KR930017614A - 불포화 알데히드 및 불포화 카르복실산 합성용 촉매의 제조방법 - Google Patents

불포화 알데히드 및 불포화 카르복실산 합성용 촉매의 제조방법 Download PDF

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KR930017614A
KR930017614A KR1019930002864A KR930002864A KR930017614A KR 930017614 A KR930017614 A KR 930017614A KR 1019930002864 A KR1019930002864 A KR 1019930002864A KR 930002864 A KR930002864 A KR 930002864A KR 930017614 A KR930017614 A KR 930017614A
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catalyst
unsaturated
unsaturated carboxylic
volume
synthesis
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KR1019930002864A
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KR100204321B1 (ko
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세이고 와따나베
모도무 오오기다
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나가이 야다로오
미쯔비시레이온 가부시끼가이샤
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

몰리부덴과 비스무트를 함유하는 다성분계의 불포화 알데히드 및 불포화 카르복실산 합성용 촉매를 제조할대에 질소산화물을 1용량%이상, 산소를 0.5용량%에사 함유하는 분위기중에서 동 촉매용 원료의 건조물을 소성시킴을 특징으로 하는 불포화 알데히드 및 불포화 카르복실산 합성용 촉매의 제조방법.

Description

불포화 알데히드 및 불포화 카르복실산 합성용 촉매의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 적어도 몰리부덴화합물과 비스무트화합물을 성분으로 함유하는 혼합용액 또는 수성슬러리를 건조하여 얻은 건조물을 소성시킴으로서 몰리부덴 및 비스무트를 함유하는 다성분계의 불포화 알데히드와 불포화 카르복실산 합성용 촉매를 얻는 제조방법에 있어서, 소성단계로서 200℃-600℃의 범위온도에서 소성시킬때 적어도 2분간에 걸쳐 질소 산화물을 1용량%이상으로 하고 산소를 0.5용량%이상 함유시킨 분위기중에서 이 건조물을 소성시킴을 특징으로 하느 불포화 알데히드 및 불포화 카르복실산 합성용 촉매의 제조방법.
  2. 제1항에 있어서, 질소산화물을 1용량%이상, 산소를 0.5용량%이상 함유하는 분위기중, 소성의 초기단계에서 소성시킴을 특징으로 하는 불포화 알데히드 및 불포화 카르복실산 합성을 촉매의 제조방법.
  3. 제1항 기재의 제조방법에 의해 제조된 불포화 알데히드 및 불포화 카르복실산 합성을 촉매를 사용하여 프로필렌, 이소부틸렌 또는 3급 부탄올을 분자상 산소에 의해 기상접촉산화 시킴을 특징으로 하는 (메타) 아크롤레인 및 (메타)아크릴산의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930002864A 1992-02-27 1993-02-27 불포화 알데히드 및 불포화 카르복실산 합성용 촉매의 제조방법 KR100204321B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP92-076076 1992-02-27
JP04076076A JP3108511B2 (ja) 1992-02-27 1992-02-27 不飽和アルデヒド及び不飽和カルボン酸合成用触媒の製造法

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KR930017614A true KR930017614A (ko) 1993-09-20
KR100204321B1 KR100204321B1 (ko) 1999-06-15

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Country Status (6)

Country Link
US (1) US5349092A (ko)
EP (1) EP0558028B1 (ko)
JP (1) JP3108511B2 (ko)
KR (1) KR100204321B1 (ko)
DE (1) DE69302504T2 (ko)
MY (1) MY109251A (ko)

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JP4185217B2 (ja) * 1999-05-25 2008-11-26 株式会社日本触媒 複合酸化物触媒、並びに（メタ）アクロレインおよび（メタ）アクリル酸の製造方法
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
JP4970986B2 (ja) * 2007-03-08 2012-07-11 株式会社日本触媒 複合酸化物触媒の製造方法および該触媒を用いた不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP5768326B2 (ja) * 2010-04-22 2015-08-26 三菱レイヨン株式会社 触媒の製造方法およびメタクリル酸の製造方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins

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Also Published As

Publication number Publication date
KR100204321B1 (ko) 1999-06-15
DE69302504D1 (de) 1996-06-13
US5349092A (en) 1994-09-20
JP3108511B2 (ja) 2000-11-13
MY109251A (en) 1996-12-31
EP0558028A1 (en) 1993-09-01
EP0558028B1 (en) 1996-05-08
JPH05237388A (ja) 1993-09-17
DE69302504T2 (de) 1996-10-10

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