KR940007048A - 포스포릴티오메틸 설폭사이드 - Google Patents
포스포릴티오메틸 설폭사이드 Download PDFInfo
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- KR940007048A KR940007048A KR1019930019328A KR930019328A KR940007048A KR 940007048 A KR940007048 A KR 940007048A KR 1019930019328 A KR1019930019328 A KR 1019930019328A KR 930019328 A KR930019328 A KR 930019328A KR 940007048 A KR940007048 A KR 940007048A
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- Prior art keywords
- alkyl
- alkylthio
- compound
- alkylamino
- optionally substituted
- Prior art date
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- -1 Phosphorylthiomethyl sulfoxide Chemical class 0.000 title claims abstract 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 6
- 239000001301 oxygen Substances 0.000 claims abstract 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 4
- 125000003282 alkyl amino group Chemical group 0.000 claims abstract 4
- 125000004414 alkyl thio group Chemical group 0.000 claims abstract 4
- 125000004663 dialkyl amino group Chemical group 0.000 claims abstract 4
- 125000001072 heteroaryl group Chemical group 0.000 claims abstract 4
- 229910052717 sulfur Chemical group 0.000 claims abstract 4
- 239000011593 sulfur Chemical group 0.000 claims abstract 4
- 125000003545 alkoxy group Chemical group 0.000 claims abstract 2
- 125000000217 alkyl group Chemical group 0.000 claims abstract 2
- 239000000575 pesticide Substances 0.000 claims abstract 2
- 125000003107 substituted aryl group Chemical group 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 4
- 125000006559 (C1-C3) alkylamino group Chemical group 0.000 claims 3
- 241000607479 Yersinia pestis Species 0.000 claims 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims 3
- 125000001624 naphthyl group Chemical group 0.000 claims 3
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims 2
- 125000005605 benzo group Chemical group 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- 125000004076 pyridyl group Chemical group 0.000 claims 2
- 125000000714 pyrimidinyl group Chemical group 0.000 claims 2
- 125000004768 (C1-C4) alkylsulfinyl group Chemical group 0.000 claims 1
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 1
- 239000003905 agrochemical Substances 0.000 claims 1
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 claims 1
- 125000001164 benzothiazolyl group Chemical group S1C(=NC2=C1C=CC=C2)* 0.000 claims 1
- 125000004541 benzoxazolyl group Chemical group O1C(=NC2=C1C=CC=C2)* 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 125000004773 chlorofluoromethyl group Chemical group [H]C(F)(Cl)* 0.000 claims 1
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 claims 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 claims 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000006125 ethylsulfonyl group Chemical group 0.000 claims 1
- 125000002541 furyl group Chemical group 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 125000005956 isoquinolyl group Chemical group 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 claims 1
- JVJQPDTXIALXOG-UHFFFAOYSA-N nitryl fluoride Chemical compound [O-][N+](F)=O JVJQPDTXIALXOG-UHFFFAOYSA-N 0.000 claims 1
- 125000002971 oxazolyl group Chemical group 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 claims 1
- 125000003373 pyrazinyl group Chemical group 0.000 claims 1
- 125000003226 pyrazolyl group Chemical group 0.000 claims 1
- 125000002098 pyridazinyl group Chemical group 0.000 claims 1
- 125000005493 quinolyl group Chemical group 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 150000003462 sulfoxides Chemical class 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 125000001113 thiadiazolyl group Chemical group 0.000 claims 1
- 125000000335 thiazolyl group Chemical group 0.000 claims 1
- 125000001544 thienyl group Chemical group 0.000 claims 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 1
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6536—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and sulfur atoms with or without oxygen atoms, as the only ring hetero atoms
- C07F9/6539—Five-membered rings
- C07F9/6541—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
- A01N57/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34 containing aromatic radicals
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
- A01N57/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34 containing heterocyclic radicals
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
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- C07F9/40—Esters thereof
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Abstract
본 발명은 농약으로서 사용할 수 있는 하기 일반식(Ⅰ)의 신규한 포스포릴티오메틸 설폭사이드에 관한 것이다.
상기 식에서, Q는 산소 또는 황을 나타내고, R1은 알킬, 알킬티오, 알킬아미노 또는 디알킬아미노를 나타내며, R2는 알콕시, 알킬티오, 알킬아미노 또는 디알킬아미노를 나타내고, R3는 임의로 치환된 아릴 또는 임의로 치환된 헤테로아릴을 나타낸다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 일반식(Ⅰ)의 포르포릴티오메틸 설폭사이드.상기 식에서, Q는 산소 또는 황을 나타내고, R1은 알킬, 알킬티오, 알킬아미노 또는 디알킬아미노를 나타내며, R2는 알콕시, 알킬티오, 알킬아미노 또는 디알킬아미노를 나타내고, R3는 임의로 치환된 아릴 또는 임의로 치환된 헤테로아릴을 나타낸다.
- 제1항에 있어서, Q는 산소 또는 황을 나타내고, R1은 C1-C6-알킬, C1-C6-알킬티오, C1-C5-알킬아미노 또는 디-(C1-C5-알킬)-아미노를 나타내며, R2는 C1-C6-알콕시, C1-C6-알킬티오, C1-C5-알킬아미노 또는 디-(C1-C5-알킬)-아미노를 나타내고, R3는 각 경우에 임의로 치환된 페닐 또는 나프틸을 나타내거나, 1 내지 3개의 헤테로 원자를 함유하는 임의로 치환되고/나거나 임의로 벤조 융합된 헤테로아릴을 나타내며, 이들 페닐, 나프틸, 헤테로아릴 또는 벤조 융합된 환은 시아노, 니트로, 할로겐, C1-C4-알킬, C1-C4-알콕시, C1-C4-알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐 또는 C1-C4-알콕시카보닐, C1-C4-할로게노알킬, C1-C4-할로게노알콕시, C1-C4-할로게노알킬티오, C1-C4-할로게노알킬설피닐 및/또는 C1-C4-할로게노알킬설포닐에 의해 치환될 수 있는 화합물.
- 제1항에 있어서, Q는 산소 또는 황을 나타내고, R1은 C1-C4-알킬, C1-C4-알킬티오, C1-C3-알킬아미노, 또는 디-(C1-C3-알킬)-아미노를 나타내며, R2는 C1-C4-알콕시, C1-C4-알킬티오, C1-C3-알킬아미노, 또는 디-(C1-C3-알킬)-아미노를 나타내고, R3는 페닐, 나프닐, 피리딜, 피리미디닐, 피리다지닐, 피라지닐, 퓨릴, 티에닐, 피라졸릴, 티아졸릴, 티아디아졸릴, 옥사디아졸릴, 옥사졸릴, 퀴놀릴, 이소퀴놀릴, 벤족사졸릴, 벤조티아졸릴 및 벤즈이미다졸릴로 구성된 그룹중에서 선택된 임의로 치환된 래디칼을 나타내며, 여기에서 적합한 치환체는 시아노, 니트로, 불소, 염소, 브롬, 메틸, 에틸, 메톡시, 에톡시, 메틸티오, 에틸티오, 메틸설피닐, 에틸설피닐, 메틸 설포닐, 에틸설포닐, 메톡시카보닐, 에톡시카보닐, 디플루오로메틸, 트리플루오로메틸, 클로로플루오로메틸, 디플루오로메톡시, 트리플루오로메톡시, 디플루오로메틸티오, 트리플루오로메틸티오, 클로로디플루오로메틸티오, 트리플루오로메틸설피닐 및/또는 트리플루오로메틸설포닐인 화합물.
- 제1항에 있어서, Q는 산소를 나타내며, R1은 C1-C4-알킬, C1-C4-알킬티오, C1-C3-알킬아미노 또는 디-(C1-C2-알킬)-아미노를 나타내며, R2는 C1-C4-알콕시를 나타내고, R3는 각각 할로겐, C1-C4-알킬, C1-C4-알콕시, C1-C4-알킬티오, C1-C4-알콕시카보닐, 니트로 및/또는 시아노에 의해 임의로 치환된 페닐, 피리딜 및 피리미디닐로 구성된 그룹중에서 선택된 래디칼을 나타내는 화합물.
- 제1항에 있어서, Q가 산소를 나타내는 화합물.
- 일반식(Ⅱ)의 포스포릴티오메틸 설파이드를, 적합하다면 촉매의 존재하 및 적합하다면 희석제의 존재하에서, 산화제와 반응시킴을 특징으로 하여, 제1항에 따르는 일반식(Ⅰ)의 포스포릴티오메틸 설폭사이드를 제조하는 방법.상기 식에서, Q, R1, R2및 R3는 상기 언급한 의미를 갖는다.
- 제1항에 따르는 일반식(Ⅰ)의 화합물을 적어도 하나 함유함을 특징으로 하는 농약.
- 해충을 구제하기 위한 제1항에 따르는 일반식(Ⅰ)의 화합물의 용도.
- 제1항에 따르는 일반식(Ⅰ)의 화합물을 해충 및/또는 그들의 환경에 작용시킴을 특징으로 하여 해충을 구제하는 방법.
- 제1항에 따르는 일반식(Ⅰ)의 화합물을 중량제 및/또는 계면활성제와 혼합시킴을 특징으로 하여 농약을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4232174A DE4232174A1 (de) | 1992-09-25 | 1992-09-25 | Phosphorylthiomethylsulfoxide |
| DEP4232174.3 | 1992-09-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR940007048A true KR940007048A (ko) | 1994-04-26 |
Family
ID=6468848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930019328A KR940007048A (ko) | 1992-09-25 | 1993-09-22 | 포스포릴티오메틸 설폭사이드 |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0589319A1 (ko) |
| JP (1) | JPH06192280A (ko) |
| KR (1) | KR940007048A (ko) |
| DE (1) | DE4232174A1 (ko) |
| MX (1) | MX9305674A (ko) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2999874A (en) * | 1956-12-01 | 1961-09-12 | Bayer Ag | Esters of phosphoric and thiophosphoric acids containing sulfoxide groups and process for their production |
| FR1311303A (fr) * | 1961-10-18 | 1962-12-07 | Stauffer Chemical Co | Nouveaux insecticides et acaricides |
| AR204000A1 (es) * | 1973-04-02 | 1975-11-12 | American Cyanamid Co | Nuevos esteres de oxiacidos fosforicos y metodo para su preparacion |
| DE3818764A1 (de) * | 1988-06-02 | 1989-12-07 | Bayer Ag | Dithiophosphonsaeureester |
-
1992
- 1992-09-25 DE DE4232174A patent/DE4232174A1/de not_active Withdrawn
-
1993
- 1993-09-13 EP EP93114667A patent/EP0589319A1/de not_active Withdrawn
- 1993-09-15 MX MX9305674A patent/MX9305674A/es unknown
- 1993-09-20 JP JP5255262A patent/JPH06192280A/ja active Pending
- 1993-09-22 KR KR1019930019328A patent/KR940007048A/ko not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE4232174A1 (de) | 1994-03-31 |
| MX9305674A (es) | 1994-05-31 |
| JPH06192280A (ja) | 1994-07-12 |
| EP0589319A1 (de) | 1994-03-30 |
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