KR930019797A - 아크릴 접착제 조성물 및 유기붕소 개시제시스템 - Google Patents

아크릴 접착제 조성물 및 유기붕소 개시제시스템 Download PDF

Info

Publication number
KR930019797A
KR930019797A KR1019930003694A KR930003694A KR930019797A KR 930019797 A KR930019797 A KR 930019797A KR 1019930003694 A KR1019930003694 A KR 1019930003694A KR 930003694 A KR930003694 A KR 930003694A KR 930019797 A KR930019797 A KR 930019797A
Authority
KR
South Korea
Prior art keywords
carbon atoms
alkyl
aldehyde
hydrogen
group
Prior art date
Application number
KR1019930003694A
Other languages
English (en)
Other versions
KR960008486B1 (en
Inventor
엠. 스쿨치 마틴
Original Assignee
데이비드 엘. 해밀톤
내쇼날 스타치 앤드 케미칼 인베스트 홀딩 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 데이비드 엘. 해밀톤, 내쇼날 스타치 앤드 케미칼 인베스트 홀딩 코포레이션 filed Critical 데이비드 엘. 해밀톤
Publication of KR930019797A publication Critical patent/KR930019797A/ko
Application granted granted Critical
Publication of KR960008486B1 publication Critical patent/KR960008486B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
    • H05K3/386—Improvement of the adhesion between the insulating substrate and the metal by the use of an organic polymeric bonding layer, e.g. adhesive
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/939—Multipackage system
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymerization Catalysts (AREA)

Abstract

본 발명은 아크릴접착제 조설물에 유용한 2요소 개시제시스템에 관한 것이며, 제1요소는 안정화된 유기붕소아민착물로 이루어지고, 제2요소는 알데히드 불안정화제 또는 활성화제로 이루어진다. 본 개시제는 엘라스토머 아크릴접착제 조성물에 특히 유용하며, 실온에서 우수한 접착특성으로 비교적 느린 경화시스템을 제공하므로, 보다 긴 개방시간이 요구되는 응용분야에 유용하다.

Description

아크릴 접착제 조성물 및 유기붕소 개시제시스템.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. A)다음식
    으로 이루어지는 안정화된 유기붕소 아민착물(식중, R, R1 ,R2는 탄소원자수 1~10의 알킬 또는 페닐이고, R3, R4는 수소 또는 탄소원자수 1~10의 알킬, 또는
    또는
    여기서, R5, R6은 수소 또는 탄소원자수 1~10의 알킬, m은 2~10, n은 1~6)과, B)다음식 r-(CHO)x으로 이루어지는 불안정화 유효향의 알데히드 활성화제(식중, R은 탄소원자수 1~10의 일킬 또는 탄소원자수 6~10의 아릴이고, x는 1~2)로 이루어지는 2요소 개시제 조성물.
  2. 제1항에 있어서, 유기붕소 아민착물에 있어서 R, R1 ,R2는 탄소원자수 1~4의 알킬이고, R3, R4,R5는 수소 또는 탄소원자수 1~4의 알킬이고, R6은 수소이고, m은 2~6, n은 1~2이고, B)부분의 알데히드의 R기는 탄소원자수 1~4의 알킬기 또는 탄소원자수 6~8의 아릴이고, x는 1인 2요소 개시제 조성물.
  3. 제2항에 있어서, 알데히드의 R기는 아릴기이고, 알대히드 대아민착물은 중량부로 0.5 : 1 내지 20 : 1로 사용되고, B)부분은 또한 식 R-OOH(식중, R은 수소, 탄소원자수 1~10의 알킬 또는 탄소원자수6~14의 아릴 또는 알카릴)의 히드로페록시 화합물을 포함하는 2요소 개시제 조성물.
  4. 제3항에 있어서, 착물은 트리에틸 붕소와 에틸렌 디아민 또는 프로필렌 디아민의 조합물인 2요소 개시제 조성물.
  5. 제1요소는 중합가능한 아크릴모노머와, 다음식
    으로 이루어지는 유효량의 안정화된 유기붕소 아민착물개시제(식중, R, R1,R2는 탄소원자수 1~10의 알킬 또는 페닐이고, R3, R4는 수소 또는 탄소원자수 1~10의 알킬또는
    또는
    여기서, r5, r6은 수소 또는 탄소원자수 1~10의 알킬, m은 2~10, n은 1~6)로 이루어지고, 제2요소는 다음식 r-(cho)x으로 이루어지는 불안정화 유효량의 유기알데히드(식중, r은 탄소원자수 1~10의 알킬 또는 탄소 원자수 6~10의 아릴이고, x는 1~2)로 이루어지는 경화가능한 2요소 접착제 조성물.
  6. 제5항에 있어서, 유기붕소 아민착물에 있어서 R, R1,R2는 탄소원자수 1~4의 알킬이고, R3, R4,R5는 수소 또는 탄소원자수 1~4의 알킬이고, R6은 수소이고, m은 2~6, n은 1~2이고, 알데히드 활성제의 R기는 탄소원자수 1~4의 알킬기 또는 탄소원자수 6~8의 아릴기이고, x는 1인 2요소 접착제 조성물.
  7. 제6항에 있어서, 알데히드의 R기는 아릴기이고, 알데히드 대아민착물은 중량부로 0.5 : 1 내지 20 : 1로 사용되고, 제2요소는 또한 식 R-OOH(식중, R은 수소, 탄소원자수 6~14의 아릴 또는 알카릴)의 히드로페록시 화합물을 포함하는 2요소 접착제 조성물.
  8. 제5항에 있어서, 아크릴모노머를 함유하는 조성물의 제1요소는 또한 고무폴리머를 포함하고, 알데히드 활성화재를 함유하는 제2요소는 또한 고무폴리머가 용해된 중합가능한 아크릴모노머를 포함하고, 조성물의 총중량을 기준으로 유기붕소 아민착물은 0.1~5중량%, 알대히드 활성화제는 0.5~10.0중량%로 사용되는 2요소 접착제 조성물.
  9. 제8항에 있어서, 조성물의 총중량을 기준으로 아클리모노머는 10~90중량%, 고무폴리머는 5~80중량%로 사용되고, 아크릴모노머는 알킬 아크릴레이트 또는 메타크릴레이트이고, 고무폴리머는 폴리부타디엔, 폴리이소프렌 폴리이소부틸렌, 스티렌/부타디엔/스티렌, 스티렌/이소프렌/스티렌, 부타디엔/스티렌, 부타디엔/아클리로니트릴 및 부타디엔/알킬 아크릴레이트의 폴리머, 코폴리머, 블록, 그라프트 또는 랜덤 코폴리머이고, 제2요소는 또한 식 R-OOH(식중, R은 수소, 탄소원자수 1~10의 알킬 또는 탄소원자수 6~14의 아릴 또는 알키릴)의 히드로페록시 화합물을 포함하는 2요소 접착제 조성물.
  10. 제5항 내지 제9항중 어느 한항의 경화가능한 접착제 조성물을 대향하는 표면사이에 삽입하고, 상기 표면을 서로 인접한 관계로 배치하고, 접착제를 경화시키는 단계로 이루어지는 대향표면의 접착방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR93003694A 1992-03-17 1993-03-12 A crylic adhesive composition and organoboron initiator system KR960008486B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US852,855 1992-03-17
US07/852,855 US5286821A (en) 1992-03-17 1992-03-17 Acrylic adhesive composition and organoboron initiator system

Publications (2)

Publication Number Publication Date
KR930019797A true KR930019797A (ko) 1993-10-19
KR960008486B1 KR960008486B1 (en) 1996-06-26

Family

ID=25314400

Family Applications (1)

Application Number Title Priority Date Filing Date
KR93003694A KR960008486B1 (en) 1992-03-17 1993-03-12 A crylic adhesive composition and organoboron initiator system

Country Status (6)

Country Link
US (2) US5286821A (ko)
EP (1) EP0561352A1 (ko)
JP (1) JPH07116249B2 (ko)
KR (1) KR960008486B1 (ko)
AU (1) AU649582B2 (ko)
CA (1) CA2091701A1 (ko)

Families Citing this family (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3535167B2 (ja) * 1994-02-22 2004-06-07 ミネソタ マイニング アンド マニュファクチャリング カンパニー 有機ホウ素アミン錯体に基づく重合開始剤システムを用いて製造される重合性組成物
EP0671433B1 (en) * 1994-03-09 1998-06-17 Mitsui Chemicals, Inc. Polymer composition and core-shell elastomer used therefor
US5690780A (en) 1995-02-22 1997-11-25 Minnesota Mining And Manufacturing Company Polymerizable compositions made with polymerization initiator systems based on organoborane amine complexes
US5721183A (en) * 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
US5621143A (en) * 1995-04-14 1997-04-15 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
US5616796A (en) * 1995-04-14 1997-04-01 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive composition made therewith
US5686544A (en) * 1995-08-11 1997-11-11 Minnesota Mining And Manufacturing Company Organoborane polyamine complex initiator systems and polymerizable compositions made therewith
AU6177796A (en) * 1995-08-11 1997-03-12 Minnesota Mining And Manufacturing Company Initiator system and adhesive composition made therewith
WO1997017383A1 (en) 1995-11-07 1997-05-15 Minnesota Mining And Manufacturing Company Initiator system and adhesive composition made therewith
US5952409A (en) * 1996-01-31 1999-09-14 3M Innovative Properties Company Compositions and methods for imparting stain resistance and stain resistant articles
US5935711A (en) * 1996-10-23 1999-08-10 3M Innovative Properties Company Organoborane amine complex initiator systems and polymerizable compositions made therewith
US6812308B2 (en) * 2000-11-21 2004-11-02 3M Innovative Properties Company Initiator systems and adhesive compositions made therewith
US6383655B1 (en) 1998-06-12 2002-05-07 3M Innovative Properties Company Low odor polymerizable compositions useful for bonding low surface energy substrates
AU1929100A (en) 1998-12-03 2000-06-19 Dexter Corporation, The Adhesive compositions with retarding additive
US6252023B1 (en) * 1999-03-19 2001-06-26 3M Innovative Properties Company Organoborane amine complex inatator systems and polymerizable compositions made therewith
US6486090B1 (en) * 1999-11-04 2002-11-26 3M Innovative Properties Company Initiator/hydroxide and initiator/alkoxide complexes, systems comprising the complexes, and polymerized compositions made therewith
US6410667B1 (en) * 1999-11-04 2002-06-25 3M Innovative Properties Company Initiator/amidine complexes, systems comprising the complexes, and polymerized compositions made therewith
US6806330B1 (en) 1999-12-17 2004-10-19 Dow Global Technologies Inc. Amine organoborane complex polymerization initiators and polymerizable compositions
US6479602B1 (en) * 2000-03-15 2002-11-12 3M Innovative Properties Polymerization initiator systems and bonding compositions comprising vinyl aromatic compounds
EP1201722A1 (en) * 2000-10-23 2002-05-02 Loctite (R & D) Limited Polymerisation initiators, polymerisable compositions, and uses thereof
CN1237077C (zh) * 2001-02-21 2006-01-18 3M创新有限公司 工作寿命长的可聚合体系
US20030047268A1 (en) * 2001-08-23 2003-03-13 Korchnak Gregory J. Method for repairing fuel tanks
US20030044553A1 (en) 2001-08-23 2003-03-06 Ravi Ramanathan Fuel tanks
US6740716B2 (en) 2001-10-30 2004-05-25 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
US6630555B2 (en) * 2001-11-06 2003-10-07 Lord Corporation Internally blocked organoborate initiators and adhesives therefrom
US6849569B2 (en) 2001-12-31 2005-02-01 3M Innovative Properties Company Initiator systems comprising β-ketone compounds
US6734268B2 (en) * 2001-12-31 2004-05-11 3M Innovative Properties Company Metal salt modifiers for bonding compositions
US6762260B2 (en) 2002-03-05 2004-07-13 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
WO2003089536A2 (en) * 2002-04-19 2003-10-30 Loctite (R & D) Limited Polymerisation initiators based on ammonium tetraalkyl boranes, polymerisable compositions, and uses thereof for bonding low surface energy substrates
US6867271B1 (en) 2002-06-24 2005-03-15 Henkel Corporation Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces
US20040001945A1 (en) * 2002-06-27 2004-01-01 Cate Peter J. Composite foam structure having an isotropic strength region and anisotropic strength region
US7098279B2 (en) * 2002-10-22 2006-08-29 Loctite (R&D) Limited Non-flammable and non-combustible adhesive bonding systems having adherence to low energy surfaces
US6777512B1 (en) 2003-02-28 2004-08-17 Dow Global Technologies Inc. Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components
US20040242817A1 (en) * 2003-05-29 2004-12-02 Lord Corporation Internally coordinated organoboranes
CN100480279C (zh) * 2003-06-09 2009-04-22 陶氏环球技术公司 稳定的有机硼烷聚合反应引发剂和可聚合的组合物
US20040259990A1 (en) * 2003-06-18 2004-12-23 Sonnenschein Mark F. Paint formulation for a low surface energy substrate
CA2534825A1 (en) * 2003-08-13 2005-02-24 Dow Global Technologies Inc. Method for joining piping systems and piping to equipment, fixtures, devices, structures, and appliances
KR20060063945A (ko) * 2003-08-13 2006-06-12 다우 글로벌 테크놀로지스 인크. 기질과 물체를 접합시키는 방법
DE10339329A1 (de) * 2003-08-25 2005-03-24 Röhm GmbH & Co. KG Monomer - Polymer-Systeme mit steuerbarer Topfzeit
JP2005120215A (ja) * 2003-10-16 2005-05-12 Hori Glass Kk ２液型構造用アクリル接着剤組成物およびこれを用いた接着構造
GB0326286D0 (en) 2003-11-11 2003-12-17 Vantico Gmbh Initiator systems for polymerisable compositions
US8501886B2 (en) * 2003-12-22 2013-08-06 Dow Global Technologies Llc Accelerated organoborane amine complex initiated polymerizable compositions
US7534843B2 (en) * 2003-12-22 2009-05-19 Dow Global Technoloigies, Inc. Accelerated organoborane amine complex initiated polymerizable compositions
WO2005085376A1 (en) * 2004-02-27 2005-09-15 Akzo Nobel N.V. Polymerization initiator systems containing aluminum compounds as curing inhibitors and polymerizable compositions made therewith
US7360552B2 (en) 2004-04-23 2008-04-22 Dow Global Technologies Inc. Injectable structural adhesive
EP1609831B1 (en) * 2004-06-23 2006-08-16 Sika Technology AG (Meth)acrylic adhesive with low odor and high impact resistance
US8202932B2 (en) * 2004-12-03 2012-06-19 Loctite (R&D) Limited Adhesive bonding systems having adherence to low energy surfaces
CN101120026B (zh) * 2005-02-16 2011-08-03 陶氏康宁公司 使用有机基硼烷胺络合物的聚合物颗粒和包封的组合物
US7408012B1 (en) 2005-04-18 2008-08-05 Loctite (R&D) Limited Adhesive bonding systems having adherence to low energy surfaces
CA2624322A1 (en) * 2005-10-07 2007-04-19 Dow Global Technologies Inc. Amido-organoborate initiator systems
US7682663B2 (en) * 2006-02-23 2010-03-23 Bowling Green State University Remote curing of polymer coating by gaseous, vaporous or aerosol initiating agent
US7887668B2 (en) * 2006-08-30 2011-02-15 Dow Global Technologies Inc. Amine organoborane polymerizable compostion and uses therefor
US7524907B2 (en) * 2006-10-12 2009-04-28 Dow Global Technologies, Inc. Accelerated organoborane initiated polymerizable compositions
US20080103274A1 (en) * 2006-10-12 2008-05-01 Jialanella Gary L Accelerated organoborane initiated polymerizable compositions
US20080299317A1 (en) * 2007-05-29 2008-12-04 Hable Christopher T Acrylate adhesive material and method of use therefor
US8742050B2 (en) * 2008-03-28 2014-06-03 Henkel US IP LLC Two part hybrid adhesive
US20110104508A1 (en) * 2008-08-29 2011-05-05 Dow Global Technologies Inc. Adhesive for bonding to flexible polymer surfaces
JP2012506859A (ja) * 2008-10-23 2012-03-22 ダウ グローバル テクノロジーズ エルエルシー オルガノボラン化合物用ブロッキング剤
EP2635625B1 (en) 2010-11-01 2016-11-30 Dow Brasil S.A. Polyolefins having one or more surfaces modified to improve adhesion of polyisocyanate functional adhesives thereto
GB2491170B (en) 2011-05-26 2013-11-06 Henkel Ireland Ltd Two-part polymerisable compositions
US9382452B2 (en) 2013-02-07 2016-07-05 Illinois Tool Works, Inc. Low surface energy bonding adhesive formulation and process for the use thereof
US9771501B2 (en) 2013-02-20 2017-09-26 Illinois Tool Works, Inc. Galvanized metal bonding adhesive formulation and process for the use thereof
JP6297857B2 (ja) * 2014-02-21 2018-03-20 スリーエム イノベイティブ プロパティズ カンパニー ２液型接着剤及びそれを含む構造体
CN107429143B (zh) * 2015-04-23 2019-08-16 日立化成株式会社 粘接剂组合物和连接结构体
JP6849303B2 (ja) * 2015-08-12 2021-03-24 スリーエム イノベイティブ プロパティズ カンパニー ２液型接着剤及びその硬化物を含む構造体
JP6190933B2 (ja) 2016-02-09 2017-08-30 サンメディカル株式会社 重合性組成物およびキット、ならびに重合開始剤
EP3415539B1 (en) 2016-02-09 2022-03-30 Sun Medical Co., Ltd. Polymerizable composition and kit thereof, and polymerization initiator
EP3689945A4 (en) 2017-09-29 2021-06-02 Sun Medical Co., Ltd. COMPOSITE PARTICLES, KIT, MATERIAL AND PROCESS FOR THE PRODUCTION OF COMPOSITE PARTICLES
GB2580162B (en) 2018-12-21 2022-07-13 Henkel IP & Holding GmbH One-part photocurable (meth) acrylate compositions
FR3098815B1 (fr) * 2019-07-18 2021-06-25 Bostik Sa Procédé de polymérisation avec un complexe de borane-amine
CN110358455A (zh) * 2019-08-01 2019-10-22 烟台艾格路电子科技有限公司 一种低气味快速固化的丙烯酸胶黏剂
FR3109383B1 (fr) * 2020-04-16 2022-05-06 Bostik Sa Composition bi-composante et utilisations

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3275611A (en) * 1960-12-30 1966-09-27 Monsanto Co Process for polymerizing unsaturated monomers with a catalyst comprising an organoboron compound, a peroxygen compound and an amine
CH430219A (fr) * 1962-04-07 1967-02-15 Edison Soc Procédé de polymérisation et copolymérisation des composés éthyléniquement non saturés
US3616040A (en) * 1968-08-14 1971-10-26 Loctite Corp Process for bonding with acrylate polymerized by a peroxy and a condensation product of aldehyde and a primar or secondary amine
GB1463506A (en) * 1973-12-19 1977-02-02 Merkl G G Method of preparing a resinous material and product thereof
IE50787B1 (en) * 1980-05-09 1986-07-23 Loctite Corp Polyisoprene toughened adhesive composition
US4404345A (en) * 1981-09-16 1983-09-13 Minnesota Mining And Manufacturing Company Novel adhesive compositions
US4602073A (en) * 1985-06-07 1986-07-22 National Starch And Chemical Corporation Adhesive compositions
JPH0781115B2 (ja) * 1988-12-29 1995-08-30 カネボウ・エヌエスシー株式会社 二液型アクリル系接着剤組成物
US5106928A (en) * 1991-04-29 1992-04-21 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system

Also Published As

Publication number Publication date
KR960008486B1 (en) 1996-06-26
US5286821A (en) 1994-02-15
JPH07116249B2 (ja) 1995-12-13
EP0561352A1 (en) 1993-09-22
CA2091701A1 (en) 1993-09-18
US5376746A (en) 1994-12-27
AU3305493A (en) 1993-10-21
AU649582B2 (en) 1994-05-26
JPH0693235A (ja) 1994-04-05

Similar Documents

Publication Publication Date Title
KR930019797A (ko) 아크릴 접착제 조성물 및 유기붕소 개시제시스템
KR920019899A (ko) 아크릴접착제 조성물과 유기보론 개시제계 및 그 접착방법
KR950008636A (ko) 도료 조성물
BR0308306A (pt) Iniciadores de polimerização de complexo de organoborano/amina e composições polimerizáveis
KR860008247A (ko) 감압성 접착제 조성물
BR9307444A (pt) Composição polimérica óleo lubrificante concentrado e processo para a preparação da composição polimérica
GB1582693A (en) Filled cyanoacrylate adhesive compositions
BR8907097A (pt) Cimento para osso
US4713405A (en) α-cyanoacrylate adhesive composition of matter
KR890000614A (ko) 방오용 페인트
KR890010001A (ko) 헤어 스타일링 제품에 사용하기 위한 저 유리전이온도 접착성 공중합체
MY127462A (en) Polymer to be used as processing aid in a vinyl chloride resin composition
NO20003136L (no) Et polysiloksan som har en kopolymer dispergert deri og tetningsmasse inneholdende samme
KR830006386A (ko) 고니트릴 수지와 소수성 나이론의 조성물
KR900004848A (ko) 블록 중합체에 의해 변성된 에폭시 수지 조성물
AU4414300A (en) Method for obtaining oxacarbonyl polymers, functionalisation, resulting polymersand functionalising agent
JPS6448059A (en) Photoresist composition
NO924261L (no) To-komponentsystem for belegning
ES2105300T3 (es) Composicion para pinturas.
DK12089A (da) Haerdelig dispersion
BR0207499A (pt) Agentes de tratamento de superfìcie para bases polìmeras orgânicas de sistemas de (met)acrilato aeróbicos polimerizáveis
KR940019797A (ko) 내한 충격성이 우수한 고무 변성 스티렌계 수지조성물 및 그의 제조 방법
EP0484540A4 (en) Automotive topcoating composition
KR900003212A (ko) 중합화 방법
KR960024669A (ko) 동밀착력이 우수한 감광성 수지 조성물

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20010410

Year of fee payment: 6

LAPS Lapse due to unpaid annual fee