KR950017899A - 알킬 라디칼에 의해 α위치가 치환된 알데히드의 제조방법 - Google Patents

알킬 라디칼에 의해 α위치가 치환된 알데히드의 제조방법 Download PDF

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KR950017899A
KR950017899A KR1019940034609A KR19940034609A KR950017899A KR 950017899 A KR950017899 A KR 950017899A KR 1019940034609 A KR1019940034609 A KR 1019940034609A KR 19940034609 A KR19940034609 A KR 19940034609A KR 950017899 A KR950017899 A KR 950017899A
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carried out
ppm
weight
process according
isomerization
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KR1019940034609A
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KR100319330B1 (ko
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베버 위르겐
스프링거 헬무트
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페터즈, 라이헬트
훽스트 아크티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Abstract

분자내 탄소수가 8 내지 17이고, 알킬 라디킬에 의해 α위치가 치환된 알데히드를 탄소수가 하나 적은 말단 올레핀으로 부터 수득한다. 이 목적을 위해, 올레핀을 먼저 철 카보닐의 존재하에 다음, 철 화합물을 분리 제거하지 않고 촉매로서 로듐의 존재하에 하이드로포밀화한다.

Description

알킬 라디칼에 의해위치가 치환된 알데히드의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 알단 이중결합이 우세한 올레핀을 액상으로 160 내지 210℃에서, 철 카보닐의 존재하에 이성체화하고, 이성체화 촉매를 분리 제거하지 않고, 이성체화 혼합물을 80 내지 200℃ 및 5 내지 50MPa의 압력에서 로듐 촉매의 존재하에 하이드로포밀화함을 포함하여, 탄소수가 7 내지 16이고 내부적 이중결합을 갖는 올레핀을 하이드로포밀화함으로써 탄소수가 8 내지 17이고 알킬 라디칼에 의해 α위치가 치환된 알데히드를 제조하는 방법.
  2. 제1항에 있어서, 이성체화를 올레핀을 기준으로 하여 50 내지 1,000중량PPm, 바람직하게는 200 내지 500중량ppm의 철 카보닐의 존재하에 수행하는 방법,
  3. 제1항 또는 제2항에 있어서, 이성체화를 170 내지 190℃에서 수행하는 방법.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 하이드로포밀화를 을레핀을 기준으로 하여 1 내지 20중량ppm, 바람직하게는 2 내지 5중량pp의 로듐의 존재하에 수행하는 방법.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, 하이드로포밀화를 120 내지 150℃의 온도에서 수행하는 방법.
  6. 제1항 내지 제5항 중의 어느 한 항에 있어서, 하이드로포밀화를 20 내지 30MPa의 압력에서 수행하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940034609A 1993-12-23 1994-12-16 알킬라디칼에의해알파위치가치환된알데히드의제조방법 KR100319330B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4344064A DE4344064C1 (de) 1993-12-23 1993-12-23 Verfahren zur Herstellung von in alpha-Stellung durch einen Alkylrest substituierten Aldehyden
DEP4344064.9 1993-12-23

Publications (2)

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KR950017899A true KR950017899A (ko) 1995-07-20
KR100319330B1 KR100319330B1 (ko) 2002-07-27

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KR1019940034609A KR100319330B1 (ko) 1993-12-23 1994-12-16 알킬라디칼에의해알파위치가치환된알데히드의제조방법

Country Status (16)

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US (1) US5481044A (ko)
EP (1) EP0659725B1 (ko)
JP (1) JP2672473B2 (ko)
KR (1) KR100319330B1 (ko)
CN (1) CN1040100C (ko)
AU (1) AU674620B2 (ko)
BR (1) BR9405133A (ko)
CA (1) CA2138222C (ko)
CZ (1) CZ282412B6 (ko)
DE (2) DE4344064C1 (ko)
ES (1) ES2103099T3 (ko)
HU (1) HU212345B (ko)
PL (1) PL175826B1 (ko)
RU (1) RU94045264A (ko)
TW (1) TW393461B (ko)
ZA (1) ZA9410039B (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6407302B1 (en) † 1999-11-04 2002-06-18 Bp Corporation North America Inc. Isomerization process of a mixture containing vinyl and vinylidene olefins
US6982355B2 (en) * 2003-08-25 2006-01-03 Syntroleum Corporation Integrated Fischer-Tropsch process for production of linear and branched alcohols and olefins
DE102006032317A1 (de) * 2006-07-11 2008-01-24 Symrise Gmbh & Co. Kg In alpha-Stellung durch Alkylreste substituierte Aldehyde als Riech- und Aromastoffe
KR101005640B1 (ko) 2007-05-28 2011-01-05 주식회사 엘지화학 알데히드의 제조방법 및 장치
WO2021247177A1 (en) 2020-06-05 2021-12-09 SCION Holdings LLC Alcohols production
ES2929364B2 (es) * 2021-05-28 2024-03-18 Consejo Superior Investigacion Procedimiento de obtencion de alquenos lineales de cadena larga

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
NL7105267A (en) * 1971-04-19 1972-10-23 Isomerisation of alkenes - using iron carbonyl catalyst in the presence of carbon monoxide
US4200591A (en) * 1977-06-21 1980-04-29 Johnson, Matthey & Co., Limited Catalytic hydroformylation
US4178313A (en) * 1978-07-14 1979-12-11 Conoco, Inc. Olefin isomerization and hydroformylation process
US4388476A (en) * 1981-05-01 1983-06-14 Eastman Kodak Company Hydroformylation process with rhodium catalyst and oxygen stabilization thereof
WO1984003697A1 (en) * 1983-03-16 1984-09-27 Exxon Research Engineering Co High temperature hydroformylation
US4782188A (en) * 1983-11-14 1988-11-01 The Dow Chemical Company Process for hydroformylation of unsaturated compounds using iron carbonyl catalysts
US4587374A (en) * 1984-03-26 1986-05-06 Ethyl Corporation Olefin isomerization process
DE3421809A1 (de) * 1984-06-12 1985-12-12 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von 2-methyl-2-alkenalen
GB2192182B (en) * 1986-07-01 1990-05-23 Davy Mckee Process for the production of aldehydes
US5082977A (en) * 1990-02-15 1992-01-21 University Of Akron Aldehydes by olefin hydroformylation
DE4316180A1 (de) * 1992-09-16 1994-11-17 Basf Ag Verfahren zur Herstellung von Aldehyden

Also Published As

Publication number Publication date
AU8164094A (en) 1995-06-29
EP0659725B1 (de) 1997-05-02
CN1040100C (zh) 1998-10-07
ZA9410039B (en) 1995-08-29
KR100319330B1 (ko) 2002-07-27
CA2138222C (en) 1998-07-14
PL306338A1 (en) 1995-06-26
CA2138222A1 (en) 1995-06-24
ES2103099T3 (es) 1997-08-16
US5481044A (en) 1996-01-02
PL175826B1 (pl) 1999-02-26
RU94045264A (ru) 1997-02-27
DE4344064C1 (de) 1995-06-01
DE59402601D1 (de) 1997-06-05
EP0659725A1 (de) 1995-06-28
JPH07285904A (ja) 1995-10-31
JP2672473B2 (ja) 1997-11-05
BR9405133A (pt) 1995-10-17
HUT69760A (en) 1995-09-28
HU212345B (en) 1996-05-28
HU9403630D0 (en) 1995-03-28
CN1127244A (zh) 1996-07-24
CZ282412B6 (cs) 1997-07-16
AU674620B2 (en) 1997-01-02
CZ319394A3 (en) 1996-08-14
TW393461B (en) 2000-06-11

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