KR940018454A - 탄소 소진 방법 - Google Patents

탄소 소진 방법 Download PDF

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Publication number
KR940018454A
KR940018454A KR1019940000656A KR19940000656A KR940018454A KR 940018454 A KR940018454 A KR 940018454A KR 1019940000656 A KR1019940000656 A KR 1019940000656A KR 19940000656 A KR19940000656 A KR 19940000656A KR 940018454 A KR940018454 A KR 940018454A
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South Korea
Prior art keywords
soot
oxidation treatment
vanadium
partially oxidized
process according
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KR1019940000656A
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KR100306844B1 (ko
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마르티누스 게라르두스 클레멘스 틸즈 헨리쿠스
Original Assignee
알베르투스 빌헬무스 요아네스 쩨스트라텐
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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Application filed by 알베르투스 빌헬무스 요아네스 쩨스트라텐, 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 filed Critical 알베르투스 빌헬무스 요아네스 쩨스트라텐
Publication of KR940018454A publication Critical patent/KR940018454A/ko
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Publication of KR100306844B1 publication Critical patent/KR100306844B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G31/00—Compounds of vanadium
    • C01G31/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00—Obtaining refractory metals
    • C22B34/20—Obtaining niobium, tantalum or vanadium
    • C22B34/22—Obtaining vanadium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1687—Integration of gasification processes with another plant or parts within the plant with steam generation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Processing Of Solid Wastes (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Industrial Gases (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Vending Machines For Individual Products (AREA)
  • Catalysts (AREA)

Abstract

가스화 방법에 의해 얻어질 수 있는 부분적으로 산화된 바나듐을 함유한 그을음을 전환하는 방법으로서, 최종 생성물내 바나듐 펜톡사이드의 양이, 그을음내 존재하는 부분적으로 산화된 바나듐을 기준으로 계산하여, 많아야 30중량% 이도록 하는 조건하에서 수행되는 산화 처리에 상기 그을음을 적용시키는 것을 포함하는 방법.

Description

탄소 소진 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 가스화 방법에 의해 얻어질 수 있는 부분적으로 산화된 바나듐을 함유하는 그을음을 전환하는 방법으로서, 최종생성물 내 바나듐 펜톡사이드의 양이 그을음 내 존재하는 부분적으로 산화된 바나듐을 기준으로 계산하여, 많아야 30중량% 이도록 하는 조건하에서 수행되는 산화 처리에 상기 그을음을 적용시키는 것을 포함하는 방법.
  2. 제 1 항에 있어서, 산화 처리를 노상(爐床)로 내에서 수행되는 방법.
  3. 제 2 항에 있어서, 다중 노상 로를 사용하는 방법.
  4. 제1 내지 3항중 하나 이상의 항에 있어서, 산화 처리를 1200℃ 이하 반응층 온도에서 수행하는 방법.
  5. 제 4 항에 있어서, 산화처리를 700℃ 내지 900℃ 범위의 반응층 온도에서 수행하는 방법.
  6. 제1 내지 5항중 하나 이상의 항에 있어서, 부분적으로 산화된 바나듐을 70중량% 까지, 바람직하게 35중량%까지 (건조 기준으로) 함유하는 그을음을 산화 처리에 적용시키는 방법.
  7. 제1 내지 5항중 하나 이상의 항에 있어서, 실질적으로 건조한 그을음을 산화 처리에 적용시키는 방법.
  8. 제1 내지 7항중 하나 이상의 항에 있어서, 최종 생성물 내 바나듐 펜톡사이드의 양이, 그을음 내 존재하는 부분적으로 산화된 바나듐을 기준으로 계산하여, 많아야 25중량%, 바람직하게는 15중량% 이하 이도록 하는 방법으로 산화 처리를 수행하는 방법.
  9. 제 1 내지 8항중 하나 이상의 항에 있어서, 가스 유출물이 표준 조건의 온도 및 압력 하에서 공기를 기준으로 계산하여, 적어도 12부피%의 산소, 바람직하게 15부피% 이상의 산소를 함유하는 방법.
  10. 제1 내지 8항중 하나 이상의 항에 있어서, 조절제의 존재하에 산화 처리를 수행하는 방법.
  11. 제10항에 있어서, 중기, 이산화탄소 또는 질소를 조절제로 사용하는 방법.
  12. 제1 내지 10항중 하나 이상의 항에 있어서, 산화제의 질량천이 계수 및 탄소 연소 속도 상수 간의 비율이 〈0.1 이게 하는 조건하에서 산화 처리를 수행하는 방법.
  13. 부분 산화 반응기내에서 산소 및 조절제의 존재하에 바나듐을 함유하는 탄화수소를 원료 합성 가스로 전환하고, 반응기를 이탈하고 하나 이상의 세척 단계에 의하여 반응기 출구 가스내 함유된 남아있는 잔류탄소를 제거하는 뜨거운 가스로 부터 고온의 증기를 생성하고, 부분적으로 산화된 바나듐 함유 그을음을 제1 내지 12항중 하나 이상이 항에 따른 방법에 적용시킴으로써 표준 조건의 온도 및 압력하에서 액체인 탄화수소를 전환하는 방법.
  14. 선행의 청구범위중 하나이상의 항에 따른 방법에 의하여 얻어지는, 바나듐 펜톡사이드를 많아야 30중량% 함유하는 부분적으로 산화된 바나듐.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940000656A 1993-01-14 1994-01-13 탄소소진방법 KR100306844B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP93200092A EP0606669A1 (en) 1993-01-14 1993-01-14 Carbon burn-off process
EP93200092,0 1993-01-14

Publications (2)

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KR940018454A true KR940018454A (ko) 1994-08-18
KR100306844B1 KR100306844B1 (ko) 2001-11-30

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EP (2) EP0606669A1 (ko)
JP (1) JPH074633A (ko)
KR (1) KR100306844B1 (ko)
CN (1) CN1036514C (ko)
AU (1) AU673699B2 (ko)
CA (1) CA2113319C (ko)
DE (1) DE69422203T2 (ko)
ES (1) ES2143523T5 (ko)
FI (1) FI111838B (ko)
NO (1) NO309987B1 (ko)
PT (1) PT606957E (ko)
ZA (1) ZA94234B (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0606669A1 (en) † 1993-01-14 1994-07-20 Shell Internationale Researchmaatschappij B.V. Carbon burn-off process
CN1049163C (zh) * 1995-08-28 2000-02-09 中国石油化工总公司石油化工科学研究院 热不稳定催化剂的氧化烧炭再生
JP2004532174A (ja) 2001-03-30 2004-10-21 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ ガス化プロセスで得られる煤水スラリーの脱水方法
DE10152686B4 (de) * 2001-10-19 2004-09-23 Lurgi Ag Verfahren zur thermischen Behandlung von Vanadium enthaltenden Rückständen
ITBA20120049A1 (it) * 2012-07-24 2014-01-25 Itea Spa Processo di combustione
US9896918B2 (en) 2012-07-27 2018-02-20 Mbl Water Partners, Llc Use of ionized water in hydraulic fracturing

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE756946R (fr) * 1969-10-03 1971-04-01 Continental Ore Corp Procede de traitement de scories contenant du
SE399280B (sv) * 1976-04-20 1978-02-06 Sotex Ab Forfarande for att utvinna metaller, sasom vanadin, ur sot fran forbrenning av olja
DE2718404A1 (de) * 1977-04-26 1978-11-02 Metallgesellschaft Ag Gewinnung einer vanadiumreichen substanz aus der thermischen vergasung fluessiger kohlenwasserstoffe
US4203759A (en) * 1978-05-01 1980-05-20 Exxon Research & Engineering Co. Process for the preparation of a vanadium-containing metallic ash concentrate
FR2432051A1 (fr) * 1978-07-27 1980-02-22 Inst Francais Du Petrole Procede permettant la recuperation d'elements metalliques contenus dans des produits carbones
DE3119609A1 (de) * 1981-05-16 1982-12-02 Ruhrchemie Ag, 4200 Oberhausen Herstellung von synthesegas aus aschereichen kohlenwasserstoffen
US4477416A (en) * 1982-09-27 1984-10-16 Union Carbide Corporation Salt roasting of vanadium ore in the presence of carbon
DE4137320A1 (de) † 1991-11-13 1993-05-19 Metallgesellschaft Ag Verfahren zum behandeln eines vanadiumhaltigen rueckstands
DE4213328A1 (de) * 1991-11-13 1993-10-28 Metallgesellschaft Ag Verfahren zum Behandeln eines vanadiumhaltigen Rückstands
EP0606669A1 (en) † 1993-01-14 1994-07-20 Shell Internationale Researchmaatschappij B.V. Carbon burn-off process

Also Published As

Publication number Publication date
EP0606669A1 (en) 1994-07-20
NO940119L (no) 1994-07-15
CA2113319C (en) 2006-12-19
FI111838B (fi) 2003-09-30
ES2143523T5 (es) 2008-08-01
EP0606957B2 (en) 2008-03-12
NO940119D0 (no) 1994-01-13
ZA94234B (en) 1994-08-22
CA2113319A1 (en) 1994-07-15
DE69422203T2 (de) 2000-04-20
AU5318594A (en) 1994-07-21
FI940169A0 (fi) 1994-01-13
KR100306844B1 (ko) 2001-11-30
JPH074633A (ja) 1995-01-10
EP0606957A1 (en) 1994-07-20
DE69422203D1 (de) 2000-01-27
NO309987B1 (no) 2001-04-30
EP0606957B1 (en) 1999-12-22
ES2143523T3 (es) 2000-05-16
AU673699B2 (en) 1996-11-21
CN1036514C (zh) 1997-11-26
CN1092377A (zh) 1994-09-21
FI940169A (fi) 1994-07-15
PT606957E (pt) 2000-05-31

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