KR930700803A - 유동상 반응기의 질소 함유 연료 연소시의 n₂o 배출 감소 방법 - Google Patents

유동상 반응기의 질소 함유 연료 연소시의 n₂o 배출 감소 방법

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Publication number
KR930700803A
KR930700803A KR1019920702575A KR920702575A KR930700803A KR 930700803 A KR930700803 A KR 930700803A KR 1019920702575 A KR1019920702575 A KR 1019920702575A KR 920702575 A KR920702575 A KR 920702575A KR 930700803 A KR930700803 A KR 930700803A
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South Korea
Prior art keywords
flue gas
gas
hydrogen radical
injected
radical providing
Prior art date
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KR1019920702575A
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English (en)
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KR0164586B1 (ko
Inventor
힐투넨 마티
와이 리 얌
제이 오크스 에릭
Original Assignee
원본미기재
에이. 아할스트롬 코포레이션
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Application filed by 원본미기재, 에이. 아할스트롬 코포레이션 filed Critical 원본미기재
Publication of KR930700803A publication Critical patent/KR930700803A/ko
Application granted granted Critical
Publication of KR0164586B1 publication Critical patent/KR0164586B1/ko

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • F23C10/04—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
    • F23C10/08—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases
    • F23C10/10—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases the separation apparatus being located outside the combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/08—Arrangements of devices for treating smoke or fumes of heaters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2206/00—Fluidised bed combustion
    • F23C2206/10—Circulating fluidised bed
    • F23C2206/101—Entrained or fast fluidised bed
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/10—Nitrogen; Compounds thereof
    • F23J2215/101—Nitrous oxide (N2O)
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/20—Non-catalytic reduction devices
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Treating Waste Gases (AREA)
  • Chimneys And Flues (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Noodles (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)

Abstract

내용 없음.

Description

유동상 반응기의 질소 함유 연료 연소시의 N2O 배출 감소 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 의하여 N2O를 감소시키는 대표적 순환 유동상 시스템의 개략도;
제2, 3도는 다른 실시예의 개략도이다.

Claims (14)

  1. 입자의 유동성에 의한 제1 연소 단계와, 제1 연소 단계에서 배출되는 연도 가스로부터 입자를 분리시키는 입자 분리기를 가진 유동상 반응기에서 질소 함유 연료를 연소시킬때 나오는 연도 가스로부터 N2O의 배출을 감소시키는 방법에 있어서, 다음의 연소적 단계가 포함되는 방법. (a)질소 함유 연료와, 연료를 연소시키는 산소 함유 가스를 반응기의 제1 연소 단계로 공급하고, (b)제1 연소 단계의 온도를 약 700℃-900℃로 유지시키며; (c)입자를 함유한 연도 가스를 제1 연소 단계로부터 배출시키고; (d)연도 가스 내의 N20 환원을 촉진하기 충분한 양의 수소 라디칼이 발생하도록 연도 가스와 동일하거나 더 높은 온도에서 수소 라디칼을 생성시킬 수 있는 수소 라디칼 제공 첨가제를 배출되는 연도 가스에 첨가하며; (e)N2O 환원이 용이하도록 첨가된 수소 라디칼과 연도 가스를 양호하게 혼합시키고; (f)연도 가스로부터 입자의 대부분을 분리시킨다.
  2. 제1항에 있어서, 연도 가스의 온도를 900℃이상으로 상승시키는 열을 공급하기 위하여 첨가제를 연소시키기 위한 산소 함유 가스가, 배출되는 연도 가스로 공급되는 방법.
  3. 제1항에 있어서, 수소 라디칼 제공 유체는 입자 밀도가 200kg/m2이하인 연도 가스 통로 내로 분사되는 방법.
  4. 제1항에 있어서, 첨가제와 연도 가스와 양호하게 혼합되도록 수소 라디칼 제공 첨가제가 입자 분리기 내 또는 이와 인접한 위치로 분사되는 방법.
  5. 제4항에 있어서, 수소 라디칼 제공 첨가제가 입자 분리기의 상부로 분사되는 방법.
  6. 제1항에 있어서, 수소 라디칼 제공 첨가제가 대류부와 입자 분리기를 연결하는 연도 가스 통로 내로 분사되는 방법.
  7. 제5항에 있어서, 수소 라디칼 제공 첨가제가 연도 가스로 분사되는 위치의 바로 상류측의 연도 가스 통로에 배치된 연교환 수단에 의하여 연도 가스의 온도가 제어되는 방법.
  8. 제1항에 있어서, 수소 라디칼 제공 첨가제가 유동상 반응기와 연결된 대류부 내의 과열기 바로 앞에서 분사되는 방법.
  9. 제1항에 있어서, 수소 라디칼 제공 첨가제가 유동상 반응기와 연결된 가스 터빈 앞에서 연소기 내로 분사되는 방법.
  10. 제1항에 있어서, 수소 라디칼 제공 첨가제가 메탄, 오일, 알콜, 연분해 장치의 가스, 가스화 장치의 가스, 또는 액화 석유 가스로 구성된 군에서 선택되는 방법.
  11. 제1항에 있어서, 수소 라디칼 제공 첨가제가 유동상 반응기와 연결된 별도의 가스화 장치로부터 공급되는 가스인 방법.
  12. 제1항에 있어서, 연도 가스에 산소가 잔류하도록 공기 계수가 1보다 큰 과량의 산소 함유 가스가 제1연소 단계로 공급되는 방법.
  13. 제2항에 있어서, 산소 함유 가스가 수소 라디칼 제공 첨가제와 미리 혼합되어, 배출되는 연도 가스로 공급되는 방법.
  14. ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019920702575A 1990-04-17 1991-04-15 유동상 반응기의 질소 함유 연료 연소시의 n2o 배출 감소 방법 KR0164586B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US509,373 1990-04-17
US07/509,373 US5043150A (en) 1990-04-17 1990-04-17 Reducing emissions of N2 O when burning nitrogen containing fuels in fluidized bed reactors
US509373 1990-04-17
PCT/FI1991/000112 WO1991016575A1 (en) 1990-04-17 1991-04-15 Method and apparatus for reducing emissions of n2o when burning nitrogen-containing fuels in fluidized bed reactors

Publications (2)

Publication Number Publication Date
KR930700803A true KR930700803A (ko) 1993-03-16
KR0164586B1 KR0164586B1 (ko) 1998-12-15

Family

ID=24026395

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920702575A KR0164586B1 (ko) 1990-04-17 1991-04-15 유동상 반응기의 질소 함유 연료 연소시의 n2o 배출 감소 방법

Country Status (17)

Country Link
US (1) US5043150A (ko)
EP (1) EP0525001B1 (ko)
JP (1) JPH0792206B2 (ko)
KR (1) KR0164586B1 (ko)
AT (1) ATE124778T1 (ko)
AU (1) AU651343B2 (ko)
BG (1) BG60777B1 (ko)
BR (1) BR9106359A (ko)
CA (1) CA2080698C (ko)
DE (1) DE69111058T2 (ko)
DK (1) DK0525001T3 (ko)
FI (1) FI100913B (ko)
HU (1) HU213482B (ko)
NO (1) NO178478C (ko)
PL (1) PL168255B1 (ko)
RU (1) RU2093755C1 (ko)
WO (1) WO1991016575A1 (ko)

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Also Published As

Publication number Publication date
AU651343B2 (en) 1994-07-21
PL168255B1 (pl) 1996-01-31
RU2093755C1 (ru) 1997-10-20
BG60777B1 (bg) 1996-03-29
US5043150A (en) 1991-08-27
FI924679A0 (fi) 1992-10-16
EP0525001B1 (en) 1995-07-05
HU213482B (en) 1997-07-28
ATE124778T1 (de) 1995-07-15
DE69111058D1 (de) 1995-08-10
AU7662491A (en) 1991-11-11
KR0164586B1 (ko) 1998-12-15
HU9203265D0 (en) 1992-12-28
JPH05505021A (ja) 1993-07-29
DE69111058T2 (de) 1996-01-04
HUT62406A (en) 1993-04-28
JPH0792206B2 (ja) 1995-10-09
BG97087A (bg) 1993-12-24
NO923991D0 (no) 1992-10-14
NO178478C (no) 1996-04-03
CA2080698A1 (en) 1991-10-18
NO178478B (no) 1995-12-27
FI100913B (fi) 1998-03-13
EP0525001A1 (en) 1993-02-03
DK0525001T3 (da) 1995-08-21
FI924679A (fi) 1992-10-16
NO923991L (no) 1992-10-14
WO1991016575A1 (en) 1991-10-31
CA2080698C (en) 1995-10-03
BR9106359A (pt) 1993-04-27

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