KR940703899A - 재 활용 가능한 기질용 제거 가능한 감압성 접착제 - Google Patents

재 활용 가능한 기질용 제거 가능한 감압성 접착제

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Publication number
KR940703899A
KR940703899A KR1019940702215A KR19940702215A KR940703899A KR 940703899 A KR940703899 A KR 940703899A KR 1019940702215 A KR1019940702215 A KR 1019940702215A KR 19940702215 A KR19940702215 A KR 19940702215A KR 940703899 A KR940703899 A KR 940703899A
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South Korea
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weight
sensitive adhesive
pressure
total
rosin
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KR1019940702215A
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English (en)
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KR100255497B1 (ko
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마가렛트 베르나드 말리카
로렌스 슈나이더스 조셉
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리차드 피. 랜달
애버리 데니슨 코포레이션
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Publication of KR940703899A publication Critical patent/KR940703899A/ko
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/26—Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
    • C08L93/04—Rosin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

에멀젼 감압 접착 폴리머를 로진 기초 산성 점착제 및 로진 기초 계면 활성제와 조합한 것에 기초한 온수 및 알칼리 제거 가능한 감압 접착조성물을 제공한다.

Description

재 활용 가능한 기질용 제거 가능한 감압성 접착제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (a) 에멀젼 중합에 의해 형성되는 아크릴계 감압 고분자로서, 이 고분자는 , 중합된 것에 기준해서 단량체 전체의 중량에 대하여; (ⅰ) 총 중량이 전체 단량체에 대하여 최소한 35중량% 이상되며, 알킬기에 4 내지 8개의 탄소를 포함하는, 최소한 한종 이상의 알킬아크릴레이트; 및 (ⅱ) 총 중량이 전체 단량체에 대하여 0 이상 5중량%까지 포함되며, 3 내지 5의 탄소원자를 포함하는 불포화 카르복실산으로 이루어지거나, 또는, 로진산 점착제 및 로진-기초 계면 활성제와 상용성 있을 정도의 충분한 극성을 갖는 고무-기초 에멀젼 폴리머로 구성되며, (b) 폴리머 각 100중량부에 대하여 첨가제로서; (ⅰ) 로진산 점착제 3 내지 20중량부, 및 (ⅱ) 로진 기초 계면활성제 1 내지 10중량부로 이루어지며, 이와 같이 이루어지는 감압 접착 조성물은 종이 배면에 적용될 때 극성 또는 비극성 기질을 온수 또는 알칼리에 노출시키게 되면 5분이내에 비종이 표면으로부터 깨끗하게 제거되어 질 수 있는 감압 접착 조성물.
  2. 아크릴계, 감압 접착제는 본래적으로 점착성이 있으며, 중합된 것을 기준으로 하여 단량체 전체 중량에 대하여; (a) 총 중량이 전체 단량체에 대하여 35 내지 60중량%되며, 알킬기에 4 내지 8의 탄소수를 포함하는 최소한 한종의 알킬 아크릴레이트; (b) 총 중량이 전체 단량체에 대하여 15 내지 35중량%되며, 산의 알킬기에서 2 내지 16의 탄소수를 포함하는 최소한 한종의 비닐 에스테르; (c) 총 중량이 전체 당량체에 대하여 20 내지 40중량%되며, 디에스테르의 각 알킬기는 각각 독립적으로 6 내지 12의 탄소수를 포함하는 최소한 한종의 디카르복실산의 디에스테르; 및 (d) 총 중량이 전체 당량체에 대하여 0 이상 5중량%까지 되며, 3 내지 5의 탄소수를 갖는 최소한 한종의 불포화 카르복실산으로 구성되며, 상기한 폴리머는 -30℃ 이하의 유리전이 온도를 갖고, 폴리머의 50 내지 70중량%의 겔함량을 갖는 ; 제1항에 따른 감압 접착 조성물.
  3. 아크릴계 에멀진 폴리머는 본래적으로 점착성이 있는 감압 접착 폴리머이며, (a) 총 중량이 40 내지 50중량%이며, 알킬기에서 4 내지 8의 탄소수를 갖는 2-에틸헥실 아크릴레이트, 이소옥틸 아크릴레이트, 및 이들의 혼합물을 포함하는 최소한 하나의 알킬 아크릴레이트; (b) 15 내지 35중량%의 비닐 아세테이트; (c) 총 중량이 20 내지 40중량%이며, 디-2-에틸헥실 말레이트 및 디-2-에틸헥실 푸말레이트 및 이들의 혼합물에서 선택되어지는 디카르복실산의 최소한 하나의 디에스테르; 및 (d) 1 내지 3중량%의 량으로 존재하는, 아크릴 산, 메타크릴 산, 및 이들의 혼합물로 이루어지는 군에서 선택되어지는 불포화 카르복실산; 으로 이루어지며, 이 폴리머는 -30℃ 이하의 유리 전이 온도 및 폴리머의 중량에 대하여 50 내지 70%의 겔 함량을 갖는 , 제1항에 따른 감압 접착 조성물.
  4. 본래 점착성이 있는 아크릴계 감압 접착 폴리머는 전체 단량체 총 중량에 대하여, (a) 2-에틸헥실아크릴레이트 48중량%; (b) 비닐 아세테이트 21중량%; (c) 디-2-에틸헥실 말레이트 29중량%; 및 (d) 아크릴산 1중량% 및 메타크릴산 1중량%; 으로 구성되어지는 제1항에 따른 감압 접착 조성물.
  5. 고무-기초 에멀젼 폴리머는 스틸렌을 20 내지 50중량% 포함하는 카르복실화 스틸렌-부타디엔 랜덤 코폴리머인 제1항에 따른 감압 접착 조성물.
  6. 점착제가 3 내지 15중량%의 농도로 사용되어지는 제1항 내지 제5항중 어느 하나의 항에 따른 감압 접착 조성물.
  7. 계면 활성제가 1 내지 5중량%로 사용되어지는 제1항 내지 제6항중 어느 하나의 항에 따른 감압 접착 조성물.
  8. 점착제가 50 이상 210 이하의 산 수를 갖는 제1항 내지 제7항중 어느 하나의 항에 따른 감압 접착 조성물.
  9. 점착제는, 비결정화이며, 부분적으로 중합된 로진, 변성 로진, 불균형 로진, 안정화된 로진, 수소화로진 및 이들의 혼합물로 이루어지는 군에서 선택되어지며, 50 이상 210 이하의 산 수를 갖는 제1항 내지 제7항중 어느 하나의 항에 따른 감압 접착 조성물.
  10. 계면 활성제가 에틸렌옥사이드 15몰을 함유하는 비이온성 침엽수 로진인 제1항 내지 제9항중 어느 하나의 항에 따른 감압 접착 조성물.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940702215A 1991-12-24 1992-12-22 재 활용 가능한 기질용 제거 가능한 감압성 접착제 KR100255497B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US813.354 1991-12-24
US813,354 1991-12-24
US07/813,354 US5183841A (en) 1991-12-24 1991-12-24 Removable pressure-sensitive adhesives for recyclable substrates
PCT/US1992/011161 WO1993013181A1 (en) 1991-12-24 1992-12-22 Removable pressure-sensitive adhesives for recyclable substrates

Publications (2)

Publication Number Publication Date
KR940703899A true KR940703899A (ko) 1994-12-12
KR100255497B1 KR100255497B1 (ko) 2000-05-01

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Country Status (11)

Country Link
US (2) US5183841A (ko)
EP (1) EP0618947B1 (ko)
JP (1) JPH07506126A (ko)
KR (1) KR100255497B1 (ko)
AU (1) AU672381B2 (ko)
BR (1) BR9206986A (ko)
CA (1) CA2126351C (ko)
DE (1) DE69226653T2 (ko)
MX (1) MX9207556A (ko)
TW (1) TW316277B (ko)
WO (1) WO1993013181A1 (ko)

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CA2126351A1 (en) 1993-07-08
KR100255497B1 (ko) 2000-05-01
US5385965A (en) 1995-01-31
JPH07506126A (ja) 1995-07-06
EP0618947B1 (en) 1998-08-12
DE69226653T2 (de) 1998-12-24
DE69226653D1 (de) 1998-09-17
EP0618947A1 (en) 1994-10-12
BR9206986A (pt) 1995-09-12
TW316277B (ko) 1997-09-21
AU672381B2 (en) 1996-10-03
EP0618947A4 (en) 1995-05-31

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