KR950032335A - 방사선 경화성 조성물 - Google Patents

방사선 경화성 조성물 Download PDF

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KR950032335A
KR950032335A KR1019950014156A KR19950014156A KR950032335A KR 950032335 A KR950032335 A KR 950032335A KR 1019950014156 A KR1019950014156 A KR 1019950014156A KR 19950014156 A KR19950014156 A KR 19950014156A KR 950032335 A KR950032335 A KR 950032335A
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composition
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weight
coo
acrylate
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페터스 스테판
반덴 아인데 이반
반 기셀 아우구스트
마리 루츠 쟌
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알. 뒤셀도르프, 아이.씨.아이.에이.
유씨비 에스.에이.
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Publication of KR950032335A publication Critical patent/KR950032335A/ko

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Abstract

본 발명은 100중량부단 (a) CH2=CH-COO- 및 CH2=C(CH3)-COO-로부터 선택된 최소한 2개의 기를 함유하고 있는 최소한 하나의 방사선 중합가능한 화합물의 최소한 20 중량부; 및 (b) 하기 일반식의 최소한 하나의 (2-옥소-1-피롤리디닐)알킬 아크릴레이트:
(상기 식에서 R은 2 내지 4개의 탄소 원자를 함유하는 알킬렌 라디칼을 나타내고, R1은 수소 원자 또는 메틸 라디칼을 나타낸다)를 포함하는 방사선 경화성 조성물에 관한 것이다. 이 방사선 경화성 조성물은 자외선 조사에 의해 또는 가속화된 전자 빔에 의해 고속의 경화를 나타내며, 가장 다양한 기판에 대한 양호한 접착성, 높은 표면 경도, 개성된 내마모성 및 내화학약품성, 및 양호한 기계적 성질과 같은 우수한 특성을 가지는 코딩의 제조에 적절하다.

Description

방상선 경화성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

100 중량부단 (a)CH2=CH-COO- 및 CH2=C(CH3)-COO-로부터 선택된 최소한 2개의 기를 함유하고 있는 최소한 하나의 방사선 중합가능한 화합물의 최소한 20 중량부; 및 (b)하기 일반식의 최소한 하나의 (2-옥소-1-피롤리디닐)알킬 아크릴레이트:
(상기 식에서 R은 2 내지 4개의 탄소 원자를 함유하는 알킬렌 라디칼을 나타내고, R1은 수소 원자 또는 메틸 라디칼을 나타낸다)를 포함하는 방사선 경화성 조성물.
제1항에 있어서, (2-옥소-1-피롤리디닐)알킬 아크릴레이트(b)가 2-(2-옥소-1-피롤리디닐)에틸 아크릴레이트 또는 메타크릴레이트인 것을 특징으로 하는 조성물.
제1항에 있어서, 100중량부당 5 내지 50중량부의 (2-옥소-1-피롤리디닐)알킬 아크릴레이트(b)를 포함하는 것을 특징으로 하는 조성물.
제1항에 있어서, 화합물 (a)가 분자량 2 내지 15개, 바람직하게는 2 내지 6개의 CH2=CH-COO- 및 CH2=C(CH3)-COO-로부터 선택된기를 함유하는 것을 특징으로 하는 조성물.
제1항에 있어서, 화합물 (a)과 2 내지 6개의 히드록실기를 함유하는 다가 알코올의 아크릴산 및 메타크릴산 에스테르로 이루어지는 군으로부터 선택된 화합물인 것을 특징으로 하는 조성물.
제1항에 있어서, 화합물(a)가 10,000이하의 분자량을 가지는 올리고머 또는 프레폴리머인 것을 특징으로 하는 조성물.
제6항에 있어서, 올리고머 또는 프레폴리머가 폴리에스테르 아크릴레이트, 폴리에스테르 메타크릴레이트, 우레탄 아크릴레이트, 우레탄 메타크릴레이트, 에폭시 아크릴레이트, 에폭시 메타크릴레이트, 아크릴계 아크릴레이트 및 아크릴계 메타크릴레이트로 이루어지는 군으로부터 선택되어지는 것을 특징으로 하는 조성물.
제1항에 있어서, 화합물(a)와 상이한 하나 또는 그 이상의 포화 또는 불포화 올리고머 또는 중합체를 추가로 포함하는 것을 특징으로 하는 조성물.
제8항에 있어서, 상기 화합물(a)와 상이한 올리고머 또는 중합체가 포화 폴리에스테르, 불포화 폴리에스테르, (메트)아크릴계 중합체 및 할로겐화된 폴리에스테르로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 조성물.
제8항에 있어서, 2 내지 6개의 히드록실 기를 함유하고 있는 다가 알코올의 아크릴산 및 메타크실산의 에스테르로 이루어지는 군으로부터 선택된 최소한 하나의 화합물(a)과의 혼합 상태로 상기 화합물 (a)와 상이한 올리고머 또는 중합체를 포함하는 것을 특징으로 하는 조성물.
제1항에 있어서, CH2=CH-COO- 및 CH2=C(CH3)-COO-로부터 선택된 최소한 2개의 기를 함유하고 있는 최소한 하나의 화합물 (a)를, 100중량부당 35 내지 95 중량부로 포함하는 것을 특징으로 하는 조성물.
제1항에 있어서, 추가로 광개시제 및 임의로 활성화제로서 3차 아민을 포함하는 것을 특징으로 하는 조성물.
제12항에 있어서, 100중량부당 15중량%까지의 광개시제를 포함하는 것을 특징으로 하는 조성물.
제1항에 있어서, 추가로 첨가제, 충전제, 안료 및 염료로 이로어지는 군으로부터 선택된 최소한 하나의 보조 성분을 포함하는 것을 특징으로 하는 조성물.
(2-옥소-1-피롤리디닐)알킬 아크릴레이트(b)가 화합물(a)의 점도보다 실제로 낮은 점도를 가지는 조성물을 제조하기에 충분한 양으로 존재하는 제1항이 방사선 경화성 조성물의 기판의 표면에 도포하고, 상기 조성물을 경화된 코팅이 형성되기에 충분한 시간 동안 자외선 또는 가속화된 전자빔에 노출시키는 것으로 이루어지는, 기판을 코팅하기 위한 방법.
제1항에 따르는 조성물을 포함하는, 자외선 조사에 의해 경화가능한 코팅, 와니스, 도료, 잉크 또는 라미네이트용 접착제.
제1항에 따르는 조성물을 포함하는, 가속화된 전자 빔에 의해 경화가능한 코팅, 와니스, 도료, 잉크 또는 라미네이트용 접착제.
제16항에 따르는 코팅, 와니스, 도료, 잉크, 또는 접착제를 사용하여 형성된 제조 물품.
제17항에 따르는 코팅, 와니스, 도료, 잉크, 또는 접착제를 사용하여 형성된 제조 물품.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950014156A 1994-05-31 1995-05-31 방사선 경화성 조성물 KR950032335A (ko)

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EP0685535A1 (fr) 1995-12-06
ES2114292T3 (es) 1998-05-16
DE69501363D1 (de) 1998-02-12
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JPH0841133A (ja) 1996-02-13
ATE161873T1 (de) 1998-01-15

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