2-CRR2(Ⅱ)상기식에서, 각각의 R은 독립적으로 H 또는 CH3를 나타내고, 각각의 R1및 R2는 독립적으로 식 COOR3또는 OOCR3의 기를 나타내며, 각각의 R3는 독립적으로 하이드로카빌 기를 나타낸다.
- 제1항에 있어서, R3이 적어도 4개의 탄소원자를 갖는 직쇄 알킬 기를 나타내는 조성물.
- 제1항 또는 제2항에 있어서, R3이 30개 이하의 탄소원자를 갖는 조성물.
- 제1항 내지 제3항중 어느 한 항에 있어서, R1및 R2가 각각 -OOCR3을 나타내는 조성물.
- 제1항 내지 제4항중 어느 한 항에 있어서, R이 H를 나타내는 조성물.
- 제1항 내지 제5항중 어느 한 항에 있어서, 조성물(b)이고, 식에서 R1및 R2가 각각 식 OOCR3의 기를 나타내고 여기서, R3이 5 내지 13개의 탄소 원자를 갖는 알킬기를 나타내는 조성물.
- 제6항에 있어서, 중합체 성분(b)(i) 및 (b)(ii)가 각각 20,000이하의 수평균 분자량(Mn)을 갖는 조성물.
- 제7항에 있어서, Mn이 3,000 내지 6,000 범위 내인 조성물.
- 제7항 또는 제8항에 있어서, 성분(b)(i) 및 (b)(ii)의 Mn이 200이하 차이나는 조성물.
- 제7항 내지 제9항중 어느 한 항에 있어서, 중합체 성분(b)(i) 및 (b)(ii)가 각각 0.3 내지 7.5몰%의 식I 및 식Ⅱ의 단위를 함유하는 조성물.
- 제1항 내지 제10항중 어느 한 항에 있어서, 중합체 또는 적어도 하나의 중합체가 에틸렌-불포화 에스테르 공중합체의 비누화 및 재-에스테르화에 의해 제조된 조성물.
- 제1항 내지 제10항중 어느 한 항에 있어서, R1및 R2가 둘다 -COOR3을 나타내고 중합체가 에틸렌-비닐 아세테이트 공중합체의 비누화 및 재-에스테르화에 의해 제조된 조성물.
- 제1항 내지 제5항중 어느 한 항에 있어서, (b)조성물이고, 공중체(i)가 에틸렌-비닐 아세테이트 공중합체이고/이거나 R1이 COOR3(여기서, R3이 탄소원자수 2 내지 7의 직쇄 알킬기이다)을 나타내는 공중합체이고, 공중합체(ii)가 R2가 COOR3(여기서, R3이 탄소원자수 2 내지 7의 직쇄 알킬기이다)을 나타내는 공중합체인 조성물.
- 제1항 내지 제13항중 어느 한 항에 있어서, 왁스 결정화 저지제를 또한 포함하여 이루어지는 조성물.
- 제14항에 있어서, 상기 저지제가 중합체(a)의 에스테르 함량 또는 (b)(i) 및 (b)(ii)의 높은 대표치의 에스테르 함량보다 적어도 2몰% 높은 에스테르 함량을 갖는 에틸렌-비닐 에스테르 공중합체인 조성물.
- 제1항 내지 제15항중 어느 한 항에 있어서, 코움 중합체를 또한 포함하여 이루어지는 조성물.
- 제16항에 있어서, 코움 중합체가 하기 일반식을 갖는 조성물:상기식에서, D는 R, COOR11, OCOR, R12COOR11, 또는 OR11이고; E는 H, CH3, D 또는 R12이고; G는 H 또는 D이고, J는 H, R12, COOR12, R12OCOR11, COOH 또는 아릴 또는 헤테로고리 기이고; K 는 H, COOR12, OCOR12, OR12또는 COOH이고 L은 H, R12, COOR12, OCOR12, COOH 또는 아릴이고; R11은 C10이상의 하이드로카빌이고; R12는 C1이상의 하이드로카빌이고; m 및 n은 몰비를 나타내고, m은 1.0 내지 0.4의 범위내에 있고, n은 0 내지 0.6의 범위내에 있다.
- 제16항 내지 제17항에 있어서, 코움 중합체가 비닐 아세테이트와 푸마레이트 에스테르의 공중합체인 조성물.
- 제18항에 있어서, 에스테르기가 탄소원자수 12내지 20의 알킬기인 조성물.
- 제19항에 있어서, 에스테르기가 탄소원자수 14의 알콜, 또는 탄소원자수 14 및 16의 알콜의 혼합물로부터 유도되는 조성물.
- 제1항 내지 제15항중 어느 한 항에 있어서, 둘 이상의 상이한 코움 중합체의 혼합물을 포함하여 이루어지는 조성물.
- 제16항에 있어서, 상기 혼합물이 i)C14푸마레이트 에스테르-비닐 아세테이트 공중합체 및 ii)C14/C16푸마레이트 에스테르-비닐 아세테이트 공중합체를 포함하여 이루어지는 조성물.
- 제1항 내지 제22항중 어느 한 항에 있어서, 극성 질소 화합물을 또한 포함하여 이루어지는 조성물.
- 제1항에 있어서, 본 명세서의 실시예들 중 어느 하나에 기재된 것과 실질적으로 같은 조성물.
- 제1항 내지 제24항중 어느 한 항의 청구된 것과 같은 첨가제 조성물을 포함하여 이루어지는 연료 또는 윤활유 조성물.
- 제25항에 있어서, 오일 중량을 기준으로 하여 전체 비율 0.005 내지 1%의 첨가제 조성물에 함유하는 조성물.
- 제25항에 있어서, 오일 중량을 기준으로 하여 전체 비율 0.001 내지 0.1%의 첨가제 조성물에 함유하는 조성물.
- 제25항에 있어서, 오일 중량을 기준으로 하여 전체 비율 0.004 내지 0.06%의 첨가제 조성물에 함유하는 조성물.
- 오일 또는 오일과 혼화성인 용매 내에 제1항 내지 제24항중 어느 한 항에 정의된 조성물을 포함하여 이루어지는 첨가제 농축물.
- 오일의 저온 특성을 개선함에 있어서, 제1항 내지 제24항중 어느 한 항에 청구된 것과 같은 첨가제 조성물의 용도.
- 본 명세서에 기재된 임의의 신규한 특징 또는 본 명세서에 기재된 특징들의 임의의 신규한 조합.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9213871.8 | 1992-06-30 | ||
GB929213871A GB9213871D0 (en) | 1992-06-30 | 1992-06-30 | Oil additives and compositions |
PCT/EP1993/001665 WO1994000515A1 (en) | 1992-06-30 | 1993-06-29 | Oil additives and compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
KR950702222A true KR950702222A (ko) | 1995-06-19 |
KR100293916B1 KR100293916B1 (ko) | 2001-10-24 |
Family
ID=10717943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940704855A KR100293916B1 (ko) | 1992-06-30 | 1993-06-29 | 오일첨가제및조성물 |
Country Status (12)
Country | Link |
---|---|
US (1) | US6638325B1 (ko) |
EP (1) | EP0649445B2 (ko) |
JP (1) | JP3411572B2 (ko) |
KR (1) | KR100293916B1 (ko) |
CN (1) | CN1085226C (ko) |
AT (1) | ATE151800T1 (ko) |
AU (1) | AU4560993A (ko) |
CA (1) | CA2137227C (ko) |
DE (1) | DE69309928T3 (ko) |
GB (1) | GB9213871D0 (ko) |
RU (1) | RU95107404A (ko) |
WO (1) | WO1994000515A1 (ko) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9213904D0 (en) * | 1992-06-30 | 1992-08-12 | Exxon Chemical Patents Inc | Oil additives and compositions |
GB9417670D0 (en) * | 1994-09-02 | 1994-10-19 | Exxon Chemical Patents Inc | Oil additives, compositions and polymers for use therein |
GB9417667D0 (en) * | 1994-09-02 | 1994-10-19 | Exxon Chemical Patents Inc | Oil additives, compositions and polymers for use therein |
GB9725578D0 (en) | 1997-12-03 | 1998-02-04 | Exxon Chemical Patents Inc | Oil additives and compositions |
DE19754555A1 (de) | 1997-12-09 | 1999-06-24 | Clariant Gmbh | Verfahren zur Herstellung von Ethylen-Mischpolymerisaten und deren Verwendung als Zusatz zu Mineralöl und Mineralöldestillaten |
DE10349850C5 (de) | 2003-10-25 | 2011-12-08 | Clariant Produkte (Deutschland) Gmbh | Kaltfließverbesserer für Brennstofföle pflanzlichen oder tierischen Ursprungs |
DE10349851B4 (de) * | 2003-10-25 | 2008-06-19 | Clariant Produkte (Deutschland) Gmbh | Kaltfließverbesserer für Brennstofföle pflanzlichen oder tierischen Ursprungs |
DE10357877B4 (de) * | 2003-12-11 | 2008-05-29 | Clariant Produkte (Deutschland) Gmbh | Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften |
DE10357878C5 (de) * | 2003-12-11 | 2013-07-25 | Clariant Produkte (Deutschland) Gmbh | Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften |
DE10357880B4 (de) * | 2003-12-11 | 2008-05-29 | Clariant Produkte (Deutschland) Gmbh | Brennstofföle aus Mitteldestillaten und Ölen pflanzlichen oder tierischen Ursprungs mit verbesserten Kälteeigenschaften |
US20050138859A1 (en) * | 2003-12-16 | 2005-06-30 | Graham Jackson | Cold flow improver compositions for fuels |
WO2005087092A1 (en) * | 2004-02-24 | 2005-09-22 | Wisconsin Alumni Research Foundation | Side-firing probe for performing optical spectroscopy during core needle biopsy |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
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US3402223A (en) * | 1966-03-23 | 1968-09-17 | Union Carbide Corp | High molecular weight ethylene copolymer and low molecular weight ethylene-vinyl acetate copolymer blend |
US3642459A (en) * | 1968-04-01 | 1972-02-15 | Exxon Research Engineering Co | Copolymers of ethylene with unsaturated esters and oil compositions containing said copolymers |
DE1914756C3 (de) † | 1968-04-01 | 1985-05-15 | Exxon Research and Engineering Co., Linden, N.J. | Verwendung von Ethylen-Vinylacetat- Mischpolymerisaten für Erdöl-Destillate |
GB1314855A (en) * | 1970-06-17 | 1973-04-26 | Monsanto Chemicals | Lubricating oil compositions containing viscosity index improvers |
DE2037673C2 (de) † | 1970-07-16 | 1985-07-04 | Exxon Research and Engineering Co., Linden, N.J. | Polymerisatgemische als Fließpunktverbesserer für Kohlenwasserstoffe und deren Verwendung |
US3961916A (en) * | 1972-02-08 | 1976-06-08 | Exxon Research And Engineering Company | Middle distillate compositions with improved filterability and process therefor |
GB1499568A (en) † | 1974-04-17 | 1978-02-01 | Exxon Research Engineering Co | Preparation of copolymers of ethylene and ethylenically unsaturated monomers and distillate oil containing copolymers so produced |
US4211534A (en) * | 1978-05-25 | 1980-07-08 | Exxon Research & Engineering Co. | Combination of ethylene polymer, polymer having alkyl side chains, and nitrogen containing compound to improve cold flow properties of distillate fuel oils |
JPS5840391A (ja) * | 1981-09-03 | 1983-03-09 | Sumitomo Chem Co Ltd | 燃料油の低温流動性改良方法 |
DD230549A3 (de) † | 1983-02-02 | 1985-12-04 | Leuna Werke Veb | Additivgemisch |
EP0155807A3 (en) * | 1984-03-22 | 1985-11-27 | Exxon Research And Engineering Company | Middle distillate compositions with improved low temperature properties |
DE3501384A1 (de) * | 1985-01-17 | 1986-07-17 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur verbesserung der fliessfaehigkeit von mineraloelen und mineraloeldestillaten |
JPS6270488A (ja) † | 1985-09-24 | 1987-03-31 | Mitsubishi Petrochem Co Ltd | 燃料油添加剤および流動性の改善された燃料油 |
DE3613247C2 (de) † | 1986-04-19 | 1995-04-27 | Roehm Gmbh | Konzentrierte Emulsionen aus Ethylen-Vinylacetat-Copolymeren, Verfahren zu deren Herstellung und deren Verwendung als Stockpunktverbesserer |
DE3625174A1 (de) † | 1986-07-25 | 1988-01-28 | Ruhrchemie Ag | Verfahren zur verbesserung der fliessfaehigkeit von mineraloelen und mineraloeldestillaten |
JPH0218494A (ja) † | 1988-07-07 | 1990-01-22 | Sumitomo Chem Co Ltd | 燃料油およびその低温流動性向上剤 |
GB9007970D0 (en) * | 1990-04-09 | 1990-06-06 | Exxon Chemical Patents Inc | Fuel oil compositions |
GB9213904D0 (en) * | 1992-06-30 | 1992-08-12 | Exxon Chemical Patents Inc | Oil additives and compositions |
GB9213909D0 (en) * | 1992-06-30 | 1992-08-12 | Exxon Chemical Patents Inc | Oil additives and compositions |
GB9213827D0 (en) * | 1992-06-30 | 1992-08-12 | Exxon Chemical Patents Inc | Oil additives and compositions |
-
1992
- 1992-06-30 GB GB929213871A patent/GB9213871D0/en active Pending
-
1993
- 1993-06-29 CN CN93107717A patent/CN1085226C/zh not_active Expired - Lifetime
- 1993-06-29 US US08/356,194 patent/US6638325B1/en not_active Expired - Fee Related
- 1993-06-29 RU RU95107404/04A patent/RU95107404A/ru unknown
- 1993-06-29 EP EP93915732A patent/EP0649445B2/en not_active Expired - Lifetime
- 1993-06-29 CA CA002137227A patent/CA2137227C/en not_active Expired - Lifetime
- 1993-06-29 AT AT93915732T patent/ATE151800T1/de not_active IP Right Cessation
- 1993-06-29 KR KR1019940704855A patent/KR100293916B1/ko not_active IP Right Cessation
- 1993-06-29 AU AU45609/93A patent/AU4560993A/en not_active Abandoned
- 1993-06-29 WO PCT/EP1993/001665 patent/WO1994000515A1/en active IP Right Grant
- 1993-06-29 JP JP50205894A patent/JP3411572B2/ja not_active Expired - Lifetime
- 1993-06-29 DE DE69309928T patent/DE69309928T3/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR100293916B1 (ko) | 2001-10-24 |
DE69309928D1 (de) | 1997-05-22 |
CN1085226C (zh) | 2002-05-22 |
JPH07508300A (ja) | 1995-09-14 |
EP0649445B2 (en) | 2002-05-02 |
EP0649445B1 (en) | 1997-04-16 |
CA2137227A1 (en) | 1994-01-06 |
DE69309928T3 (de) | 2004-08-26 |
CA2137227C (en) | 2003-10-14 |
GB9213871D0 (en) | 1992-08-12 |
DE69309928T2 (de) | 1997-10-23 |
RU95107404A (ru) | 1996-12-27 |
CN1081694A (zh) | 1994-02-09 |
WO1994000515A1 (en) | 1994-01-06 |
ATE151800T1 (de) | 1997-05-15 |
EP0649445A1 (en) | 1995-04-26 |
US6638325B1 (en) | 2003-10-28 |
AU4560993A (en) | 1994-01-24 |
JP3411572B2 (ja) | 2003-06-03 |
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