KR930019628A - 피리딘디카르복실레이트 화합물의 제조방법 - Google Patents

피리딘디카르복실레이트 화합물의 제조방법 Download PDF

Info

Publication number
KR930019628A
KR930019628A KR1019930003514A KR930003514A KR930019628A KR 930019628 A KR930019628 A KR 930019628A KR 1019930003514 A KR1019930003514 A KR 1019930003514A KR 930003514 A KR930003514 A KR 930003514A KR 930019628 A KR930019628 A KR 930019628A
Authority
KR
South Korea
Prior art keywords
pyridinedicarboxylate
dialkyl
acid
formula
compound
Prior art date
Application number
KR1019930003514A
Other languages
English (en)
Inventor
프랜시스 도우너 쥬니어 로버트
Original Assignee
알퐁스 아아르 노에
아메리칸 사이아나밋드 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 알퐁스 아아르 노에, 아메리칸 사이아나밋드 캄파니 filed Critical 알퐁스 아아르 노에
Publication of KR930019628A publication Critical patent/KR930019628A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/55—Acids; Esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/80—Acids; Esters in position 3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

,

Description

피리딘디카르복실레이트 화합물의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 고온에서 산의 존재 및 임의로 용매의 존재하에서 하기 일반식 Ⅱ의,-불포화 옥심을 :
    (여기서, Y및 Z은 일반식 Ⅰ에 대해 하기 서술된 바와 같음)
    하기 일반식 Ⅲ의 아미노부텐디오에이트와 반응시키는 것을 특징으로 하는 :
    (여기서,는 각각 독립적으로 수소,알킬,시클로 알킬, 페닐이거나, 그들이 부착된 원자와 함께 취해져서 산소로 임의로 차단된 5 또는 6원 지환족 고리를 형성할 수 있고,는 일반식 Ⅰ에 대해 상기 서술된 바와 같음)
    하기 일반식 Ⅰ의 화합물을 제조하는 방법 :
    (여기서,는 각각 독립적으로 페닐 또는 페닐로 임의로 치환된알킬이고 Y 및 Z는 각각 독립적으로 수소 또는 1-3개의 할로겐으로 임의로 치환된알킬 떠는알킬시기임).
  2. 제1항에 있어서, 일반식 Ⅱ의,-불포화 옥심 및 일반식 Ⅲ의 아미노부텐디오에이트가 약 1:1-1:1.5 몰당량의 비율로 존재하는 방법.
  3. 제1항에 있어서, 산기 아세트산, P-틀루엔설폰산, 메탄설폰산, 황산, 인산, 옥시염화인, 삼염화인, 삼브롬화인, 염화수소 및 브롬화수소로 구성되는 군으로 부터 선택되는 방법.
  4. 제3항에 있어서, 산이 염화수소인 방법.
  5. 제1항에 있어서, 반응이 용매의 존재하에 실행되는 방법.
  6. 제5항에 있어서, 용매가 크실렌, 틀루엔, 벤젠, 할로벤젠, 디할롭젠, 디할로에탄, 디할로메탄, 에틸 아세테이트, 에틸 프로피오네이트, 메탄올, 에탄올, 프로판올 및 부탄올로 구성되는 군으로 부터 선택되는 방법.
  7. 제6항에 있어서, 용매가 디클로로 에탄인 방법.
  8. 제1항에 있어서, 온도가 약 50℃-180℃인 방법.
  9. 제1항에 있어서, Z가 수소이고 Y가 하나의 할로겐으로 임의로 치환된알킬 또는알콕시기인 일반식 Ⅰ인 화합물을 제조하는 방법.
  10. 제9항에 있어서, 디알킬 5-에틸-2,3-피리딘디카르복실레이트, 디알킬 2,3-피리딘디카르복실레이트, 디알킬 5-메틸-2,3-피라딘디카르복실레이트, 디알킬 5-(메톡시메틸)-2,3-피리딘디카르복실레이트 및 디알킬 5-(클로로메틸)-2,3-피리딘디카르복실레이트로 부터 선택되는 화합물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930003514A 1992-03-10 1993-03-09 피리딘디카르복실레이트 화합물의 제조방법 KR930019628A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/849,117 1992-03-10
US07/849,117 US5227491A (en) 1992-03-10 1992-03-10 Process for the preparation of dialkyl 2,3-pyridinedicarboxylate and derivatives thereof from an α,β-unsaturated oxime and an aminobutenedioate

Publications (1)

Publication Number Publication Date
KR930019628A true KR930019628A (ko) 1993-10-18

Family

ID=25305103

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930003514A KR930019628A (ko) 1992-03-10 1993-03-09 피리딘디카르복실레이트 화합물의 제조방법

Country Status (23)

Country Link
US (1) US5227491A (ko)
EP (1) EP0560019B1 (ko)
JP (1) JPH0656787A (ko)
KR (1) KR930019628A (ko)
CN (1) CN1042332C (ko)
AR (1) AR248130A1 (ko)
AT (1) ATE137222T1 (ko)
AU (1) AU659283B2 (ko)
BR (1) BR9301107A (ko)
CA (1) CA2091213A1 (ko)
CZ (1) CZ283077B6 (ko)
DE (1) DE69302309T2 (ko)
DK (1) DK0560019T3 (ko)
ES (1) ES2086791T3 (ko)
FI (1) FI101961B (ko)
GR (1) GR3019908T3 (ko)
HU (1) HU210903B (ko)
IL (1) IL104956A (ko)
MX (1) MX9301127A (ko)
SG (1) SG52412A1 (ko)
SK (1) SK279565B6 (ko)
TW (1) TW276250B (ko)
ZA (1) ZA931676B (ko)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006060029A2 (en) * 2004-04-08 2006-06-08 Dow Agrosciences Llc Insecticidal n-substituted sulfoximines
TWI398433B (zh) 2006-02-10 2013-06-11 Dow Agrosciences Llc 殺蟲性之ｎ-取代（６-鹵烷基吡啶-３-基）烷基磺醯亞胺
TWI381811B (zh) * 2006-06-23 2013-01-11 Dow Agrosciences Llc 用以防治可抵抗一般殺蟲劑之昆蟲的方法
TWI387585B (zh) * 2006-09-01 2013-03-01 Dow Agrosciences Llc 殺蟲性之ｎ-取代（雜芳基）烷基烴基硫亞胺
BRPI0719053B1 (pt) * 2006-09-01 2016-09-27 Dow Agrosciences Llc inseticidas alquil sulfoximinas (1,3-tiazol 2-substituido) n-substituídas, bem como composição e método para controle de insetos
TWI395736B (zh) * 2006-11-08 2013-05-11 Dow Agrosciences Llc 作為殺蟲劑之雜芳基（取代的）烷基ｎ-取代的磺醯亞胺（二）
US7709648B2 (en) * 2007-02-09 2010-05-04 Dow Agrosciences Llc Process for the preparation of 2-substituted-5-(1-alkylthio)alkylpyridines
AR066366A1 (es) * 2007-05-01 2009-08-12 Dow Agrosciences Llc Mezclas sinergicas plaguicidas
JP5276660B2 (ja) * 2007-07-20 2013-08-28 ダウ アグロサイエンシィズ エルエルシー 植物の成長力の増大
BRPI0909036A8 (pt) * 2008-03-03 2018-10-23 Dow Agrosciences Llc pesticidas
CN103724257B (zh) * 2012-10-11 2015-06-10 中国中化股份有限公司 一种制备2,3-二羧酸酯吡啶类化合物的方法
CN104447527B (zh) * 2013-09-23 2017-06-06 中国中化股份有限公司 一种制备吡啶‑2，3‑二羧酸酯化合物的方法
CN111468080B (zh) * 2020-04-13 2021-01-01 深圳市广万达环保科技有限公司 一种工业废水的环保处理方法及处理剂

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4798619A (en) * 1980-06-02 1989-01-17 American Cyanamid Co. 2-(2-imidazolin-2-yl)-pyridines and quinolines and use of said compounds as herbicidal agents
US4460776A (en) * 1982-05-25 1984-07-17 American Cyanamid Company Process for the preparation of 6-substituted-2,3-pyridinedicarboxylic acid diesters
US4748244A (en) * 1984-05-11 1988-05-31 Ciba-Geigy Corporation Process for the preparation of pyridine-2-3-dicarboxylic acid derivatives, and novel 1-amino-1,4-dihydropyridine-2-3-diarboxylic acid derivatives
EP0233150B1 (de) * 1986-02-10 1992-11-11 Ciba-Geigy Ag Verfahren zur Herstellung von 2-(Imidazolin-2-yl)-pyridin- und -chinolin-3-carbonsäuren
US4766218A (en) * 1986-08-29 1988-08-23 American Cyanamid Company Method for the preparation of quinoline-2,3-dicarboxylic acid
EP0274379B1 (en) * 1987-01-06 1993-06-30 Sugai Chemical Industry Co., Ltd. Process for preparing pyridine-2,3-dicarboxylic acid compounds
JPH0625116B2 (ja) * 1987-07-08 1994-04-06 ダイソー株式会社 ピリジン−２，３−ジカルボン酸誘導体の製造法
GB8721986D0 (en) * 1987-09-18 1987-10-28 Ici Plc Pyridine derivative
DE3840554A1 (de) * 1988-12-01 1990-06-13 Wacker Chemie Gmbh Verfahren zur herstellung von pyridin-2,3-dicarbonsaeureestern
HUT57727A (en) * 1990-05-11 1991-12-30 Hoechst Celanese Corp Process for producing pyridinecarboxylic acid derivatives

Also Published As

Publication number Publication date
DE69302309T2 (de) 1996-11-21
HU210903B (en) 1995-09-28
JPH0656787A (ja) 1994-03-01
AU3408493A (en) 1993-09-16
HU9300657D0 (en) 1993-05-28
EP0560019B1 (en) 1996-04-24
DK0560019T3 (da) 1996-05-13
IL104956A0 (en) 1993-07-08
HUT64030A (en) 1993-11-29
FI931033A0 (fi) 1993-03-09
CA2091213A1 (en) 1993-09-11
AR248130A1 (es) 1995-06-30
FI101961B1 (fi) 1998-09-30
FI931033A (fi) 1993-09-11
CZ13493A3 (en) 1994-01-19
TW276250B (ko) 1996-05-21
US5227491A (en) 1993-07-13
FI101961B (fi) 1998-09-30
EP0560019A1 (en) 1993-09-15
SG52412A1 (en) 1998-09-28
ZA931676B (en) 1993-10-06
ATE137222T1 (de) 1996-05-15
AU659283B2 (en) 1995-05-11
SK8393A3 (en) 1993-10-06
SK279565B6 (sk) 1999-01-11
CN1042332C (zh) 1999-03-03
DE69302309D1 (de) 1996-05-30
CZ283077B6 (cs) 1997-12-17
MX9301127A (es) 1994-01-31
ES2086791T3 (es) 1996-07-01
IL104956A (en) 1997-02-18
CN1076191A (zh) 1993-09-15
GR3019908T3 (en) 1996-08-31
BR9301107A (pt) 1993-09-14

Similar Documents

Publication Publication Date Title
KR930019628A (ko) 피리딘디카르복실레이트 화합물의 제조방법
SU552025A3 (ru) Способ получени производных фенил-имидазолил-алканов
SU514569A3 (ru) Способ получени производных пиридазина
KR840000508A (ko) 4-아닐리노피리미딘 유도체의 제조방법
GB1357852A (en) Process for the preparation of 1,2,4-triazin-5-ones
KR960017638A (ko) 옥사졸 아민 중간체를 통한 아릴피롤류 살충제의 제조방법
GB1398377A (en) Preparation of resorcinol and alkyl-substituted derivatives thereof
KR900016194A (ko) 퀴나졸린 유도체의 제조방법
Newcomb et al. 4-bromo-3, 3-dimethyl-1-butene: a new probe for radical intermediates in reactions in strongly basic media
AU3498999A (en) Process and intermediates for the manufacture of pyridine-2,3-dicarboxylate compounds
GB1124248A (en) Novel benzdiaz [1,4] epine derivatives and processes for the preparation thereof
GB1529903A (en) Piperidine derivatives and their use as stabilisers for synthetic polymers
US2855395A (en) Phthalides
KR840008647A (ko) 대칭 1,4-디하이드로피리딘디카복실 에스테르의 제조방법
IE40334B1 (en) Derivatives of 1-phenoxy-3-aminopropan-2-ol and process for their preparation
JPS5583786A (en) Diazepine derivative and its preparation
Gottlieb et al. Stannous Chloride Reduction of Nitroalkenes in Amines. Synthesis and Cycloaddition of α-Dialkylaminoaldoxime
Martin et al. Ketenes. VII. Some Reactions of 3-Ethoxy-2, 2-dimethylcyclobutanone with Aromatic Amines1
US3389149A (en) 4-oxo-2, 4, 5, 6, 7, 7alpha-hexahydroheterocyclic compounds and preparation thereof
GB1077983A (en) Substituted naphthoxazinones and preparation thereof
JPS5888361A (ja) ３−アミノ−１，４−ビス（アルコキシカルボニル）マレイミド類およびその製法
KR960013204A (ko) 4-아릴-2-퍼플루오로알킬-3-옥사졸린-5-온의 제조 방법
CN115572258A (zh) 一种c2轴手性的联喹啉骨架化合物的制备方法
KR970061868A (ko) 방향족 니트릴의 제조 방법
SU439988A1 (ru) Способ получени 2-(аминофенилимино)-3аза-1-тиациклоалканов

Legal Events

Date Code Title Description
A201 Request for examination
E701 Decision to grant or registration of patent right
NORF Unpaid initial registration fee