KR940003600A - 산소의 존재하에서 메탄을 사용한 NOx 및 일산화탄소의 촉매적 환원방법 - Google Patents

산소의 존재하에서 메탄을 사용한 NOx 및 일산화탄소의 촉매적 환원방법 Download PDF

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KR940003600A
KR940003600A KR1019920019110A KR920019110A KR940003600A KR 940003600 A KR940003600 A KR 940003600A KR 1019920019110 A KR1019920019110 A KR 1019920019110A KR 920019110 A KR920019110 A KR 920019110A KR 940003600 A KR940003600 A KR 940003600A
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zeolite
exchanged
methane
carbon monoxide
oxygen
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리 유진
넬슨 아모르 존
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윌리암 에프 마쉬
에어 프로덕츠 앤드 케미칼스 인코오포레이티드
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Abstract

본 발명은 메탄이 환원제로서 사용될때 산소-함유 연소 생성물에 존재하는 NOx 및 일산화탄소를 촉매적으로 파괴하는 방법을 설명하고 있다.
상기 방법은 산소의 존재하에 연료원을 연소시켜 질소산화물, 일산화탄소 및 산소를 함유하는 연소생성물을 형성시키는 단계, 메탄을 상기 연소 생성물에 도입하되, 질소산화물에 대한 메탄 총량이 용적 비로 표시할때 0.1 이상이 되도록 도입하는 단계; 및 교환된 결정 제올라이트 촉매의 존재하에, 질소산화물 및 일산화탄소 일부를 기체 질소, 물 및 이산화탄소로 전환시키기에 충분한 조건하에서 질소산화물, 일산화탄소, 메탄 및 산소를 반응 시키는 단계를 포함한다. 적절한 촉매에는 실리콘대 알루미늄의 비가 약 2.5 또는 그 이상인 제올라이트가 포함되며 상기 제올라이트는 갈륨, 니오비움, 코발트, 니켈, 철, 크롬, 로디움 및 망간으로 구성된 군으로부터 선택된 양이온으로 교환되어 있다.

Description

산소의 존재하에서 메탄을 사용한 NOx 및 일산화탄소의 촉매적 환원방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 페리에라이트 기제 촉매에 의한 NO 전환율을 온도에 따라 Co-ZSM-5와 비교하여 나타내고 있다.

Claims (19)

  1. 연소 생성물에 있는 질소산화물 및 일산화탄소를 파괴하는 방법에 있어서, (a) 산소의 존재하에 연료원을 연소시켜 질소산화물, 일산화탄소 및 산소를 함유하는 연소생성물을 형성시키는 단계 ; (b) 메탄을 상기 연소 생성물에 도입하되, 질소산화물에 대한 메탄 총량이 용적비로 표시할때 0.1 이상이 되도록 도입하는 단계, 및 (c) 실리콘 대 알루미늄의 비가 약 2.5 또는 그 이상이고, 코발트, 니켈, 철, 크롬, 로디움, 갈륨 및 망간으로 구성된 군으로부터 선택된 양이온으로 교환된 결정 제올라이트를 함유하는 촉매의 존재하에, 상기 질소산화물 및 일산화탄소의 일부를 기체 질소, 물 및 이산화탄소로 전환시키기에 충분한 조건하에서 상기 연소 생성물, 메탄 및 산소를 반응시키는 단계를 포함하는 것을 특징으로 하는 방법.
  2. 제1항에 있어서, 상기 제올라이트는 교환된 제올라이트 총중량의 0,1 내지 약 l5wt% 양이온으로 교환되는 것을 특징으로 하는 방법.
  3. 제2항에 있어서. 상기 제올라이트 MOR, MFI 또는 FER 구조 형태의 제올라이트를 포함하는 것을 특징으로 하는 방법.
  4. 제1항에 있어서, 상기 연료원의 연소 단계는 내연기관내에서 실시되는 것을 특징으로하는 방법.
  5. 제4항에 있어서, 상기 촉매는 불활성 지지체 상의 백금 또는 팔라디움 촉매를 포함하는 별도의 단계를 추가로 포함하는 것을 특징으로 하는 방법.
  6. 제4항에 있어서, 상기 연료원은 C1내지 C5를 갖는 기상 또는 액상 탄화수소로 구성된 군으로로부터 선택된 하나 또는 그 이상의 성분을 함유하는 것을 특징으로 하는 방법.
  7. 제1항에 있어서, 상기 연료원의 연소단계는 외연 장치내에서 실시되는 것을 특징으로 하는 방법.
  8. 제7항에 있어서, 상기 연료원은 석탄, 오일, 폐석, 천연가스 및 C1내지 약C15을 갖는 기상 및 액상 탄화수소로 구성된 군으로부터 선택된 하나 또는 그 이상의 성분을 함유하는 것을 특징으로 하는 방법.
  9. 제1항에 있어서, 상기 촉매의 존재하에 연소생성물을 반응시키는 단계는 250℃내지 700℃의 온도 0.5 내지 300 대기압에서 수행되는 것을 특징으로 하는 방법.
  10. 제3항에 있어서, 상기 반응은 1,000hr-1 내지 100,000hr-1의 시간당 기체공간 속도로 고정된 베드반응기에서 수행되는 것을 특징으로 하는 방법.
  11. 제2항에 있어서, 상기 교환된 제올라이트는 교환된 제올라이트 총중량의 0.01 내지 약 2wt%에 해당하는 원소 주기율표의 제 3주기 전이금속 또는 5,6,7 및 11족 금속들로부터 선택된 부가의 금속으로 추가로 교환되는 것을 특징으로 하는 방법.
  12. 제2항에 있어서, 상기 금속-교환된 제올라이트는 함침된 금속-교환된 제올라이트의 총중량의 0.01wt% 내지 15wt%에 해당하는, 주기율표 5,6,7 및 11족 원소로부터 선택된 금속을 함유하는 음이온성 또 중성 종으로 항침되는 것을 특징으로 하는 방법.
  13. 제12항에 있어서, 금속-교환뇐 제올라이트상에 함침되는 종치 니오비움, 몰리브덴, 은, 바나듬망간으로 구성된 군으로부터 선택된 금속을 포함하는 것을 특징으로 하는 방법
  14. 제2항에 있어서, 상기 금속-교환된 제올라이트가 함침된 금속-교환된 제올라이트의 총량의 0.1 내지 23wt% 알루미나로 함침되는 것을 특징으로 하는 방법.
  15. 제3항에 있어서, 상기 MOR 구조형태의 제올라이트가 모르데나이트. Na-D, 프틸롤라이트 및 제올론으로 구성된 군으로부터 선택되는 것을 특징으로 하는 방법.
  16. 제3항에 있어서, 상기 MFI 구조 형태의 제올라이트가 ZSM-5, 실리칼라이트-1, 실리칼라이트, Zeta-1, Zeta-3 및 AZ-1으로 구성된 군으로부터 선택되는 것을 특징으로 하는 방법.
  17. 제3항에 있어서, 상기 FER구조 형태의 제올라이트가 페리에라이트, SR -D, Fu-9, Nu-23 및 ZSM-35로 구성된 군으로부터 선택되는 것을 특징으로 하는 방법.
  18. 제3항에 있어서, 상기 촉매가 갈륨-교환된 ZSM-5인 것을 특징으로 하는 방법.
  19. 제 3항에 있어서, 상기 촉매는 알루미나가 침전된 Co-ZSM-5인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920019110A 1992-08-13 1992-10-17 산소의 존재하에서 메탄을 사용한 NOx 및 일산화탄소의 촉매적 환원방법 KR960000013B1 (ko)

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US07/929,619 US5260043A (en) 1991-08-01 1992-08-13 Catalytic reduction of NOx and carbon monoxide using methane in the presence of oxygen

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